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排序方式: 共有839条查询结果,搜索用时 15 毫秒
821.
Wei S Messerer R Tsogoeva SB 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(51):14380-14384
Two birds one stone: A new atom-economical one-pot approach to enantioselective chiral drug synthesis, involving in situ multistep organocatalyst formation and the application of the reaction for multistep sequential synthesis of β-adrenergic blockers is disclosed (see scheme). 相似文献
822.
823.
Joanna Prażmowska Adam Szyszka Regina Paszkiewicz Marek Tłaczała 《Central European Journal of Physics》2011,9(2):398-403
In this paper, a study of the influence of hydrogen (concentrations 6 ppm − 1%) on the work function of thin metallic films
at moderately elevated temperatures is presented. The work function was measured indirectly by the observation of the surface
potential of dedicated test structures using scanning surface potential microscope. Metallic layers with thicknesses of 10,
20, 30, and 50 nm were deposited on semiconductor substrates as well as on a thick gold layer. The investigations were focused
on palladium thin films although a comparison to results obtained for platinum layers was also discussed. 相似文献
824.
Maria Cristina Andres Arbage Gervsio Annes Degrazia Guilherme Sausen Welter Dbora Regina Roberti Otvio Costa Acevedo Osvaldo Luiz Leal de Moraes Simone Teleginski Ferraz Andra Ucker Timm Virnei Silva Moreira 《Physica A》2008,387(16-17):4376-4386
A parameterization for the transport processes in a shear driven planetary boundary layer (PBL) has been established employing turbulent statistical quantities measured during the north wind phenomenon in southern Brazil. Therefore, observed one-dimensional turbulent energy spectra are compared with a spectral model based on the Kolmogorov arguments. The good agreement obtained from this comparison leads to well defined formulations for the turbulent velocity variance, local decorrelation time scale and eddy diffusivity. Furthermore, for vertical regions in which the wind shear forcing is relevant, the eddy diffusivity derived from the north wind data presents a similar profile to those obtained from the non-extensive statistical mechanics theory. Finally, a validation for the present parameterization has been accomplished, using a Lagrangian stochastic dispersion model. The Prairie Grass data set, which presents high mean wind speed, is simulated. The analysis developed in this study shows that the turbulence parameterization constructed from wind data for north wind flow cases is able to describe the diffusion in a high wind speed, shear-dominated PBL. 相似文献
825.
A one-dimensional nonlinear fractional filtration equation with the Riemann–Liouville time-fractional derivative is proposed for modeling fluid flow through a porous medium. This equation is derived under an assumption that the fluid has a fractional equation of state in which the fluid density depends on the time-fractional derivative of pressure. The obtained equation belongs to the diffusion-wave type of equations. A case when the order of fractional differentiation is close to an integer number is considered, and a small parameter is introduced into the fractional filtration equation under consideration. An expansion of the Riemann–Liouville time-fractional derivative into the series with respect to this small parameter is obtained. Using this expansion, a first-order approximation of the derived fractional filtration equation is performed. Next, the problem of approximate Lie point symmetry group classification for this approximate nonlinear filtration equation with a small parameter is studied. It is shown that approximate symmetry groups admitted by different realizations of the approximate filtration equation have much more dimensions than the corresponding exact Lie point symmetry groups admitted by unperturbed fractional diffusion-wave equations. Obtained classification results permit to construct approximate invariant solutions for the considered nonlinear time-fractional filtration equations. 相似文献
826.
Benedikta Puodinait Lidija Kosychova Zita Stumbrevi
it Regina Jan
ien Zita Talaikyt 《Journal of heterocyclic chemistry》1999,36(4):1013-1016
Condensation of 3-nitro-1,2-phenylenediamine with ethyl acetoacetate in boiling xylene gave two isomeric 2,3-dihydro-4-methyl-9-nitro- and 2,5-dihydro-4-methyl-6-nitro-1H-1,5-benzodiazepin-2-ones, the 9-nitro derivative thermal rearrangement product N-isopropenyl-4-nitrobenzimidazolone and a non cyclic acetoacetamide derivative. At room temperature these reactants afforded 2,3-dihydro-2-ethoxycarbonyl-methyl-2-methyl-4-nitrobenzimidazole. 相似文献
827.
A Pd-Ag (24 wt%) alloy composite membrane was prepared by the magnetron sputtering. A γ-Al_2O_3 membrane was synthesized by the sol-gel method and used as substrate of the Pd-Ag alloy film. The process parameters of the magnetron sputtering were optimized as a function of the compactness of the Pd-Ag alloy film. The best membrane with a thickness of 1 μm was produced with a sputtering pressure of 2.7 Pa and a substrate temperature of 400℃. The membrane had an H_2/N_2 permselectivity of 51.5--1000 and an H_2 permeation rate of 0.036--1.17×10~(-5)cm~3/cm~2·s· Pa, depending on operating conditions. 相似文献
828.
Andreas Stroh 《Nachrichten aus der Chemie》1999,47(8):1064-1065
829.
Marcos Antonio Villetti Adryana Rocha Clementino Ilaria Dotti Patricia Regina Ebani Eride Quarta Francesca Buttini Fabio Sonvico Annalisa Bianchera Redouane Borsali 《Molecules (Basel, Switzerland)》2021,26(21)
Tamoxifen citrate (TMC), a non-steroidal antiestrogen drug used for the treatment of breast cancer, was loaded in a block copolymer of maltoheptaose-b-polystyrene (MH-b-PS) nanoparticles, a potential drug delivery system to optimize oral chemotherapy. The nanoparticles were obtained from self-assembly of MH-b-PS using the standard and reverse nanoprecipitation methods. The MH-b-PS@TMC nanoparticles were characterized by their physicochemical properties, morphology, drug loading and encapsulation efficiency, and release kinetic profile in simulated intestinal fluid (pH 7.4). Finally, their cytotoxicity towards the human breast carcinoma MCF-7 cell line was assessed. The standard nanoprecipitation method proved to be more efficient than reverse nanoprecipitation to produce nanoparticles with small size and narrow particle size distribution. Moreover, tamoxifen-loaded nanoparticles displayed spherical morphology, a positive zeta potential and high drug content (238.6 ± 6.8 µg mL−1) and encapsulation efficiency (80.9 ± 0.4 %). In vitro drug release kinetics showed a burst release at early time points, followed by a sustained release profile controlled by diffusion. MH-b-PS@TMC nanoparticles showed higher cytotoxicity towards MCF-7 cells than free tamoxifen citrate, confirming their effectiveness as a delivery system for administration of lipophilic anticancer drugs. 相似文献
830.
Trimethylamine‐bis(trifluoromethyl)boranes R(CF3)2B · NMe3 (R = cis/trans‐CF3CF=CF ( 1/2 ), HC≡C ( 3 ), H2C=CH ( 4 ), C2H5 ( 5 ), C6H5CH2 ( 6 ), C6F5 ( 7 ), C6H5 ( 8 )) react with NEt3 × 3 HF depending on the nature of R at 155–200 °C under replacement of the trimethylamine ligand to form the corresponding fluoro‐bis(trifluoromethyl)borates [R(CF3)2BF]– ( 1 a/2 a – 8 a ). The structures of 7 , K[C6H5CH2(CF3)2BF] ( K‐6 a ), and K[C6H5(CF3)2BF] ( K‐8 a ) have been investigated by single‐crystal X‐ray diffraction. In 7 the CF3 groups make short repulsive contacts with NMe3 and C6F5 entities – the B–CF3 bonds being unusually long. The B–F bond lengths of K‐6 a and K‐8 a (1.446(3) and 1.452(2) Å, respectively) are long for a fluoroborate. 相似文献