Effects of fluorescent light and vacuum packaging on the rate of decomposition of pigments in paprika (Capsicum annuum) powder determined by reversed-phase high-performance liquid chromatography.

The effect of storage time, the presence of light and oxygen on the decomposition rate of carotenoid pigments in paprika (Capsicum annuum) powders was determined by reversed-phase high-performance liquid chromatography (RP-HPLC). The similarities and dissimilarities of pigment composition of samples under various storage conditions was elucidated by principal component analysis (PCA) and stepwise regression analysis (SRA). Calculations proved that the overall decomposition rate of pigment sections equally depended on the storage time and on the presence of light and oxygen, the effect of storage time being the most decisive factor while the impact of oxygen was the lowest. The selectivity of decomposition also depended on the storage time and on the presence of oxygen the influence of storage time being the most important. RP-HPLC followed by PCA and SRA can be successfully used for the study of the impact of environmental conditions on the decomposition of carotenoid pigments of paprika powders.     

Novel bis-betaines and betaines within [1(4)]meta-heterophane frameworks

After prior selection of betaine building blocks for the construction of quadrupolar heterophane frameworks, a convergent "3+1" synthetic strategy is reported for the synthesis of the title macrocycles composed of heterocyclic betaine subunit(s). These typify the first example of simple cyclophanes constructed out of both highly pi-excessive and highly pi-deficient heteroaromatic moieties linked in a 1,3-alternating fashion. The chemical reactivity of the quadrupolar heterophanes 1a and 1c toward electrophiles under neutral conditions corroborated their bis-betaine structure. The structural features of the bis-betaines 1, betaines 2 x PF6 and 5 x X, and the corresponding dicationic [1(4)]heterophanes 3 x 2X and 4 x 2Cl were studied by 1H and 13C NMR spectroscopy and electrospray ionization mass spectrometry, and confirmed by single-crystal X-ray diffraction analysis of macrocycles 1a and 2a x PF6.     

Controlling chaos in a satellite power supply subsystem

In this work, we show that chaos control techniques can be used to increase the region that can be efficiently used to supply the power requests for an artificial satellite. The core of a satellite power subsystem relies on its DC/DC converter. This is a very nonlinear system that presents a multitude of phenomena ranging from bifurcations, quasi-periodicity, chaos, coexistence of attractors, among others. The traditional power subsystem design techniques try to avoid these nonlinear phenomena so that it is possible to use linear system theory in small regions about the equilibrium points. Here, we show that chaos control can be used to efficiently extend the applicability region of the satellite power subsystem when it operates in regions of high nonlinearity.     

Risk Taking: Gender Differences and Educational Opportunity

This article focuses on two issues related to educational opportunity: (1) the relationship between risk-taking behavior and mathematics performance, and (2) whether there are gender differences in risk-taking behavior. From a review of literature it was concluded that students who are greater risk-takers perform better on mathematics tests and that males are greater risk-takers than females. It follows, therefore, that males perform better on mathematics tests in which risk-taking plays a role. It was further concluded that these differences effect the opportunities that girls are afforded in their desires to attend college, the availablitity of scholarships, and their self-confidence in mathematics.     

Isobaric volume and enthalpy recovery of glasses. II. A transparent multiparameter theory

A multiordering parameter model for glass-transition phenomena has been developed on the basis of nonequilibrium thermodynamics. In this treatment the state of the glass is determined by the values of N ordering parameters in addition to T and P; the departure from equilibrium is partitioned among the various ordering parameters, each of which is associated with a unique retardation time. These times are assumed to depend on T, P, and on the instantaneous state of the system characterized by its overall departure from equilibrium, giving rise to the well-known nonlinear effects observed in volume and enthalpy recovery. The contribution of each ordering parameter to the departure and the associated retardation times define the fundamental distribution function (the structural retardation spectrum) of the system or, equivalently, its fundamental material response function. These, together with a few experimentally measurable material constants, completely define the recovery behavior of the system when subjected to any thermal treatment. The behavior of the model is explored for various classes of thermal histories of increasing complexity, in order to simulate real experimental situations. The relevant calculations are based on a discrete retardation spectrum, extending over four time decades, and on reasonable values of the relevant material constants in order to imitate the behavior of polymer glasses. The model clearly separates the contribution of the retardation spectrum from the temperature-structure dependence of the retardation times which controls its shifts along the experimental time scale. This is achieved by using the natural time scale of the system which eliminates all the nonlinear effects, thus reducing the response function to the Boltzmann superposition equation, similar to that encountered in the linear viscoelasticity. As a consequence, the system obeys a rate (time) -temperature reduction rule which provides for generalization within each class of thermal treatment. Thus the model establishes a rational basis for comparing theory with experiment, and also various kinds of experiments between themselves. The analysis further predicts interesting features, some of which have often been overlooked. Among these are the impossibility of extraction of the spectrum (or response function) from experiments involving cooling from high temperatures at finite rate; and the appearance of two peaks in the expansion coefficient, or heat capacity, during the heating stage of three-step thermal cycles starting at high temperatures. Finally, the theory also provides a rationale for interpreting the time dependence of mechanical or other structure-sensitive properties of glasses as well as for predicting their long-range behavior.     

Evidence for the two-pole structure of the lambda(1405) resonance

The K- p --> pi0pi0sigma0 reaction is studied within a chiral unitary model. The distribution of pi0sigma0 states forming the lambda(1405) shows, in agreement with a recent experiment, a peak at 1420 MeV and a relatively narrow width of gamma = 38 MeV. The mechanism for the reaction is largely dominated by the emission of a pi0 prior to the K- p interaction leading to the lambda(1405). This ensures the coupling of the lambda(1405) to the K- p channel, thus maximizing the contribution of the second state found in chiral unitary theories, which is narrow and of higher energy than the nominal lambda(1405). This is unlike the pi- p --> K0pisigma reaction, which gives more weight to the pole at lower energy and with a larger width. The data of these two experiments, together with the present theoretical analysis, provide firm evidence of the two-pole structure of the lambda(1405).     

Intrinsic aging and effective viscosity in the slow dynamics of a soft glass with tunable elasticity

We investigate by rheology and light scattering the influence of the elastic modulus, G0, on the slow dynamics and the aging of a soft glass. We show that the slow dynamics and the aging can be entirely described by the evolution of an effective viscosity, eta(eff), defined as the characteristic time measured in a stress relaxation experiment times G0. At all times, eta(eff) is found to be independent of G0, of elastic perturbations, and of the rate at which the sample is quenched in the glassy phase. We propose a simple model that links eta(eff) to the internal stress built up at the fluid-to-solid transition.