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排序方式: 共有189条查询结果,搜索用时 31 毫秒
81.
Cengiz Soykan ükran Güven Ramazan Cokun 《Journal of polymer science. Part A, Polymer chemistry》2005,43(13):2901-2911
82.
Schiff base derivatives have gained great importance due to revealing a great number of biological properties. Schiff bases were synthesized by treatment of 4-amino-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one ( 1 ) with various aldehydes in methanol at reflux. In addition, diamine was reacted with an aldehyde to yield the corresponding Schiff bases. The structures of synthesized Schiff bases were elucidated by spectroscopic methods such as microanalysis, 1H-NMR, 13C-NMR, and FTIR. Antioxidant activities of synthesized Schiff bases were carried out using different antioxidant assays such as 1,1-diphenyl-2-picryl-hydrazyl free radical (DPPH•) scavenging, 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) radical scavenging, and reducing power activity. (E)-4-((1H-indol-3-yl)methyleneamino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one ( 3 ), (E)-1,5-dimethyl-4-((2-methyl-1H-indol-3-yl)methyleneamino)-2-phenyl-1H-pyrazol-3(2H)-one ( 5 ), (E)-1,5-dimethyl-2-phenyl-4-(thiophen-2-ylmethyleneamino)-1H-pyrazol-3(2H)-one ( 7 ), (E)-1,5-dimethyl-2-phenyl-4-(quinolin-2-ylmethyleneamino)-1H-pyrazol-3(2H)-one ( 9 ), (1S,2S,N1,N2)-N1,N2-bis((1H-indol-3-yl)methylene)cyclohexane-1,2-diamine ( 11 ), and (1S,2S,N1,N2)-N1,N2-bis((2-methyl-1H-indol-3-yl)methylene)cyclohexane-1,2-diamine ( 12 ) were synthesized in high yields. Compound 5 displayed a good ABTS•+ activity. Compound 3 revealed the outstanding activity in all assays. Compound 7 has the best-reducing power ability in comparison to other synthesized compounds. Although compounds 5, 11, 12 are new, compounds 3, 7, 9 are known. Due to revealing a good antioxidant activity, the synthesized compounds ( 3, 5, 7 ) have the potential to be used as synthetic antioxidant agents. 相似文献
83.
Five novel 4-phenylquinazolinols were synthesised in three steps. Their application as ligands in the titanium tetraisopropoxide promoted catalytic enantioselective addition of phenylacetylene to a variety of aldehydes gave propargylic alcohols. Under the optimised reaction conditions, the best enantioselectivity was obtained using l-lactic acid derived 4-phenylquinazolinol and apart from the cyclohexylcarbaldehyde derivative, 16 propargylic alcohols were then synthesised in moderate to excellent enantiomeric excess from 53% to 97%. 相似文献
84.
Sertan Alkan Merve Nilay Aydin Ramazan Coban 《Mathematical Methods in the Applied Sciences》2019,42(16):5266-5273
In this paper, the model of an electromechanical system, which is a system of linear differential equations, is studied. Haar wavelet collocation method (HWCM) is applied for finding the approximate solution of the model. HWCM reduces the system of the model into a matrix‐vector form that contains the unknown Haar coefficients, and these coefficients are easily calculated. To demonstrate the validity and applicability of HWCM, numerical solutions of the system for different parameter values in the system are presented. The obtained results demonstrate the efficiency and accuracy of the method. All of the computations are performed via a program written in Mathematica. 相似文献
85.
Ramazan Ozarslan Ahu Ercan Erdal Bas 《Mathematical Methods in the Applied Sciences》2019,42(18):6648-6659
In this article, β‐type fractional Sturm‐Liouville Coulomb operator is considered by Hilfer fractional derivative. Fundamental spectral theory is investigated for the aforementioned problem. In this context, it is shown that the operator is self‐adjoint, eigenfunctions correspond to the distinct eigenfunctions are orthogonal, and eigenvalues are real. Furthermore, applications of this problem are given by the Adomian decomposition method and the results are shown with visual graphs. 相似文献
86.
In the presence of BF3, a series of symmetrical and unsymmetrical ethers reacted with epichlorohydrin and 2‐[(benzyloxy)methyl]oxirane, two terminal epoxides, to afford 1‐alkoxy‐3‐chloropropan‐2‐ol and 1‐alkoxy‐3‐(benzyloxy)propan‐2‐ol. The cleavage of unsymmetrical ethers occurred via an SN2 or SN1 mechanism. Secondary epoxides did not give similar ring‐opening products. 相似文献
87.
Ümmihan Taşkoparan Yilmaz Aysel Kekillioglu Ramazan Mert 《Journal of Analytical Chemistry》2013,68(12):1064-1069
Phenolic compounds possess antioxidant, antitumor, antimutagenic, antibacterial and anticarcinogenic properties. Gallic acid (2,3,4-trihydroxybenzoic acid) is a natural phenolic compound; therefore, determination of trace gallic acid is very important. In this work, a novel, sensitive and reliable method was developed using differential pulse polarography. The most suitable buffer system was found to be Britton-Robinson (B-R) buffer, pH 10.0. The gallic acid peak in this medium appeared at about ?160 mV, it responded well to standard additions, and high reproducibility was obtained. The calibration graph was linear in the concentration range of gallic acid from 1.0–50.0 μM with a correlation coefficient of 0.999. The limit of detection (LOD) and limit of quantification (LOQ) were obtained as 0.3 and 1.0 μM, respectively. The proposed method was successfully applied to the determination of gallic acid in fruit juices. The influences of some other commonly found inorganic and organic salts on the determination were also examined. Some interferiences were eliminated by using complexing agents, e.g. EDTA. 相似文献
88.
We prove some direct and converse theorems of trigonometric approximation in weighted Orlicz spaces with weights satisfying
so called Muckenhoupt’s A
p
condition. 相似文献
89.
In this study, a platinum electrode was coated with NiZn layer (Pt/NiZn) in a nickel-zinc bath by electrodeposition for use
as anode material for methanol electrooxidation in alkaline solution. The electrode prepared was etched in a concentrated
alkaline solution (30% NaOH) to produce a porous and electrocatalytic surface suitable for use in the methanol electrooxidation
(Pt/NiZn). The surface morphologies and compositions of coating before and after alkaline leaching were determined by energy
dispersive X-ray (EDX) and scanning electron microscopy (SEM) techniques. The effect of NiZn coated platinum electrode for
methanol electrooxidation was investigated in 1 M NaOH solution by cyclic voltammetry (CV) and electrochemical impedance spectroscopy
(EIS) techniques. Methanol electrooxidation on Pt/NiZn electrode was studied at various temperatures and potential scan rates.
The results showed that Pt/NiZn electrode behaved as an efficient catalyst for the electrooxidation of methanol in alkaline
medium. 相似文献
90.
Nuraje N Asmatulu R Cohen RE Rubner MF 《Langmuir : the ACS journal of surfaces and colloids》2011,27(2):782-791
Mechanically durable, long-lasting antifog coatings based on polysaccharides were developed using a layer-by-layer (LBL) assembly process. The unique properties of these coatings are a result of a molecular-level blending of the polysaccharides, with multilayers containing chitosan and carboxymethyl cellulose providing the best overall properties. The antifog properties resulted from a strong interaction between the polar and H-bonding elements of the assembled polymers and water molecules and the concomitant formation of thin films of water. Environmental scanning electron microscopy (ESEM) studies confirmed that fogging coatings are decorated with light scattering, micrometer-sized droplets of water whereas antifogging coatings remain droplet free. To improve the mechanical durability of the multilayer films on substrates, the surface was modified via self-assembly of epoxy-functionalized silane molecules. Cross-linking chemistry was then applied to improve the mechanical robustness of the LBL films on various surfaces. These films were characterized using several techniques: optical profilometery (PL), spectroscopic ellipsometry (EL), contact angle goniometry (CA), and atomic force microscopy (AFM). The antifog properties of the films were evaluated by several tests under different environmental conditions. This work demonstrates that the unique water-adsorbing properties of polysaccharides can be exploited to create permanent antifog properties, which may be useful for various applications. 相似文献