A New Approach to the Exact Solutions of the Effective Mass Schrödinger Equation

Effective mass Schrödinger equation is solved exactly for a given potential. Nikiforov-Uvarov method is used to obtain energy eigenvalues and the corresponding wave functions. A free parameter is used in the transformation of the wave function. The effective mass Schrödinger equation is also solved for the Morse potential transforming to the constant mass Schrödinger equation for a potential. One can also get solution of the effective mass Schrödinger equation starting from the constant mass Schrödinger equation.     

Cyclic alkenenitriles: chemoselective oxonitrile cyclizations

Potassium tert-butoxide triggers the chemoselective cyclization between nitrile anions and remote, enolizable carbonyl groups, despite the acidity difference favoring enolate formation and addition to the nitrile group. Domino deprotonation, cyclization, and dehydration efficiently transform a diverse array of omega-oxonitriles into carbocyclic and heterocyclic five- and six-membered alkenenitriles in a single synthetic operation.     

The removal of textile dyes by diatomite earth

The adsorption of some textile dyes by diatomite was investigated using Sif Blau BRF (SB), Everzol Brill Red 3BS (EBR), and Int Yellow 5GF (IY). Adsorption of these textile dyes onto diatomite earth samples was studied by batch adsorption techniques at 30 degrees C. The adsorption behavior of textile dyes on diatomite samples was investigated using a UV-vis spectrophotometric technique. The effect of particle size of diatomite, diatomite concentration, the effect of initial dye concentrations, and shaking time on adsorption was investigated. Adsorption coverage over the surface of diatomite was studied using two well-known isotherm models: Langmuir's and Freundlich's. These results suggest that the dye uptake process mediated by diatomite has a potential for large-scale treatment of textile mill discharges. According to the equilibrium studies, the selectivity sequence can be given as IY > SB > EBR. Values of the removal efficiency of the dyes ranged from 28.60 to 99.23%. These results show that natural diatomite holds great potential to remove textile dyes from wastewater.     

Light-activated hybrid organic/inorganic antimicrobial coatings

Light-activated antimicrobial coatings were obtained by the covalently immobilizing photo-sensitizers in a hybrid organic/inorganic matrix. These coatings were deposited via sol-gel chemistry using epoxy and methyl functional silanes. The light-activated chromophores used in this study were Methylene Blue, Toluidine Blue O, and Rose Bengal. The immobilized photo-sensitizers did not leach from the coatings. The mechanically durable hybrid coatings comprising 2.5% by weight of Rose Bengal had a good adhesion to the glass surface. These coatings were tested for the photo-deactivation of Escherichia coli and Staphylococcus aureus using illumination by a commercial fluorescent lamp. Log reduction of E. coli and S. aureus were >4 when illuminated by the fluorescent lamp in 1 and 3?h, respectively. Due to its high mechanical durability and chemical resistance, such light-activated hybrid coatings are promising candidates for indoor applications in healthcare facilities.

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Heavy-quark bound states in potentials with the Bethe-Salpeter equation

The spinless Bethe—Salpeter equation is solved for three attractive static quark-antiquark potentials of the form V(r)=–ar^–+br+c, 01, and the effective non-Coulombic power-law potential of the formV(r)=ar ^0.1+c to obtain the spin-averaged energy levels in bottomonium (b ) and charmonium (c ) families. The shifted 1/N expansion technique is used. Calculations of the energy eigenvalues are carried out up to third order and parameters of each potential are adjusted to obtain the best agreement with the experimental spin-averaged data (SAD). Flavor-dependent and flavor-independent cases are considered in this work.     

Improvement of Thermostability and Activity of Firefly Luciferase Through [TMG][Ac] Ionic Liquid Mediator

Firefly luciferase catalyzes production of light from luciferin in the presence of Mg²⁺?CATP and oxygen. This enzyme has wide range of applications in biotechnology and development of biosensors. The low thermal stability of wild-type firefly luciferase is a limiting factor in most applications. Improvements in activity and stability of few enzymes in the presence of ionic liquids were shown in many reports. In this study, kinetic and thermal stability of firefly luciferase from Photinus pyralis in the presence of three tetramethylguanidine-based ionic liquids was investigated. The enzyme has shown improved activity in the presence of [1, 1, 3, 3-tetramethylguanidine][acetate], but in the presence of [TMG][trichloroacetate] and [TMG][triflouroacetate] activity, it decreased or unchanged significantly. Among these ionic liquids, only [TMG][Ac] has increased the thermal stability of luciferase. Incubation of [TMG][Ac] with firefly luciferase brought about with decrease of K _m for ATP.     

A new bis(azine) tetradentate ligand and its transition metal complexes: Synthesis,characterisation, and extraction properties

A new bis(bidentate) azine ligand was prepared by linking (1Z,1′Z)-1,1′-{butane-1,4-diylbis[oxybenzene-4,1-diyl(1Z)ethyl-1-ylidene]}dihydrazine to salicylaldehyde. Two kinds of binuclear copper(II) and nickel(II) complexes with different stoichiometries were prepared. Reaction of bis(azine) ligand with Cu(II) and Ni(II) acetate at a 1: 1 mole ratio gave double-stranded binuclear bis(azine) complexes with stoichiometry [M(L)(H₂O)₂]₂ containing [M(II)N₂O₂] centres while at a 2: 1 mole ratio, reaction of Cu(II) and Ni(II) chloride with bis(azine) resulted in dinuclear metal complexes with the general stoichiometry [M₂(L)Cl₂(H₂O)₂]. Structures of the bis(azine) ligand and its complexes were identified by elemental analysis, IR and UV-VIS spectra, magnetic susceptibility measurements, TGA, and powder XRD. Extraction properties of the bis(azine) ligand towards some transition metal cations and dichromate anions were also reported. It was found that the bis(azine) ligand does not extract cations but it has high extraction ability towards dichromate anions.     

Approximate Analytical Solutions of Dirac Equation with Spin and Pseudo Spin Symmetries for the Diatomic Molecular Potentials Plus a Tensor Term with Any Angular Momentum

Approximate analytical solutions of the Dirac equation are obtained for some diatomic molecular potentials plus a tensor interaction with spin and pseudospin symmetries with any angular momentum. We find the energy eigenvalue equations in the closed form and the spinor wave functions by using an algebraic method. We also perform numerical calculations for the Pöschl-Teller potential to show the effect of the tensor interaction. Our results are consistent with ones obtained before.     

Non-central potentials,exact solutions and Laplace transform approach

Exact bound state solutions and the corresponding wave functions of the Schrödinger equation for some non-central potentials including Makarov potential, modified-Kratzer plus a ring-shaped potential, double ring-shaped Kratzer potential, modified non-central potential and ring-shaped non-spherical oscillator potential are obtained by using the Laplace transform approach. The energy spectrums of the Hartmann potential, modified-Kratzer potential and ring-shaped oscillator potential are also briefly studied as special cases. It is seen that our analytical results for all these potentials are consistent with those obtained by other works. We also give some numerical results obtained for the modified non-central potential for different values of the related quantum numbers.