Octahedral metallo-mesogens of chromium, molybdenum and tungsten with 1,4,7-trisubstituted 1,4,7-triazacyclononane and three carbonyl groups as ligands

Liquid crystalline complexes with chromium, molybdenum and with tungsten as metallic centres are reported. 1,4,7-Trisubstituted 1,4,7-triazacyclononane and three carbonyl groups are coordinated in an octahedral geometry. The observed mesophases are characterized as disordered rectangular columnar of a pyramidic type.     

Band structures in73Se

Excited states of⁷³Se have been investigated up to spin, 21/2 using techniques of in-beamγ-ray spectroscopy in connection with the⁷⁰Ge(α, n) reaction. Mean lifetimes of 12 levels have been determined applying Doppler-shift andγ-RF-methods. Five different bands have been identified that reflect a variety of different excitation modes. The decoupled 9/2⁺ band is likely to correspond to an oblate deformation while the 5/2⁺ band is interpreted as a strongly coupled prolate band built on the Nilsson configuration [422] 5/2⁺. The 3/2^? band is a strongly coupled band built on the [301] 3/2^} configuration.Nuclear reactions:⁷⁰Ge(α,n),E=14, 16, 18, 19, 20MeV; measuredE _γ,I _γ,σ(E _γ,θ),γγ-coin, linear polarization, DSA,γ(t).⁷⁵Se deduced levels,I, π, τ, δ(E2/M1), B(σλ). Enriched targets, Ge detectors.     

Cogenerators for convex spaces

We give cogenerators for the categories of convex (= finitely superconvex), finitely positively convex, and absolute convex (= finitely totally convex) spaces introduced by Pumplün and Röhrl.Dedicated to our academic teacher Dieter Pumplün on the occasion of his sixtieth birthday.     

Evaluation of quadrature schemes for the discrete ordinates method

After reviewing the presently available quadrature schemes for the discrete ordinates method, the accuracy of different schemes is analyzed and evaluated. It is shown from a comprehensive error analysis that the moment conditions have to satisfied not only for the principal coordinates directions, as it is mostly carried out, but for any arbitrary test direction. Among the schemes with approximately 50 discrete ordinates the DCT-020-2468 quadrature was found to give the best accuracy. The highest accuracy among all schemes is achieved by the LC-11 quadrature which requires 96 discrete ordinates. This scheme is rarely used up to date and deserves more attention for high accuracy predictions.     

Zur gewichtsanalytischen Bestimmung des Mangans

Ohne Zusammenfassung     

Behavioral therapy for spasmodic dysphonia

This paper presents a general schema for classifying treatment approaches for both functional and organic voice disorders. It's use is illustrated by a review of treatments for Spasmodic Dysphonia. Most behavioral approaches have been found to be unsuccessful except for mild cases. Inhalation speech as a compensatory technique has been reported as somewhat successful for those mild/moderate cases for whom medical/surgical treatment has not been available. The fact that organic treatment levels have been more successful in the treatment of Spasmodic Dysphonia may lend support to an organic etiology