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61.
Neodymium doped bismuth layer structure ferroelectrics (BLSFs) ceramics CaBi4−xNdxTi4O15 (x=0, 0.25, 0.50, 0.75) were prepared by solid-state reaction method. X-ray diffraction pattern showed that single phase was formed when x=0-0.75. The refined lattice parameters showed that a (b) axes decrease at x=0.25 and increase with more Nd3+ dopant. The effects of Nd3+ doping on the dielectric and ferroelectric properties of CaBi4Ti4O15 ceramics are studied. Nd3+ dopant decreased the Curie temperature linearly, and the dielectric loss, tan δ, as well. The remnant polarization of Nd3+ doped CaBi4Ti4O15 ceramics was increased by 80% at x=0.25, while more Nd3+ dopant decreased the remnant polarization. CaBi3.75Nd0.25Ti4O15 ceramics had the largest piezoelectric constant d33. The structure and properties of CaBi4−xNdxTi4O15 ceramics showed that Nd3+ may occupy different crystal locations when Nd3+ content x is less than 0.25 and more than 0.50. 相似文献
62.
Deposition of Hydrogen-Free Silicon Nitride Thin Films by Microwave ECR plasma Enhanced Magnetron Sputtering at Room Temperature 下载免费PDF全文
Hydrogen-free silicon nitride (SiNx) films were deposited at room temperature by microwave electron cyclotron resonance (MW-ECR) plasma enhanced unbalance magnetron sputtering system. Both Fourier-transform infrared spectroscopy and x-ray photoelectron spectroscopy are used to study the bonding type and the change of bonding structures of the silicon nitride films. The results indicate that the chemical structure and composition of SiNx films deposited by this technique depend strongly on the N2 flow rates, the stoichiometric SiNx film, which has the highest hardness of 22.9 GPa, could be obtained at lower N2 flow rate of 4 sccm. 相似文献
63.
The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArN?C(Me)C(Me)?NAr]NiCl}2[Ar?2,6?C6H3(i‐Pr)2] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N2Cl2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
64.
65.
ZhongJunMA XianLI YangLU ChengWANG QiTaiZHENG 《中国化学快报》2003,14(6):594-596
A novel cycloartane,named sphaerophysone A,9,19-cycloart-7β,24β,25-triol-1-en-3-one,was isolated from the ethanol extract of Sphaerophysa salsula DC.The structure was elucidated on the basis of spectral evidences and confirmed by X-ray analysis,the stereochemistry of the compound was also defined by X-ray analysis. 相似文献
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67.
室温下,通过双核配合物[Cu(dppm)(NO3)]2(dppm=双二苯基膦甲烷)与四苯基硼钠在甲醇和二氯甲烷混合溶剂中反应制备了三核铜(I)配合物[Cu3(dppm)3(NO3)(OH)](NO3),经过红外光谱、热重分析、核磁和ES-MS等现代分析手段表征了配合物的物理化学性质,并进一步研究了配合物在室温下的荧光光谱特征。 相似文献
68.
D. Liu N.Q. Ngo X.Y. Dong S.C. Tjin P. Shum 《Applied physics. B, Lasers and optics》2005,81(6):807-811
We propose and experimentally demonstrate a stable dual-wavelength erbium-doped polarization-maintaining (PM) fiber laser
with tunable wavelength spacing using an all-PM linear cavity that makes use of two reflection peaks from the PM fiber Bragg
grating (PM-FBG). Experimental results show stable dual lasing lines with a wavelength separation of ∼0.22 nm and a large
optical signal-to-noise ratio (OSNR) of over 40 dB under room temperature. By applying axial strain to the PM-FBG, the center
wavelengths of the two lasing lines can be tuned over several nanometers and the wavelength separation between the lasing
lines can also be tuned to as small as 0.05 nm, which, to our knowledge, is the smallest wavelength spacing ever obtained
from a stable room-temperature dual-wavelength fiber laser. The proposed laser configuration has the advantages of simple
structure, low loss, stable dual-wavelength operation and a very small lasing linewidth of ∼5 kHz .
PACS 42.55.Wd; 42.81.-i; 42.81.Gs 相似文献
69.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
70.