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121.
Diethyl Fluoronitromethylphosphonate: Synthesis and Application in Nucleophilic Fluoroalkyl Additions 下载免费PDF全文
Stanislav Opekar Dr. Radek Pohl Pavel Beran Dr. Lubomír Rulíšek Dr. Petr Beier 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(5):1453-1458
Diethyl fluoronitromethylphosphonate ( 3 ), a previously unknown compound, was synthesized by electrophilic fluorination of diethyl nitromethylphosphonate with Selectfluor. Base‐induced decomposition of 3 was studied by NMR spectroscopy, which identified diethyl fluorophosphate and fluoronitromethane as the main decomposition products. C?H acidities [pKa values in dimethyl sulfoxide (DMSO)] of 3 , 1‐fluoro‐1‐phenylsulfonylmethanephosphonate ( 1 ; McCarthy’s reagent), tetraethyl fluoromethylenebisphosphonate ( 2 ), and some nonfluorinated phosphonates were computed, and a good correlation between calculated and experimental pKa values was found. The calculated C?H acidities increased in the sequence 2 < 1 < 3 . Diethyl fluoronitromethylphosphonate ( 3 ) was applied in the Horner–Wadsworth–Emmons reaction with aldehydes and trifluoromethyl ketones to provide new 1‐fluoro‐1‐nitroalkenes with good to high stereoselectivities. Alkylation of 3 was successful only with iodomethane, however, conjugate additions of 3 to Michael acceptors such as α,β‐unsaturated carbonyl compounds, sulfones, and nitro compounds allowed access to variously modified diethyl 1‐fluoro‐1‐nitrophosphonates. 相似文献
122.
The origin of symmetry breaking (SB) in benzene in generalized valence bond methods is investigated within a coupled cluster formalism that correlates all valence electrons. Retention of a limited number of pair correlation amplitudes (as in the perfect- and imperfect-pairing models) that incompletely describes interpair correlations leads to symmetry breaking as the orbitals and amplitudes are optimized. Local correlation models that are exact for one, two, and three interacting pairs at the doubles excitation level are compared against the exact pair correlation treatment, which correlates four interacting pairs at once in the connected double substitution operator. For simplicity, this comparison is performed with a second-order model of electron correlation, which is reasonably faithful to the infinite-order result. The significant SB known for the one-pair model (perfect pairing) is not eliminated at the two-pair level, but is virtually eliminated at the three-pair level. Therefore, a tractable hybrid model is proposed, which combines three-pair correlations at the second-order level and infinite-order treatment for the strong imperfect-pairing correlations involving one and two-pair correlations. This model greatly reduces SB in benzene and larger delocalized pi systems such as naphthalene and the phenalenyl cation and anion. The resulting optimized orbitals are localized in the sigma space but exhibit significant delocalization in the pi space. This means that correlation effects associated with different resonance structures are treated in a more balanced way than if the pi orbitals localize, leading to reduced SB. 相似文献