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排序方式: 共有355条查询结果,搜索用时 15 毫秒
81.
Sadati Sorkhi Seyyed Erfan Hashemi Mohammad M. Ezabadi Ali 《Research on Chemical Intermediates》2020,46(4):2229-2246
Research on Chemical Intermediates - A novel dicationic Brönsted acidic ionic liquid based on pyrazine has been prepared and characterized by FTIR, 1H NMR, 13C NMR, MS, thermal gravimetric and... 相似文献
82.
A kinetic spectrophotometric method for the determination of trace amounts of Ag(I) in the range of 2–20 ng mL–1 is reported. The method is based on the catalytic effect of Ag(I) on the oxidation reaction of fuschin by potassium peroxodisulfate in the presence of 1,10-phenanthroline as an activator at pH = 5. The reaction is followed spectrophotometrically by measuring the change in absorbance (A) at 544 nm using a fixed time method (6 min). The reaction variables were optimized in order to achieve the highest sensitivity. The 3s criterion detection limit was 0.7 ng mL–1, and the relative standard deviation for ten replicate measurements of 16 ng mL–1 of Ag(I) was 0.95% (n = 10). The method was successfully applied to the determination of silver in expired black and white photographic films and results showed good agreements with those obtained by atomic absorption spectrometry. 相似文献
83.
Mohammed M. Hashemi Yusef Ahmadibeni Hossien Ghafuri 《Monatshefte für Chemie / Chemical Monthly》2003,134(1):107-110
Summary. Hydrogen peroxide readily oxidizes Hantzsch type 1,4-dihydropyridines in the presence of cobalt(II) acetate as catalyst at room temperature. No evidence of a dealkylation
process for 4-alkyl 1,4-dihydropyridines has been observed.
Corresponding author. E-mail: mhashemi@sharif.ac.ir
Received January 16, 2002; accepted (revised) April 20, 2002 相似文献
84.
Mohammed M. Hashemi Hossein Ghafuri Zahed Karimi-Jaberi 《Monatshefte für Chemie / Chemical Monthly》2006,137(2):197-200
Summary. Various alkyl, aryl, and heterocyclic Hantzsch 1,4-dihydropyridines were converted to the corresponding pyridines in excellent yields and short times using sodium nitrite
in the presence of a catalytic amount of acidic silica gel at room temperature. 相似文献
85.
P. Hashemi M. M. Abolghasemi A. R. Fakhari S. N. Ebrahimi S. Ahmadi 《Chromatographia》2007,66(3-4):283-286
A new, simple hydrodistillation–solvent microextraction (HD–SME) technique has been used for analysis of the volatile components
of the aerial parts of Artemisia aucheri. The components were collected in a single microdrop, and this was injected directly for gas chromatographic–mass spectrometric
(GC–MS) analysis. The effects on extraction efficiency of extraction solvent, sample mass, microdrop volume, and extraction
time were optimized by use of a simplex method. The identities of the components of HD–SME extracts were confirmed according
to their retention indexes and mass spectra with those of standards. Forty components were extracted and identified by use
of the method; 1,8-cineol (22.8%), chrysanthenone (18.16%), α-pinene (8.33%), and mesitylene (7.41%) were the major constituents.
The results obtained from the microextraction method were compared with those obtained by conventional hydrodistillation. 相似文献
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89.
Oximes were oxidized to the corresponding carbonyl compounds in good to high yields by environmentally friendly and green oxidant,H_2O_2 catalyzed by montmorillonite K-10 supported cobalt(Ⅱ) chloride. 相似文献
90.
Tunable N‐doped carbon nanospheres from sucrose as carbon source and Tris(2‐aminoethyl)amine (TAEA) as nitrogen source by a simple and easily reproducible method were prepared. It was demonstrated that the tunable N‐doping of carbon spheres could be realized by altering the ratio of TAEA in the raw materials. The content of doped nitrogen, surface area, pore volume and pore size of carbon nanospheres were increased with the increasing of TAEA amount in the hydrothermal process. Prepared N‐doped carbon nanospheres act as solid ligand for anchoring of Ag NPs which generated via chemical reduction of Ag ions. Benzylic alcohols and aldehydes were converted into the aryl nitriles by using Ag/N‐CS‐1 nanospheres as the catalyst and O2 as the oxidant, efficiently. This catalyst was stable and could use for 6 successful runs. 相似文献