全文获取类型
收费全文 | 84篇 |
免费 | 3篇 |
专业分类
化学 | 59篇 |
数学 | 5篇 |
物理学 | 23篇 |
出版年
2023年 | 2篇 |
2021年 | 1篇 |
2020年 | 2篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2016年 | 3篇 |
2014年 | 3篇 |
2013年 | 1篇 |
2012年 | 7篇 |
2011年 | 3篇 |
2010年 | 1篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 4篇 |
2006年 | 5篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 6篇 |
2002年 | 1篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 3篇 |
1989年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1973年 | 4篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1970年 | 2篇 |
排序方式: 共有87条查询结果,搜索用时 312 毫秒
51.
A systematic computational study of the dynamics of gas bubbles rising in a viscous liquid is presented. Two-dimensional simulations are carried out. Both the dynamics of single bubbles and small groups of bubbles (bubble swarms) are considered. This is a continuation of our previous studies on the two-bubble coalescence and vortex shedding [A. Smolianski, H. Haario, P. Luukka, Vortex shedding behind a rising bubble and two-bubble coalescence: a numerical approach, Appl. Math. Model. 29 (2005) 615–632]. The proposed numerical method allows us to simulate a wide range of flow regimes, accurately capturing the shape of the deforming interface of the bubble and the surface tension effect, while maintaining the mass conservation. The computed time-evolution of bubble’s position and rise velocity shows a good agreement with the available experimental data. At the same time, the results on the dynamics of bubble interface area, which are, up to our knowledge, presented for the first time, show how much the overall mass transfer would be affected by the interface deformation in the case of the bubble dissolution. Another set of experiments that are of interest for chemical engineers modelling bubbly flows concerns the bubble swarms and their behavior in different bubble-shape regimes. The ellipsoidal and spherical shape regimes are considered to represent, respectively, the coalescing and non-coalescing bubble swarms. The average rise velocities of the bubble swarms are computed and analyzed for both regimes. 相似文献
52.
Yrjönen Teijo Haansuu Johannes Pasi Haahtela Kielo Vuorela Heikki Vuorela Pia 《平面色谱法杂志一现代薄层色谱法》2001,14(1):47-52
JPC – Journal of Planar Chromatography – Modern TLC - The aim of this study was to find suitable separation conditions for the rapid screening of indole derivatives in bacterial culture... 相似文献
53.
54.
Antti Laakso Mihail Dumitrescu Pasi Pietilä Mikko Suominen Markus Pessa 《Optical and Quantum Electronics》2008,40(11-12):853-861
The paper presents a simple and efficient Mode-Solver-based method for determining the ridge profile that ensures stable single-transverse-mode operation in ridge waveguide lasers. A quantitative figure of merit, easily derived from the Mode Solver analysis of the structure, indicates the likelihood of single transverse modal behavior over the whole bias range. The transverse mode analysis performed with the in-house developed software has been compared with the results of the commercial simulation package LASTIP and with experiments. The simulation and experimental results have been used to derive processing guidelines for achieving a stable single-transverse-mode operation in ridge waveguide lasers. 相似文献
55.
56.
Two novel peptide scaffolds, viz. cyclo[(N(alpha)-Alloc)Dpr-beta-Ala-(N(alpha)-Fmoc)Dpr-beta-Ala] (1) and cyclo[(N(alpha)-Alloc)Dpr-alpha-azido-beta-aminopropanoyl-(N(alpha)-Fmoc)Dpr-beta-Ala] (2), composed of orthogonally protected 2,3-diaminopropanoyl (Dpr) and beta-alanyl residues, have been described. Fmoc chemistry on a backbone amide linker derivatized resin has been used for the chain assembly. Selective removal of the 4-methyltrityl (Mtt) and 1-methyl-1-phenylethyl protections (PhiPr) exposes the beta-amino and carboxyl terminus, respectively, and on-resin cyclization then gives the desired orthogonally protected cyclo-beta-tetrapeptides (1 and 2). The alpha-amino groups, bearing the Fmoc and Alloc protections and the azide mask, allow stepwise orthogonal derivatization of these solid-supported cyclo-beta-tetrapeptide cores (1 and 2). This has been demonstrated by attachments of various sugar units [viz., acetyl- or toluoyl-protected carboxymethyl alpha-d-glycopyranosides (13-15) and methyl 6-O-(4-nitrophenoxycarbonyl)-alpha-d-glycopyranosides (22-24)] to obtain diverse di- and trivalent glycoclusters (33-42). Acidolytic release (TFA) from the support, followed by conventional NaOMe-catalyzed transesterification (33-40) or hydrazine-induced acyl substitution in DMF (41 and 42), gives the fully deprotected clusters (43-52) as final products. 相似文献
57.
Holappa J Nevalainen T Safin R Soininen P Asplund T Luttikhedde T Másson M Järvinen T 《Macromolecular bioscience》2006,6(2):139-144
Novel synthesis methods for the preparation of quaternary piperazine derivatives of chitosan were developed. Quaternary ammonium moiety can be selectively inserted into either one or both of the piperazine nitrogens, yielding structurally uniform chitosan derivative structures. Water-soluble end products were thoroughly characterized with FT-IR, 1H NMR, 13C NMR and 2D 1H-13C HSQC NMR. The molecular weights of the end products were determined by GPC with triple detection. 相似文献
58.
Kiviniemi T Aumanen J Myllyperkiö P Apkarian VA Pettersson M 《The Journal of chemical physics》2005,123(6):64509
Time-resolved coherent anti-Stokes Raman-scattering (CARS) measurements are carried out for iodine (I2) in solid krypton matrices. The dependence of vibrational dephasing time on temperature and vibrational quantum number v is studied. The v dependence is approximately quadratic, while the temperature dependence of both vibrational dephasing and spectral shift, although weak, fits the exponential form characteristic of dephasing by pseudolocal phonons. The analysis of the data indicates that the frequency of the pseudolocal phonons is approximately 30 cm(-1). The longest dephasing times are observed for v = 2 being approximately 300 ps and limited by inhomogeneous broadening. An increase in the dephasing rate of v = 2 as the temperature is lowered to T = 2.6 K is taken as a clear indication of lattice-strain-induced inhomogeneity of the ensemble coherence. 相似文献
59.
60.
Levänen E Mäntylä T Mikkola P Rosenholm JB 《Journal of colloid and interface science》2001,236(1):28-34
The effect of divalent and trivalent salts (CaCl(2), CaBr(2), MgCl(2), MgBr(2), LaCl(3), CeCl(3), La(NO(3))(3), and Ce(NO(3))(3)) on the micelle formation in C(8)-lecithin solutions was investigated using the techniques of static and dynamic light scattering. The critical micelle concentration (cmc), mean hydrodynamic radius (R(h)), gyration radius (R(g)), and weight-average molecular weight of the micelles were measured as functions of salt identity and concentration, amphiphile concentration, and temperature. It was found that the micelles in solutions of magnesium are less likely to form and less stable; their standard enthalpy is less exothermic as the ionic strength increases. On the contrary, the micelles in solutions of calcium and trivalent salts form easily, and are more stable; their standard enthalpy is also more exothermic as the ionic strength increases. Based on our model of the Gibb's free energy for the salt-added solutions, we obtained the following formula for the effect of salts on cmc: ln(cmc)'=ln(cmc)+k(1) I(1/2)+k(2)I, where (cmc)' and (cmc) are the critical micelle concentrations in salt-added and salt-free solutions, respectively, I is the ionic strength, and k(1) and k(2) are the salt effect parameters. The agreement between the formula and the experimental data for all the systems under study shows that the formula is more satisfactory than those suggested previously by other authors in describing the effect of salts on the cmc in the micellar solutions of not only zwitterionic but also nonionic surfactants. Copyright 2001 Academic Press. 相似文献