Combined supercritical-fluid chromatography/mass spectrometry in the analysis of diuron in plasma using on-line phase-system switching

On-line sample pretreatment by means of the phase-system switching approach is an interesting technique for the analysis of aqueous samples, e.g., plasma, by means of supercritical-fluid chromatography. In order to analyse plasma samples the following analytical procedure is used. The plasma sample is injected on to a short precolumn, which is washed with water and subsequently dried with nitrogen. Next, the solutes are desorbed with the supercritical mobile phase, analysed with packed-column supercritical-fluid chromatography and detected with either a UV detector or a mass spectrometer, equipped with a moving-belt interface. The herbicide diuron is selected as a test compound to study the feasibility of this approach. Using a selective detector the procedure is sufficiently sensitive to detect diuron in plasma, but not appropriate to detect the diuron metabolites in a post-mortem plasma sample. These have been identified with liquid chromatography/mass spectrometry. The detection limit of diuron in plasma using the procedure described is about 30 ng/mL.     

Control of small phase arrays to form a prescribed amplitude-phase distribution

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 32, No. 9, pp. 1132–1136, September, 1989.     

On the condensate values in QCD

Conclusions The sets (3) and (4) of condensates have been compared using the QCD sum rules (2) with indefinite weight functions. A bad matching between both sets of condensates and experimental data has been obtained. The standard values (3) appear to be closer to data but some increase ofQ is necessary to improve the agreement. Only higher values ofm ₀ ² could change the results of this analysis. It is interesting that negative values ofm ₀ ² considerably improve the agreement with data; note that this quantity cannot be determined with a sufficient accuracy. We conclude that the QCD sum rules (2) cannot definitely determine a privileged set of condensates.Dedicated to Academician Václav Votruba on the occasion of his eightieth birthday.     

Spectral features of laser induced plasma from YBa2Cu3O7 and GdBa2Cu3O7 highT c superconductors

Laser induced plasma emission spectra from highT _c superconducting samples of YBa₂Cu₃O₇ and GdBa₂Cu₃O₇ obtained with 1.06μm radiation from a Q switched Nd:YAG laser beam has been analysed. The results clearly show the presence of diatomic oxides in addition to ionized species of the constituent metals in the plasma thus produced.     

Anomalies of ultrasonic velocity in high-Tc ceramics YBa2Cu3Oy and BiSrCaCu2Oy

Ultrasonic longitudinal velocity and adsorption have been measured in ceramic superconductors YBa₂Cu₃O_y with various porosity and also in BiSrCaCu₂O_y. A velocity drop of about 400 ppm was found at T_c only in the measurements on cooling. The magnitude of the velocity drop is anomalously large compared with the value expected from the thermodynamics. A hysteresis of velocity with respect to temperature was observed in all the samples studied. It is suggested that some structural change at pore size level is responsible for this phenomenon.     

Low-frequency internal friction in complex composite strands

Conclusion A method was proposed which makes it possible to study the low-frequency internal friction of complex fibers. This method was used to study the internal friction of complex composite fibers based on PCA and PE. We observed a relaxation process which is typical of the composite and is absent in the pure materials.Translated from Mekhanika Kompozitnykh Materialov, No. 1, pp. 11–15, January–February, 1989.     

Effect of rare-earth oxides on the magnetic properties of anisotropic barium ferrites

The effect of rare-earth oxides on the properties of anisotropic barium ferrites has been studied by x-ray structural and Mössbauer methods. Additions of SrCO₃, as well as SrCO₃ and La₂O₃, SrCO₃ and Pr₆O₁₁, SrCO₃ and Nd₂O₃, SrCO₃ and Sm₂O₃ in amounts of 7.5 mole % Sr and 10 mole % rare-earth element to grade-A barium powder results in the substitution of barium ions by Sr and rare-earth ions; consequently, the energy of magnetic anisotropy changes and the technically important parameters B_r and (BH)_max increase.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 34–39, January, 1989.     

The spectrum of Nd in rare earth orthoaluminates. The trigonal to orthorhombic transition study of the level

Some structural and spectroscopic features of rare earth orthoaluminates are examined.The trigonal→ orthorhombic transition is studied in a series of Nd_xSm_1−xAlO₃ compounds. The evolution of the crystal structure is followed by X-ray analysis and optical absorption. The free ion and crystal field parameters of Nd³⁺ (4f³ configuration) are determined in LuAlO₃:Nd³⁺.The anomaly of the calculated splitting of the levels is slight, but well characterized in NdAlO₃. The spin correlated crystal field and orbitally correlated crystal field models are tested as well as an empirical correction which was proposed earlier.