全文获取类型
收费全文 | 3800篇 |
免费 | 183篇 |
国内免费 | 18篇 |
专业分类
化学 | 2798篇 |
晶体学 | 31篇 |
力学 | 118篇 |
综合类 | 1篇 |
数学 | 579篇 |
物理学 | 474篇 |
出版年
2023年 | 38篇 |
2022年 | 26篇 |
2021年 | 56篇 |
2020年 | 89篇 |
2019年 | 76篇 |
2018年 | 45篇 |
2017年 | 44篇 |
2016年 | 145篇 |
2015年 | 133篇 |
2014年 | 147篇 |
2013年 | 193篇 |
2012年 | 246篇 |
2011年 | 290篇 |
2010年 | 172篇 |
2009年 | 141篇 |
2008年 | 226篇 |
2007年 | 229篇 |
2006年 | 218篇 |
2005年 | 196篇 |
2004年 | 171篇 |
2003年 | 127篇 |
2002年 | 142篇 |
2001年 | 79篇 |
2000年 | 79篇 |
1999年 | 67篇 |
1998年 | 47篇 |
1997年 | 32篇 |
1996年 | 35篇 |
1995年 | 42篇 |
1994年 | 37篇 |
1993年 | 30篇 |
1992年 | 25篇 |
1991年 | 41篇 |
1990年 | 35篇 |
1989年 | 27篇 |
1987年 | 17篇 |
1985年 | 16篇 |
1984年 | 17篇 |
1983年 | 14篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 21篇 |
1979年 | 15篇 |
1978年 | 14篇 |
1977年 | 24篇 |
1976年 | 12篇 |
1975年 | 15篇 |
1974年 | 11篇 |
1973年 | 9篇 |
1972年 | 10篇 |
排序方式: 共有4001条查询结果,搜索用时 15 毫秒
21.
22.
Kochocki JA Allison WW Alner GJ Ambats I Ayres DS Balka LJ Barr GD Barrett WL Benjamin D Border P Brooks CB Cobb JH Cockerill DJ Coover K Courant H Dahlin B DasGupta U Dawson JW Edwards VW Fields TH Kirby-Gallagher LM Garcia-Garcia C Giles RH Goodman MC Heller K Heppelman S Hill N Hoftiezer JH Jankowski DJ Johns K Joyce T Kafka T Litchfield PJ Lopez FV Lowe M Mann WA Marshak ML May EN McMaster L Milburn RH Miller W Napier A Oliver WP Pearce GF Perkins DH Peterson EA Price LE Roback D Rosen DB 《Physical review D: Particles and fields》1990,42(9):2967-2973
23.
24.
The carbobenzyloxy (cbz) protecting group is evaluated for it's potential to enhance the resolution of chiral amine enantiomers using high-performance liquid chromatography (HPLC) and supercritical fluid chromatography (SFC). A series of cbz derivatives of commercially available racemates was prepared and analyzed by enantioselective chromatography using a variety of mobile phases and polysaccharide and Pirkle-type chiral stationary phases (CSPs). The cbz-derivatized product consistently demonstrated enhanced chiral resolution under HPLC and SFC conditions. Improved selectivity and resolution combined with an automated preparative HPLC or SFC system can lead to the rapid generation of highly purified enantiomers of desirable starting materials, intermediates or final products. 相似文献
25.
The palladium-catalyzed arylation of rac-(E)-3-acetoxy-1,3-diphenylprop-1-ene with arylboronic acids was studied under controlled microwave irradiation conditions. A variety of different catalysts, bases, and solvents were explored in order to achieve optimum yields in the shortest possible reaction times. The best isolated yields were obtained using Pd2(dba)3·CHCl3/PPh3 as the catalytic system, potassium phosphate monohydrate as the base, and toluene/H2O as a solvent system. Microwave irradiation using 5 mol % of the palladium catalyst for 90 s (max. temp 170 °C) generally afforded the cross-coupling products in good to excellent yields. 相似文献
26.
Cyclo-heptane, -octane, -decane, -dodecane and -octadecane have been fluorinated in the vapour phase with cobaltic fluoride. The perfluorocarbons obtained revealed varying degrees of skeletal rearrangements. Thus, cycloheptane gave perfluoro-cycloheptane and -methylcyclohexane; cyclooctane gave at least eight fluorocarbons including-bicyclo(3,3,0)octane and -cyclooctane; cyclodecane gave a complex mixture from which were isolated perfluoro cis- and trans-bicyclo(4,4,0)decanes but no perfluorocyclodecane; cyclododecane and cyclooctadecane gave complex fluorocarbon mixtures in which none of the fluorocarbons with the original cycloalkene skeleton could be detected.Tetradecafluorobicyclo(3,3,0)octane gave dodecafluorobicyclo (3,3,0)oct-1(5)-ene and decafluorobicyclo(3,3,0)octa-di-1(5), 2-ene when pyrolysed over iron gauze.The fluorination of cyclooctane also afforded 1-pentadecafluorocyclooctane which was dehydrofluorinated to tetradecafluorocyclooctene. This was converted to a range of derivatives including dodecafluorosuberic acid, 1,2-dichlorotetradecafluorocyclooctane, 1-methoxy tridecafluorocyclooctene and tetradecafluorocyclooctanone. 相似文献
27.
The adsorption, diffusion and desorption of chlorine on and from stoichiometric, reduced and partially reduced (defective) rutile TiO2{110} are investigated using ab initio density functional theory (DFT) calculations. Theoretical results are compared with experimental investigations, and microkinetic simulations based on DFT values are then used to verify the diffusion mechanisms assumed in the experimental investigations. 相似文献
28.
29.
Berhan Teclé Kaniz F. Siddiqui Christopher Ceccarelli John P. Oliver 《Journal of organometallic chemistry》1983,255(1):11-15
The structure of di-trans-β-styrylmercury has been determined by single crystal X-ray methods from counter data. The compound crystallizes in the orthorhombic space group Pbcn with unit cell dimensions a 15.413(6), b 11.161(9), c 7.668(5) Å, V 1319(1) Å3, Dcalc 2.049 g/cm3, and Z = 4. The crystal was solved by conventional heavy atom techniques. The crystal consists of individual molecular units with the mercury atom located on a two fold axis of symmetry. The CHgC fragment is nearly linear with an angle of 178°. The β-styryl groups are oriented so that a dihedral angle of 66.8° is formed between the planes defined by HgC(1)C(2) and HgC(1)′C(2)′ fragments. The HgC bond distance is 2.07(4) Å. 相似文献
30.
Summary The chromatographic performance of newly developed dicyanobiphenyl polysiloxane stationary phases were evaluated and compared
with the performance of other polar stationary phases, including the previously reported monocyanobiphenyl polysiloxanes.
Due to the unique combination of polarizable biphenyl and polar cyano functionalities in the side chains of the flexible polysiloxane
backbone, and by virtue of their mild liquid crystalline properties, the new stationary phases provide excellent resolution
of a wide variety of analytes, both polar and nonpolar, in both GC and SFC. They can be easily coated and cross-linked in
open tubular columns, and the resultant columns demonstrate excellent efficiency and performance at temperatures up to 280–300°C.
The new stationary phases exhibit enhanced selectivities for various types of isomeric compounds. 相似文献