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61.
Oleksiy V. Khavryuchenko Lidong Wang Dariusz Mitoraj Gilles H. Peslherbe 《Journal of Coordination Chemistry》2015,68(17-18):3317-3327
Coordinative incorporation of Co(II/III) cocatalytic sites into organic–inorganic hybrids of TiO2 and “polyheptazine” (PH, poly(aminoimino)heptazine, melon, or “graphitic carbon nitride”) has been investigated both by quantum chemical calculations and experimental techniques. Specifically, density-functional theory (DFT) calculations (PBE/def2-TZVPP) suggest that Co(II/III) and Zn(II) ions adsorb in nanocavities at the surface of the hybrid PH–TiO2 cluster, a prediction which can be further confirmed experimentally by 15N nuclear magnetic resonance in the case of the Zn complex. The absorption spectra of the complexes were characterized by time-dependent DFT calculations, suggesting a change of color upon Co ion binding which can in fact be observed with the naked eye. Hybrid TiO2–PH photoelectrodes were impregnated with Co(II) ions from aqueous cobalt nitrate solutions. Optical absorption data suggest that Co(II) ions are predominantly present as single ions coordinated within the nitrogen cavities of TiO2–PH, and any undesired blocking of light absorption is negligible. The cobalt-induced cocatalytic sites can efficiently couple to the holes photogenerated by visible light in TiO2–PH, leading to complete oxidation of water to dioxygen. Our results indicate that coordinative incorporation of metal ions into well-designed surface sites in the light absorber is sufficient to drive complex multielectron transformations in artificial photosynthetic systems. 相似文献
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Niladri S. Karan Aaron M. Keller Siddharth Sampat Oleksiy Roslyak Ayesha Arefin Christina J. Hanson Joanna L. Casson Anil Desireddy Yagnaseni Ghosh Andrei Piryatinski Rashi Iyer Han Htoon Anton V. Malko Jennifer A. Hollingsworth 《Chemical science》2015,6(4):2224-false
Hybrid semiconductor–metal nanoscale constructs are of both fundamental and practical interest. Semiconductor nanocrystals are active emitters of photons when stimulated optically, while the interaction of light with nanosized metal objects results in scattering and ohmic damping due to absorption. In a combined structure, the properties of both components can be realized together. At the same time, metal–semiconductor coupling may intervene to modify absorption and/or emission processes taking place in the semiconductor, resulting in a range of effects from photoluminescence quenching to enhancement. We show here that photostable ‘giant’ quantum dots when placed at the center of an ultrathin gold shell retain their key optical property of bright and blinking-free photoluminescence, while the metal shell imparts efficient photothermal transduction. The latter is despite the highly compact total particle size (40–60 nm “inorganic” diameter and <100 nm hydrodynamic diameter) and the very thin nature of the optically transparent Au shell. Importantly, the sensitivity of the quantum dot emission to local temperature provides a novel internal thermometer for recording temperature during infrared irradiation-induced photothermal heating. 相似文献
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Oleksiy A. Ignatyev 《Applied mathematics and computation》2010,216(2):388-394
The linear autonomous system of difference equations x(n+1)=Ax(n) is considered, where is a real nonsingular k×k matrix. In this paper it has been proved that if W(x) is any homogeneous polynomial of m-th degree in x, then there exists a unique homogeneous polynomial V(x) of m-th degree such that ΔV=V(Ax)-V(x)=W(x) if and only if where are the eigenvalues of the matrix A. The theorem on the instability has also been proved. 相似文献
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Christian Amatore Alexander Oleinick Oleksiy V Klymenko Irina Svir 《Chemphyschem》2005,6(8):1581-1589
Herein, we propose a method for reconstructing any plausible macroscopic hydrodynamic flow profile occurring locally within a rectangular microfluidic channel. The method is based on experimental currents measured at single or double microband electrodes embedded in one channel wall. A perfectly adequate quasiconformal mapping of spatial coordinates introduced in our previous work [Electrochem. Commun. 2004, 6, 1123] and an exponentially expanding time grid, initially proposed [J. Electroanal. Chem. 2003, 557, 75] in conjunction with the solution of the corresponding variational problem approached by the Ritz method are used for the numerical reconstruction of flow profiles. Herein, the concept of the method is presented and developed theoretically and its validity is tested on the basis of the use of pseudoexperimental currents emulated by simulation of the diffusion-convection problem in a channel flow cell, to which a random Gaussian current noise is added. The flow profiles reconstructed by our method compare successfully with those introduced a priori into the simulations, even when these include significant distortions compared with either classical Poiseuille or electro-osmotic flows. 相似文献
67.
We employed the APSYS software to perform 3D electrical and ray-tracing simulations on micro-ring light-emitting diodes (LEDs)
to verify previous experimental findings that they have higher extraction efficiency than micro-disk and broad area LEDs.
3D ray-tracing indicates the importance of inter-ring optical interactions. Furthermore we found that the higher light extraction
efficiency is at the expense of reduced internal quantum efficiency (IQE) as injection current is increased. 相似文献
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Oleksiy Lyutakov Ivan Hüttel Václav Prajzler Vítězslav Jeřábek Alexander Jančárek Vladimír Hnatowicz Václav Švorčík 《Journal of Polymer Science.Polymer Physics》2009,47(12):1131-1135
Micro‐sized patterns were created on thin poly(methyl methacrylate) (PMMA) films by the effect of external field, perpendicular to the film surface. The PMMA film, prepared by spin‐coating onto Si wafer, was heated to the fluid temperature (275 °C) and a linear pattern was created by the effect of electric field produced by a strip electrode. In another experiment, a round pattern was created as a result of local laser heating of the PMMA film under homogenous electrical field. The created patterns were analyzed by optical microscopy and profile meter. The dependence of the form and size of the created patterns on the intensity of the electric field, exposure time, and initial film thickness was examined. Wave guiding property of a linear pattern, produced by the above technique, was examined in a simple experiment. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1131–1135, 2009 相似文献
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Ivan M. Safonov Igor A. Sukhoivanov Oleksiy V. Shulika Volodymyr V. Lysak 《Superlattices and Microstructures》2008
Knowledge of the energy band diagram is very important in semiconductor physics due to the fact that the band diagram influences almost all parts of the physics of a semiconductor device. In this paper we examine a piecewise-constant approximation of the potential profile through a comparison with a comprehensive self-consistent model, with regard to the active regions of QW semiconductor lasers and amplifiers. The validity of this approximation is then defined, thus giving an insight into the physics of QW structures. 相似文献