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101.
102.
O. N. Krasnobaeva I. P. Belomestnykh T. A. Nosova T. A. Elizarova G. V. Isagulyants S. P. Kolesnikov V. P. Danilov 《Russian Journal of Inorganic Chemistry》2011,56(2):168-172
The first methods are developed for introducing niobium(V) into Mg-Al hydrotalcites used as precursors of oxide catalysts
for oxydehydrogenation (OD) of alkanes and alcohols. Samples of niobium(V)-containing oxide catalysts are synthesized. Their
catalytic properties are studied in oxydehydrogenation of ethane and ethylbenzene to styrene, oxidation dehydrocyclization
of octane into ethylbenzene and styrene, and oxydehydrogenation of sec-butanol to ketone (octane-(2)-one). It is ascertained
that ethane transformation into ethylene is highly a selective highly process (92–97%) at low temperatures (450–500°C) in
the presence of a niobium-containing catalyst; the catalyst is appreciably efficient in ethylbenzene transformation to styrene
and dehydrocyclization of n-octane to ethylbenzene and styrene, and in oxydehydrogenation of secbutanol to octane-(2)-one. All the catalysts studied
operate stably in OD reactions; no decrease in their activity or selectivity was detected after 50 h operation. 相似文献
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105.
Ihor Tarnavchyk Andriy Voronov Ananiy Kohut Nataliya Nosova Serhiy Varvarenko Volodymyr Samaryk Stanislav Voronov 《Macromolecular rapid communications》2009,30(18):1564-1569
In this study, highly stable gold and silver nanoparticles evenly distributed within a crosslinked poly(acrylamide)/poly(N‐(hydroxymethyl)acrylamide) (PAAm‐PHMAAm) network have been fabricated without addition of a reducing agent. Remarkably, the same chemical hydrogel composition has been involved in the successful fabrication of spherical gold and silver nanoparticles within the hydrogel template. The hydrogel network acts simultaneously as an efficient reducing agent and stabilizer. The PAAm–PHMAAm hydrogel network binds metal ions and, following reduction of bound to crosslinked template metal ions, proceeds via oxidation of hydroxymethyl hydrogel fragments. A one‐electron mechanism is proposed for the formation of the silver and gold nanoparticles.
106.
I. A. Bykova E. A. Monin V. M. Nosova A. V. Kisin P. A. Storozhenko 《Russian Chemical Bulletin》2012,61(9):1831-1832
A reaction of potassium tert-butoxide with chloromethyltrichlorosilane in THF leads to tri(tert-butoxy)chloromethylsilane. Upon reflux in THF, it reacted with magnesium with the formation of stable [tri(tert-butoxy)silyl]methylmagnesium chloride, whose structure was confirmed by 1H, 13C, and 29Si NMR spectroscopy. In the THF solution at 25 °C, [tri(tert-butoxy)silyl]methylmagnesium chloride exists in the equilibrium with bis{[tri(tert-butoxy)silyl]methyl}magnesium (in the ratio of 1: 1). 相似文献
107.
Nosova K. E. Tretyakov E. V. Romanenko G. V. Ovcharenko V. I. 《Russian Chemical Bulletin》2003,52(10):2231-2234
Study of the structures of compounds generated by the reactions of 4,4,5,5-tetramethyl-2-phenyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide with trifluoromethanesulfonic and picric acids demonstrated that these reactions produced salts of disproportionation products of nitronyl nitroxyl. 相似文献
108.
N. I. Rtishchev G. I. Nosova N. A. Solovskaya K. A. Romashkova V. V. Kudryavtsev 《Russian Journal of General Chemistry》2005,75(10):1584-1593
The emission bands exchibited by films of polyimides derived from 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride, hexafluoroisopropylidenedibenzene-3,3′,4,4′-tetracarboxylic dianhydride, and aromatic and heteroaromatic diamines, and also of polyamides and polyquinazolones derived from the same amines are exciplex bahnds. With polyamides, complexes in the ground state are formed. The fluorescence of the photoconductivity sensitizer Rhodamine 6G is quenched in films of these polymers by the exciplex mechanism. 相似文献
109.
V. L. Gein N. V. Nosova K. D. Potemkin Z. G. Aliev A. P. Kriven’ko 《Russian Journal of Organic Chemistry》2005,41(7):1016-1022
Base-catalyzed reactions of isopropyl acetoacetate with aromatic and heterocyclic aldehydes afforded the corresponding diisopropyl 6-hydroxy-6-methyl-4-oxocyclohexane-1,3-dicarboxylates which were brought into reactions with mono- and difunctional nitrogen-containing nucleophiles. According to the X-ray diffraction data, diisopropyl 4-oxocyclohexane-1,3-dicarboxylates in crystal exist in the ketone form.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 7, 2005, pp. 1039–1045.Original Russian Text Copyright © 2005 by Gein, Nosova, Potemkin, Aliev, Kriven’ko. 相似文献
110.