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排序方式: 共有249条查询结果,搜索用时 37 毫秒
91.
92.
Motoki Murai Takuya Kaji Takefumi Kuranaga Hiroshi Hamamoto Kazuhisa Sekimizu Masayuki Inoue 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2015,127(5):1576-1580
Lysocin E, a macrocyclic peptide, exhibits potent antibacterial activity against methicillin‐resistant Staphylococcus aureus (MRSA) through a novel mechanism. The first total synthesis of lysocin E was achieved by applying a full solid‐phase strategy. The developed approach also provides rapid access to the enantiomeric, epimeric, and N‐demethylated analogues of lysocin E. Significantly, the antibacterial activity of the unnatural enantiomer was comparable to that of the natural isomer, suggesting the absence of chiral recognition in its mode of action. 相似文献
93.
Yasui T Omoto Y Osato K Kaji N Suzuki N Naito T Okamoto Y Tokeshi M Shamoto E Baba Y 《Analytical sciences》2012,28(1):57-59
We developed a confocal microscopic method for a quantitative evaluation of the mixing performance of a three-dimensional microfluidic mixer. We fabricated a microfluidic baker's transformation (MBT) mixer as a three-dimensional passive-type mixer for the efficient mixing of solutions. Although the MBT mixer is one type of ideal mixers, it is hard to evaluate its mixing performance, since the MBT mixer is based on several cycles of complicated three-dimensional microchannel structures. We applied the method developed here to evaluate the mixing of water and a fluorescein isothiocyanate (FITC; diffusion coefficient, 4.9 × 10(-10) m(2) s(-1)) solution by the MBT mixer. This method enables us to capture vertical section images for the fluid distributions of FITC and water at different three-dimensional microchannel structures of the MBT device. These images are in good agreement with those of mixing images based on numerical simulations. The mixing ratio could be calculated by the fluorescence intensity at each pixel of the vertical section image; complete mixing is recognized by a mixing ratio of more than 90%. The mixing ratios are measured at different cycles of the MBT mixer by changing the flow rate; the mixing performance is evaluated by comparisons with the mixing ratio of the straight microchannel without the MBT mixer. 相似文献
94.
Chikashi Suzuki Tsuyoshi Nishi Masami Nakada Tomohito Tsuru Mitsuo Akabori Masaru Hirata Yoshiyuki Kaji 《Journal of Physics and Chemistry of Solids》2013
We investigated the electronic state of an (Am,U) mixed oxide with the fluorite structure using the all-electron full potential linear augmented plane wave method and compared it with those of Am2O3, AmO2, UO2, and La0.5U0.5O2. The valence of Am in the mixed oxide was close to that of Am2O3 and the valence of U in the mixed oxide was pentavalent. The electronic structure of AmO2 was different from that of Am2O3, particularly just above the Fermi level. In addition, the electronic states of Am and U in the mixed oxide were similar to those of trivalent Am and pentavalent U oxides. These electronic states reflected the high oxygen potential of AmO2 and the heightened oxygen potential resulting from the addition of Am to UO2 and also suggested the occurrence of charge transfer from Am to U in the solid solution process. 相似文献
95.
Jun?SakakibaraEmail author Masaki?Yamashita Tatsuya?Kobayashi Yuichi?Kaji Tetsuro?Oshika 《Experiments in fluids》2012,52(4):831-842
We measured velocity distributions in the anterior chamber of porcine eyes under simulated cataract surgery using stereoscopic particle image velocimetry (stereo-PIV). The surface of the cornea was detected based on the images of laser-induced fluorescent light emitted from fluorescent dye solution introduced in a posterior chamber. A coaxial phacoemulsification procedure was simulated with standard size (standard coaxial phacoemulsification) and smaller (micro coaxial phacoemulsification) surgical instruments. In both cases, an asymmetric flow rate of irrigation was observed, although both irrigation ports had the same dimensions prior to insertion into the eye. In cases where the tip of the handpiece was placed farther away from the top of the cornea, i.e., closer to the crystalline lens, direct impingement of irrigation flow onto the cornea surface was avoided and the flow turned back toward the handpiece along the surface of the corneal endothelium. Viscous shear stress on the corneal endothelium was computed based on the measured mean velocity distribution. The maximum shear stress for most cases exceeded 0.1 Pa, which is comparable to the shear stress that caused detachment of the corneal endothelial cells reported by Kaji et al. in Cornea 24:S55–S58, (2005). When direct impingement of the irrigation flow was avoided, the shear stress was reduced considerably. 相似文献
96.
Hajime Kaji 《Geometriae Dedicata》2009,139(1):75-82
In projective algebraic geometry, various pathological phenomena in positive characteristic have been observed by several authors. Many of those phenomena concerning the behavior of embedded tangent spaces seem to be controlled by the separability of (the extension of function fields defined by) the Gauss map, or by the reflexivity with respect to the projective dual for a projective variety. The purpose of this paper is to survey the studies on the relationship between the separability of the Gauss map and the reflexivity for a projective variety: Is the separability of the Gauss map equivalent to the reflexivity for a projective variety? 相似文献
97.
Wicht J Adachi I Aihara H Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Bay A Belous K Bhardwaj V Bitenc U Bondar A Bozek A Bracko M Browder TE Chang P Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Cho IS Choi Y Dalseno J Dash M Drutskoy A Eidelman S Gabyshev N Goldenzweig P Golob B Haba J Hayasaka K Hazumi M Heffernan D Hoshi Y Hou WS Hsiung YB Hyun HJ Iijima T Inami K Ishikawa A Ishino H Itoh R Iwasaki Y Kah DH Kaji H Kang JH Kapusta P Kawai H Kawasaki T Kichimi H Kim HJ Kim HO 《Physical review letters》2008,100(12):121801
We search for the radiative penguin decays B_{s}{0}-->varphigamma and B_{s}{0}-->gammagamma in a 23.6 fb{-1} data sample collected at the Upsilon(5S) resonance with the Belle detector at the KEKB e{+}e{-} asymmetric-energy collider. We observe for the first time a radiative penguin decay of the B_{s}{0} meson in the B_{s}{0}-->varphigamma mode and we measure B(B_{s}{0}-->varphigamma)=(57_{-15}{+18}(stat)-11+12(syst))x10{-6}. No significant B_{s}{0}-->gammagamma signal is observed and we set a 90% confidence level upper limit of B(B_{s}{0}-->gammagamma)<8.7x10{-6}. 相似文献
98.
Taniguchi N Nakao M Nishida S Adachi I Aihara H Arinstein K Aushev T Aziz T Bakich AM Balagura V Bay A Belous K Bhardwaj V Bitenc U Bondar A Bozek A Bracko M Browder TE Chang MC Chang P Chao Y Chen A Chen KF Chen WT Cheon BG Chiang CC Cho IS Choi Y Dalseno J Dash M Drutskoy A Dungel W Eidelman S Golob B Ha H Haba J Hara T Hayasaka K Hayashii H Hazumi M Hoshi Y Hou WS Hyun HJ Iijima T Inami K Ishikawa A Ishino H Itoh R Iwabuchi M Iwasaki M Iwasaki Y Joshi NJ Kah DH Kaji H Kang JH Kawai H 《Physical review letters》2008,101(11):111801
We report new measurements of the decays B+-->rho+gamma, B0-->rho0gamma, and B0-->omegagamma using a data sample of 657x10(6) B meson pairs accumulated with the Belle detector at the KEKB e+e- collider. We measure branching fractions B(B+-->rho+gamma)=(8.7_-2.7-1.1;+2.9+0.9)x10(-7), B(B0-->rho0gamma)=(7.8_-1.6-1.0;+1.7+0.9)x10(-7), and B(B0-->omegagamma)=(4.0_-1.7;+1.9+/-1.3)x10(-7). We also report the isospin asymmetry Delta(rhogamma)=-0.48_-0.19-0.09;+0.21+0.08 and the first measurement of the direct CP-violating asymmetry ACP(B+-->rho+gamma)=-0.11+/-0.32+/-0.09, where the first and second errors are statistical and systematic, respectively. 相似文献
99.
Chen JH Wang MZ Adachi I Aihara H Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bay A Bedny I Belous K Bitenc U Bondar A Bozek A Bracko M Browder TE Chang MC Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Cho IS Choi SK Choi Y Dalseno J Dash M Drutskoy A Eidelman S Golob B Ha H Haba J Hara T Hayasaka K Hayashii H Hazumi M Heffernan D Hoshi Y Hou WS Hsiung YB Hyun HJ Inami K Ishikawa A Ishino H Itoh R Iwasaki M Joshi NJ Kah DH Kaji H Kapusta P Katayama N Kawasaki T Kichimi H 《Physical review letters》2008,100(25):251801
Using a 492 fb{-1} data sample collected near the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e{+}e{-} collider, we observe the decay B{0}-->ppK*0 with a branching fraction of (1.18{-0.25}{+0.29}(stat)+/-0.11(syst))x10{-6}. We study the decay dynamics of B{0}-->ppK*0 and compare with B{+}-->ppK*+. The K*0 meson is found to be almost 100% polarized (with a fraction of (101+/-13+/-3)% in the helicity zero state), while the K*+ meson has a (32+/-17+/-9)% fraction in the helicity zero state. The direct CP asymmetries for B{0}-->ppK*0 and B{+}-->ppK*+ are measured to be -0.08+/-0.20+/-0.02 and -0.01+/-0.19+/-0.02, respectively. In addition, we report improved measurements of the branching fractions B(B{+}-->ppK*+)=(3.38{-0.60}{+0.73}+/-0.39)x10{-6} and B(B{0}-->ppK{0})=(2.51{-0.29}{+0.35}+/-0.21)x10{-6}, which supersede our previous measurements. 相似文献
100.
Kazuo Soga Yoshifumi Suzuki Toshiya Uozumi Eiichi Kaji 《Journal of polymer science. Part A, Polymer chemistry》1997,35(2):291-297
Several kinds of MgCl2-supported half titanocene (XTiCl3; X = cyclopentadienyl, pentamethylcyclopentadienyl, indenyl, and heptamethylindenyl) catalysts were prepared and applied to propene polymerization using Al(i-Bu)3a as cocatalyst. It was confirmed from the catalyst analysis that the ligand (X) is attached to titanium even after the reaction with Al(i-Bu)3. When polymerization was conducted without any external donor, those catalysts predominantly gave atactic PP. However, addition of a suitable monofunctional Lewis base like ethylbenzoate caused to change the stereospecificity of polymer from aspecific into highly isospecific. On the other hand, the use of a bifunctional donor like di-n-butylphthalate killed the activity almost completely. The isotactic PP was found to have a microstructure similar to that obtained with metallocene catalysts. © 1997 John Wiley & Sons, Inc. 相似文献