An analytical method for the determination of perfluorinated compounds in whole blood using acetonitrile and solid phase extraction methods

A method for the analysis of perfluorinated compounds (perfluoroalkyl sulfonates: C4, C6, C8, C10; perfluoroalkyl sulfinates: C6, C8, C10; perfluorooctanesulfonamide, N-ethyl perfluorooctanesulfonamide, N-ethyl perfluorooctanesulfonamidoacetate, perfluorocarboxylates: C4–C14; fluorotelomer carboxylate (7:3, 8:2) in whole blood using acetonitrile and OASIS WAX^® solid phase extraction (SPE) cartridge was developed. Separation of target compounds in two HPLC columns (ion exchange JJ50-2D and C18 Betasil columns) was examined. Matrix recoveries of the developed methods ranged from 70% to 120%. Separation of possible inferences such as taurodeoxycholic acid (TDC) was accomplished using an ion exchange JJ50-2D column, and this separation was validated using whole blood of different animals.     

Object plane detection and phase-amplitude imaging based on transport of intensity equation

By using transport of intensity equation (TIE), phase distribution of an object is retrieved from through-focus intensity images. This technique allows simple and robust phase imaging compared with an interferometric approach. However, it is hard to measure phase distribution when a dynamic object moves in the direction of an optical axis. To clear this problem, autofocusing TIE which is based on local statistics is proposed. The proposed technique achieves the detection of the object plane and the retrieval of a focused object phase distribution simultaneously. In this approach, an object plane is determined by the focusing techniques based on local statistics such as variance, gradient, and Laplacian of amplitude distribution, after phase distribution in an image sensor plane is retrieved by the TIE. The performance of these three statistics is evaluated in numerical and optical experiments, and a suitable focus value is determined for precise phase imaging.     

奇质量核的超越平均场玻色子费米子模型描述(英文)

对近年发展起来的一个基于核密度泛函理论和粒子核心耦合方案来计算中重质量奇A核谱性质的理论方法进行了评述。该方法首先在平均场层面通过选择合适的能量密度泛函和对力结构来自洽求解偶偶核心的势能曲面、球单粒子能级和奇粒子占有率,进一步将得到的结果作为微观输入来建立相互作用玻色子费米子模型哈密顿量,其中三个与粒子核心耦合强度相关的参数需要通过拟合一些特定奇质量核低激发谱数据来最终确定。通过对轴形变奇质量Eu同位素的低激发能谱和电磁跃迁几率的系统研究来说明该模型方法的有效性。另外,还讨论了该方法在描述轴形变奇质量核形状相变以及描述丰中子奇质量Ba同位素中八极关联方面的应用。A recently developed method for calculating spectroscopic properties of medium-mass and heavy atomic nuclei with an odd number of nucleons is reviewed, that is based on the framework of nuclear energy density functional theory and the particle-core coupling scheme. The deformation energy surface of the eveneven core, as well as the spherical single-particle energies and occupation probabilities of the odd particle(s), are obtained by a self-consistent mean-field calculation with the choice of the energy density functional and pairing properties. These quantities are then used as a microscopic input to build the interacting bosonfermion Hamiltonian. Only three strength parameters for the particle-core coupling are specifically adjusted to selected data for the low-lying states of a particular odd-mass nucleus. The method is illustrated in a systematic study of low-energy excitation spectra and electromagnetic transition rates of axially-deformed odd-mass Eu isotopes. Recent applications of the method, to the calculations of the signatures of shapes phase transitions in axially-deformed odd-mass nuclei, octupole correlations in neutron-rich odd-mass Ba isotopes, are discussed.     

Thermodynamics of black holes in Hořava–Lifshitz gravity

By using the canonical Hamiltonian method, we obtain the mass and entropy of the black holes with general dynamical coupling constant λ in Ho?ava–Lifshitz Gravity. Regardless of whether the horizon is sphere, plane or hyperboloid, we find these black holes are thermodynamically stable in some parameter space and unstable phase also exists in other parameter space. The relation between the entropy and horizon area of the black holes has an additional coefficient depending on the coupling constant λ  , compared to the λ=1$\lambda =1$ case. For λ=1$\lambda =1$, the well-known coefficient of one quarter is recovered in the infrared region.     

Thermal oxidation behaviors and structures of Fe-9Cr-1Mo alloy

Isothermal oxidation behaviors of Fe-9Cr-1Mo alloy were investigated at 600, 700, 750 and 850 ^°C for 72 h in air atmosphere. The oxidation rates were measured using a thermogravimetric analyzer (TGA). The structure and composition of the oxide scale were characterized by X-ray diffraction (XRD), energy dispersive spectrometry (EDS) and conversion electron Mössbauer spectrometry (CEMS). In this study it was found that the oxide layers form duplex structures consisting of Fe and Cr oxides. CEMS spectra are composed of one doublet due to dispersed Fe ³⁺ in Cr₂O₃ oxidation layers produced at high temperatures and two magnetic components due to Fe-Cr-Mo alloy substrate and hematite (Fe, Cr)₂O₃ with lower hyperfine field than pure hematite (52 T). Fe rich oxides are formed at the surface by oxidation at relatively low temperatures of 600 ^°C and 700 ^°C, while Cr rich (Fe, Cr)-oxides are formed in the top surface layers by oxidation at higher than 750 ^°C.     

Realization of an ultra-flat silica surface with angstrom-scale average roughness using nonadiabatic optical near-field etching

We propose a new method of optical near-field etching where a nonadiabatic process is applied to a synthetic silica substrate using a continuum wave laser (λ=532 nm) with a Cl₂ gas source. Because the absorption band edge energy of Cl₂ is higher than the photon energy of the light source, we preclude the conventional adiabatic photochemical reaction. An optical near field, generated on the nanometrically rough substrate, induces the nonadiabatic chemical reaction to the Cl₂ molecules and thereby selectively etches away the roughness, leaving an ultra-flat synthetic silica surface with a minimum average surface roughness R _a of 1.37 Å.     

Superconducting Pb island nanostructures studied by scanning tunneling microscopy and spectroscopy

Superconductivity of nanosized Pb-island structures whose radius is 0.8 to 2.5 times their coherence length was studied under magnetic fields using low-temperature scanning tunneling microscopy and spectroscopy. Spatial profiles of superconductivity were obtained by conductance measurements at zero-bias voltage. Critical magnetic fields for vortex penetration and expulsion and for superconductivity breaking were measured for each island. The critical fields depending on the lateral size of the islands and existence of the minimum lateral size for vortex formation were observed.     

ICEMS study of isothermal oxidation of Fe–Mn–Al–C–Cr–Si–Mo, Fe–Mn–Al–C–Cr–Si and Fe–9Cr–1Mo alloys

The purpose of this paper is to investigate the isothermal behavior of Fe–27.3Mn–7.6Al–C–6.5Cr–0.25Si–0.88Mo (Mo(0)) and Fe–27.3Mn–7.6Al–1.0C–6.5Cr–0.25Si (Mo(1)) alloys and compare it against Fe–9Cr–1Mo (FCR) commercial alloy. The experiments were carried out at 600°C, 700°C, 750°C and 850°C, each one during 72 h in static air. The oxidation kinetics was measured as a function of time using a Thermogravimetry analyzer (TGA). The structure and composition of the oxide scale were characterized by X-ray diffraction (XRD) and Integral Conversion Electron Mössbauer Spectroscopy (CEMS). The TGA results show that at all oxidation temperatures the sample FCR exhibit the lowest kinetic corrosion and the lowest weight gain, whereas Mo(0) the highest. By CEMS technique it were found a broad magnetic sextet, which has been fit by one hyperfine field distribution with mean hyperfine field characteristic to ferritic/martensite phase, one Fe^3?+? doublet and one singlet for the Mo(0) and Mo(1) alloys. Samples oxidized at highest temperatures exhibit a strong paramagnetic line, probably due that the Cr or Mn oxides may be enriched on the surface. Then, the magnetic phase can be converted partially into austenite phase at highest temperatures.