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71.
72.
Yamasaki Y Sagayama H Goto T Matsuura M Hirota K Arima T Tokura Y 《Physical review letters》2007,98(14):147204
Magnetic ferroelectrics or multiferroics, which are currently extensively explored, may provide a good arena to realize a novel magnetoelectric function. Here we demonstrate the genuine electric control of the spiral magnetic structure in one such magnetic ferroelectric, TbMnO3. A spin-polarized neutron scattering experiment clearly shows that the spin helicity, clockwise or counterclockwise, is controlled by the direction of spontaneous polarization and hence by the polarity of the small electric field applied on cooling. 相似文献
73.
A Scalable Biomimetic Synthesis of Resveratrol Dimers and Systematic Evaluation of their Antioxidant Activities 下载免费PDF全文
Bryan S. Matsuura Mitchell H. Keylor Bo Li YuXuan Lin Shelby Allison Prof. Dr. Derek A. Pratt Prof. Dr. Corey R. J. Stephenson 《Angewandte Chemie (International ed. in English)》2015,54(12):3754-3757
An efficient synthetic route to the resveratrol oligomers quadrangularin A and pallidol is reported. It features a scalable biomimetic oxidative dimerization that proceeds in excellent yield and with complete regioselectivity. A systematic evaluation of the natural products and their synthetic precursors as radical‐trapping antioxidants has revealed that, contrary to popular belief, this mode of action is unlikely to account for their observed biological activity. 相似文献
74.
Keiichiro Ishikawa Nobuyasu Hanari Yoshitaka Shimizu Toshihide Ihara Akira Nomura Masahiko Numata Takashi Yarita Kenji Kato Koichi Chiba 《Accreditation and quality assurance》2011,16(6):311-322
Purity assay of high-purity materials (HPMs) of phthalic acid esters (PAEs) was carried out by means of a mass balance method.
In this method, chromatographic methods such as gas chromatography-flame ionization detector (GC-FID) and/or high-performance
liquid chromatography (HPLC) in combination with other methods such as Karl-Fischer (KF) titration and vacuum evaporation
(VE) were applied. The sum of the impurities estimated by these methods allowed the estimation of the purity of the main component
by difference. Seven PAEs with varying side chain structures and levels of impurities were analysed on a systematic way in
which impurities were classified into several groups in terms of their abundance, availability of qualitative information
and availability of authentic compounds, etc. The absolute quantity of each impurity was determined by GC-FID and/or HPLC
based on the calibration made by the authentic compounds of impurities whenever available. The purities in mass fraction of
these PAEs were certified at the National Metrology Institute of Japan (NMIJ), and the PAEs were registered as primary reference
materials playing an essential role in linking the metrological traceability of the Japan Calibration Service System (JCSS)
to the International System of Units (SI). 相似文献
75.
Matsuura BS Condie AG McBee IA Buff RC Karahalis GJ Stephenson CR 《Organic letters》2011,13(23):6320-6323
An intramolecular cyclization cascade reaction has been developed utilizing a high valent palladium intermediate that generates a carbon-carbon and carbon-oxygen bond in a single transformation. This method provides rapid access to highly functionalized tricyclic scaffolds, including spirocyclic cyclohexadienones. Good yields and mild conditions are reported with high tolerance toward oxygen and water. 相似文献
76.
A set of n-principal points of a distribution is defined as a set of n points that optimally represent the distribution in terms of mean squared distance. It provides an optimal n-point-approximation of the distribution. However, it is in general difficult to find a set of principal points of a multivariate distribution. Tarpey et al. [T. Tarpey, L. Li, B. Flury, Principal points and self-consistent points of elliptical distributions, Ann. Statist. 23 (1995) 103-112] established a theorem which states that any set of n-principal points of an elliptically symmetric distribution is in the linear subspace spanned by some principal eigenvectors of the covariance matrix. This theorem, called a “principal subspace theorem”, is a strong tool for the calculation of principal points. In practice, we often come across distributions consisting of several subgroups. Hence it is of interest to know whether the principal subspace theorem remains valid even under such complex distributions. In this paper, we define a multivariate location mixture model. A theorem is established that clarifies a linear subspace in which n-principal points exist. 相似文献
77.
78.
Watanuki S Matsuura K Tomura Y Okada M Okazaki T Ohta M Tsukamoto S 《Chemical & pharmaceutical bulletin》2011,59(8):1029-1037
A series of 1-isopropyl-1,2,3,4-tetrahydroisoquinoline derivatives were synthesized and their bradycardic activities were evaluated in isolated guinea pig right atria. Structure-activity relationship studies revealed that the introduction of an appropriate substituent and its position on the 1,2,3,4-tetrahydroisoquinoline ring are essential for potent in vitro activity. Furthermore, the tether between the piperidyl moiety and the terminal aromatic ring is important for potent antihypertensive activity. Oral administration of 6-fluoro-1-isopropyl-2-{[1-(2-phenylethyl)piperidin-4-yl]carbonyl}-1,2,3,4-tetrahydroisoquinoline (3b) to spontaneously hypertensive rats (SHR) elicited antihypertensive effects without inducing reflex tachycardia, which is often caused by traditional L-type Ca2? channel blockers. 相似文献
79.
Watanuki S Matsuura K Tomura Y Okada M Okazaki T Ohta M Tsukamoto S 《Chemical & pharmaceutical bulletin》2011,59(11):1376-1385
We synthesized and evaluated inhibitory activity against T-type Ca(2+) channels for a series of 1-alkyl-N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]piperidine-4-carboxamide derivatives. Structure-activity relationship studies have revealed that the isopropyl substituent at the benzylic position plays an important role in exerting potent inhibitory activity, and the absolute configuration of the benzylic position was found to be opposite that of mibefradil, which was first launched as a new class of T-type Ca(2+) channel blocker. Oral administration of N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]-1-[2-(3-methoxyphenyl)ethyl]piperidine-4-carboxamide (17f) lowered blood pressure in spontaneously hypertensive rats without inducing reflex tachycardia, an adverse effect often caused by traditional L-type Ca(2+) channel blockers. 相似文献
80.