Thermal analysis of polyaniline poly(N-vinylpyrrolidone)-stabilized dispersions

The polyaniline dispersions stabilized with poly(N-vinylpyrrolidone) (PANI/PVP) were synthesized by oxidative polymerization with different mass ratios of PANI and PVP and different molar concentrations of the components in the polymerization mixture. The composite powders prepared from colloidal PANI/PVP dispersions were characterized by thermogravimetry and differential thermal analysis. The change in the ratio of PANI and PVP as well as the starting molar concentrations of aniline hydrochloride and oxidant has influence on the resulting properties of the dispersions. Concerning the doping, the results show that PANI/PVP powders are stable up to approximately 160 °C. Degradation of polymer chains starts at temperatures above 250 °C. The PANI/PVP composite powders with lower content of PANI exhibit slightly higher thermal stability. Further, colloidal PANI/PVP dispersions were screen-printed on aluminum foil for infrared spectroscopic characterization and on poly(ethylene terephthalate) foil for electrical measurements. The sheet resistance of printed layers measured by two-point probe was of the order of tens to thousands of kΩ sq^?1. The influence of both the change in the composition and the drying temperature is discussed.     

Charge transport and contact resistance in coplanar devices based on colloidal polyaniline dispersion

The charge transport properties of thin films prepared from colloidal dispersion of polyaniline stabilized by poly(N‐vinylpyrrolidone) (PANI/PVP) have been investigated. The electrical characterization of coplanar device comprising of gold electrodes and PANI/PVP film deposited by spin coating served to gain insights into the contact and bulk resistance. The films prepared from PANI/PVP colloidal dispersion show high stability over a large temperature range. Temperature dependent measurements in the range from 90 to 350 K reveal that the charge transport can be described by a three‐dimensional variable‐range hopping mechanism as the dominant mode in the films. The stability of the films cast from dispersion within a large temperature range opens the possibility of the application as a polymer semiconductor layer in sensors and charge‐transport interlayer in organic solar cells. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1710–1716     

Gene expression profiling using advanced mass spectrometric approaches

In the era of systems biology, computational and high-throughput experimental biological approaches are increasingly being combined to provide global snapshots of entire genomes and proteomes under tissue- and disease-specific conditions. The aim is to identify proteins changing in concentration and/or post-translational state and/or location, and develop a better molecular level understanding of the operation of biological systems. Here we describe an approach for comparative proteomics that builds upon the combination of high-performance nano-scale separations with the high-mass measurement accuracy, mass-resolving power and sensitivity of Fourier transform ion cyclotron resonance mass spectrometry to provide broad dynamic range, comprehensive and quantitative proteome measurements.     

An extension of the Landau-Kolmogorov inequality. Solution of a problem of Erdös

For any fixed finite interval [a, b] on the real line, an arbitrary natural numberr and σ>0, we describe the extremal function to the problem $\left\| {f^{(k)} } \right\|L_p \left[ {a,b} \right]^{ \to \sup } \left( {1 \leqslant k \leqslant r - 1, 1 \leqslant p< \infty } \right)$ over all functionsf ∈W _∞ ^r such that |f ^(r)(x)| ≤σ, |f(x)|≤1 on (?∞, ∞). Similarly, we solve the problem, raised by Paul Erdös, of characterizing the trigonometric polynomial of fixed uniform norm whose graph has maximal arc length over [a, b].     

Pulsradiolytische Untersuchungen der Reaktion des e aq − mit halogenierten aromatischen Verbindungen

Kinetic pulse radiolysis experiments (1 s pulse duration) on the reaction of e _aq ^– with halogenated aromatic compounds (fluoro-, chloro-, bromobenzene, benzylchloride and phenethylchloride were carried out in order to check the existence and to investigate the fate of an electron adduct. The measured absorption spectra, being identical with those previously observed for the phenyl and benzyl radical, and thepH dependence of the formation of the H-adducts, indicating no protonation of an intermediateRX ^–, can be explained simply by quantitative elimination of the halide. No evidence for the existence of an electron adduct as an intermediate could be obtained under the applied experimental conditions.

     

The semantics of knowledge attributions

The basic idea of conversational contextualism is that knowledge attributions are context sensitive in that a given knowledge attribution may be true if made in one context but false if made in another, owing to differences in the attributors’ conversational contexts. Moreover, the context sensitivity involved is traced back to the context sensitivity of the word “know,” which, in turn, is commonly modelled on the case either of genuine indexicals such as “I” or “here” or of comparative adjectives such as “tall” or “rich.” But contextualism faces various problems. I argue that in order to solve these problems we need to look for another account of the context sensitivity involved in knowledge attributions and I sketch an alternative proposal.     

Hydrolysis and retro‐aldol cleavage of ethyl threo‐2‐(1‐adamantyl)‐3‐hydroxybutyrate: competing reactions

The hydrolysis of ethyl threo‐2‐(1‐adamantyl)‐3‐hydroxybutyrate ( 1 ) and the parent ester ethyl 3‐hydroxybutyrate ( 4 ) has been studied experimentally and computationally. In the hydrolysis of threo‐ester 1 with 2 M NaOH, predominantly retro‐aldol product was observed, whereas the hydrolyzed product was present in a minor amount. When the reaction is carried out under the same conditions with the parent ester ethyl 3‐hydroxybutyrate ( 4 ), hydrolyzed product is exclusively observed. The competitive pathways, namely hydrolysis and the retro‐aldol reaction for 1 and 4 were investigated using DFT calculations in the both gas and solvent phase. The calculated results in the solvent phase at B3LYP/6–31 + G* level revealed that the formation of retro‐aldol products is kinetically preferred over the hydrolysis of threo‐ester 1 in the presence of a base. However, the parent ester 4 showed that the retro‐aldol process is less favored than the hydrolysis process under similar conditions. The steric effect imposed by the bulky adamantyl group to enhance the activation barriers for the hydrolysis of the ethyl threo‐2‐(1‐adamantyl)‐3‐hydroxybutyrate ( 1 ) was further supported by the calculations performed with tert‐butyl group at the α‐carbon atom of ethyl 3‐hydroxybutyrate ( 7 ). Copyright © 2010 John Wiley & Sons, Ltd.     

基于窄带多区域水平集方法的遥感图像分割

由于遥感图像存在边缘混叠等问题,经典的C-V模型会产生大量的冗余轮廓,而且无法分割多个同质区域的目标.为此,提出了基于C-V模型的窄带多区域水平集图像分割方法,采用N-1个水平集函数将图像分割成N(N＞1)个区域,每个水平集函数表达一个区域.该方法一方面通过建立独立多区域水平集模型可以消除多余的轮廓,避免分割区域的重叠...