全文获取类型
收费全文 | 778篇 |
免费 | 42篇 |
国内免费 | 6篇 |
专业分类
化学 | 481篇 |
晶体学 | 2篇 |
力学 | 32篇 |
数学 | 169篇 |
物理学 | 142篇 |
出版年
2022年 | 10篇 |
2021年 | 12篇 |
2020年 | 33篇 |
2019年 | 16篇 |
2018年 | 22篇 |
2017年 | 7篇 |
2016年 | 24篇 |
2015年 | 14篇 |
2014年 | 26篇 |
2013年 | 50篇 |
2012年 | 61篇 |
2011年 | 58篇 |
2010年 | 32篇 |
2009年 | 26篇 |
2008年 | 45篇 |
2007年 | 37篇 |
2006年 | 40篇 |
2005年 | 39篇 |
2004年 | 29篇 |
2003年 | 26篇 |
2002年 | 23篇 |
2001年 | 12篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 5篇 |
1996年 | 5篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1931年 | 4篇 |
1914年 | 4篇 |
1908年 | 3篇 |
1906年 | 4篇 |
1905年 | 3篇 |
1904年 | 11篇 |
1901年 | 5篇 |
1880年 | 3篇 |
1873年 | 3篇 |
排序方式: 共有826条查询结果,搜索用时 15 毫秒
81.
Consider a Hilbert space
equipped with a time-structure, i.e., a resolution E of the identity on
defined on subsets of some linearly ordered set Λ. For which x and y in
is it possible to find a causal (time respecting) compact operator T, so that Tx = y? When T is required to be a Hilbert-Schmidt operator and (Λ, E) is sufficiently regular, this question is answered in terms of the “time-densities” of x and y. The condition is that the integral ∝gLμx({s t})−1 dμy(t) should be finite, where μx and μy are the measures on Λ given by μx(Ω) = ¦|E(Ω)x¦|2 and μy(Ω) = ¦|E(Ω)y¦|2. Further a solution is given for the related problem of minimizing the sum of ¦|Tx − y¦|2 and the squared Hilbert-Schmidt norm ¦|R¦|22 of T. 相似文献
82.
The effective heat conduction of short fibre reinforced materials considering the fibre distribution
This contribution focuses on the effective heat conductivity of short fibre reinforced materials. For this purpose, a representative volume element (RVE), which is able to represent all possible fibre orientation distributions, is introduced and modelled in ABAQUS. Subsequently, the effective heat conductivity of the RVE is derived, employing a numerical homogenisation scheme, and a phenomenological material model is fitted to those results. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
83.
The spatially controlled positioning of functional materials by self-assembly is one of the fundamental visions of nanotechnology. Major steps towards this goal have been achieved using DNA as a programmable building block. This tutorial review will focus on one of the most promising methods: DNA origami. The basic design principles, organization of a variety of functional materials and recent implementation of DNA robotics are discussed together with future challenges and opportunities. 相似文献
84.
Munch HK Heide ST Christensen NJ Hoeg-Jensen T Thulstrup PW Jensen KJ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(26):7198-7204
Self-assembly of proteins mediated by metal ions is crucial in biological systems and a better understanding and novel strategies for its control are important. An abiotic metal ion ligand in a protein offers the prospect of control of the oligomeric state, if a selectivity over binding to the native side chains can be achieved. Insulin binds Zn(II) to form a hexamer, which is important for its storage in vivo and in drug formulations. We have re-engineered an insulin variant to control its self-assembly by covalent attachment of 2,2'-bipyridine. The use of Fe(II) provided chemoselective binding over the native site, forming a homotrimer in a reversible manner, which was easily followed by the characteristic color of the Fe(II) complex. This provided the first well-defined insulin trimer and the first insulin variant for which self-assembly can be followed visually. 相似文献
85.
This review provides an overview of direct and indirect technologies to screen protein–ligand interactions with mass spectrometry.
These technologies have as a key feature the selection or affinity purification of ligands in mixtures prior to detection.
Specific fields of interest for these technologies are metabolic profiling of bioactive metabolites, natural extract screening,
and the screening of libraries for bioactives, such as parallel synthesis libraries and small combichem libraries. The review
addresses the principles of each of the methods discussed, with a focus on developments in recent years, and the applicability
of the methods to lead generation and development in drug discovery. 相似文献
86.
Tommy Sonne Alstrøm Mads Peter Sørensen Niels Falsig Pedersen Søren Madsen 《Acta Appl Math》2011,115(1):63-74
The time-dependent Ginzburg-Landau equation is solved numerically for type-II superconductors of complex geometry using the
finite element method. The geometry has a marked influence on the magnetic vortex distribution and the vortex dynamics. We
have observed generation of giant vortices at boundary defects, suppressing the superconducting state far into the superconductor. 相似文献
87.
Since its introduction, click chemistry has received a considerable amount of interest. In this contribution, the term click chemistry and the reactions that fall under this term are briefly explained. The main focus of this review is on the application of click chemistry in conjunction with living radical polymerization for the synthesis of advanced macromolecular architectures. Therefore the most powerful living radical polymerization (LRP) techniques are discussed and an overview of click chemistry in the different synthetic schemes is given. A large number of examples are shown that include the synthesis of block copolymers, star-shaped polymers, surface modified particles, and polymer-protein conjugates. The enormous potential of LRP/click chemistry is probably best exemplified by the synthesis of different miktoarm star copolymers, to which a separate section is dedicated. 相似文献
88.
Zhang H Borrmann H Oeschler N Candolfi C Schnelle W Schmidt M Burkhardt U Baitinger M Zhao JT Grin Y 《Inorganic chemistry》2011,50(4):1250-1257
Single crystals of Ba(8)Au(5.3)Ge(40.7) [space group Pm(3)n (No. 223), a = 10.79891(8) ?] were prepared by a Bridgman technique. The crystal structure refinement based on single-crystal X-ray diffraction data does not reveal any vacancies in the Au/Ge framework or in the cages. In addition to the ionic bonding between Ba and the anionic framework, a direct interaction between Ba and Au atoms was identified in Ba(8)Au(5.3)Ge(40.7) by applying the electron localizability indicator. As expected by the chemical-bonding picture, Ba(8)Au(5.3)Ge(40.7) is a diamagnet and shows p-type electrical conductivity with a hole carrier concentration of 7.14 × 10(19) cm(-3) at 300 K and very low lattice thermal conductivity of ≈0.6 W m(-1) K(-1) at 500 K. The thermoelectric figure of merit ZT of single crystals of Ba(8)Au(5.3)Ge(40.7) attains 0.3 at 511 K and reaches 0.9 at 680 K in a polycrystalline sample of closely similar composition. This opens up an opportunity for tuning of the thermoelectric properties of materials in the Ba-Au-Ge clathrate system by changing the chemical composition. 相似文献
89.
We demonstrate theoretically that laser-induced coherent quantum interference control of asymptotic states of dissociating molecules is possible--even in the (one-photon) weak-field limit starting from a single vibrational eigenstate--when resonances are in play. This is illustrated for the NaI molecule, where it is shown that the probability of observing atomic fragments as well as the distribution of their relative momenta can be changed by a phase modulated pulse with a fixed bandwidth. This type of control is restricted to finite times during the indirect fragmentation. 相似文献
90.
Grabow JU Mata S Alonso JL Peña I Blanco S López JC Cabezas C 《Physical chemistry chemical physics : PCCP》2011,13(47):21063-21069
Nicotine has been investigated in the gas phase and two conformational forms were characterized through their rotational spectra. Two spectroscopic techniques have been used to obtain the spectra: a new design of broadband Fourier transform microwave (FTMW) spectroscopy with an in-phase/quadrature-phase-modulation passage-acquired-coherence technique (IMPACT) and narrowband FTMW spectroscopy with coaxially oriented beam-resonator arrangement (COBRA). The rotational, centrifugal distortion and hyperfine quadrupole coupling constants of two conformers of nicotine have been determined and found to be in N-methyl trans configurations with the pyridine and pyrrolidine rings perpendicular to one another. The quadrupole hyperfine structure originated by two (14)N nuclei has been completely resolved for both conformers and used for their unambiguous identification. 相似文献