On single and bimodal optimum buckling loads of clamped columns

We study the problem of determining the optimum shape of a thin, elastic, clamped column of given length and volume, such that the fundamental buckling load is a maximum. The column cross-sections are assumed to be geometrically similar, and a minimum allowable value is specified for the cross-sectional area.Investigating the optimization problem parametrically in terms of this minimum constraint, we reveal a significant feature. There exists a threshold value for the constraint, beyond which the optimum columns are all associated with single mode optimum buckling loads, whereas, for any value of the constraint less than the threshold value, the optimum columns are associated with bimodal fundamental buckling loads.This bimodal behaviour necessitates an extension and a mathematical reformulation of the current optimization problem, which is outlined and solved in the paper. In particular, we revise the result hitherto considered to be the optimum solution for an unconstrained column with clamped ends.     

Über die Beziehungen zwischen der Galoisgruppe und dem Raum der Anordnungen eines formal-reellen Körpers

Ohne Zusammenfassung     

Measurement of weak meson form factors in spacelike regions

With the construction of high energy, high intensity accelerators (NAL & CERN, SPS) investigation of neutrino scattering on virtual pions, á la Chew-Low, becomes experimentally possible. We propose to analyse the process ν + N → μ^? + K + Δ to extract the usual K_?3 form factor(s) for spacelike momentum transfer. A model calculation suggests that f₊(T) can be determined reasonably well from a triple differential cross section, whereas only rough information on f_?(T) may be obtained from the transverse polarization of the muon. The experiment proposed requires scanning of several millions of bubble chamber pictures.     

Beta relaxation in the shear mechanics of viscous liquids: Phenomenology and network modeling of the alpha-beta merging region

The phenomenology of the beta relaxation process in the shear-mechanical response of glass-forming liquids is summarized and compared to that of the dielectric beta process. Furthermore, we discuss how to model the observations by means of standard viscoelastic modeling elements. Necessary physical requirements to such a model are outlined, and it is argued that physically relevant models must be additive in the shear compliance of the alpha and beta parts. A model based on these considerations is proposed and fitted to data for Polyisobutylene 680.     

A combined measurement of thermal and mechanical relaxation

In order to describe relaxation the thermodynamic coefficient can be generalized into a complex frequency-dependent cross response function. We explore theoretically the possibility of measuring for a supercooled liquid near the glass transition. This is done by placing a thermistor in the middle of the liquid which itself is contained in a spherical piezoelectric shell. The piezoelectric voltage response to a thermal power generated in the thermistor is found to be proportional to but factors pertaining to heat diffusion and adiabatic compressibility κ_S(ω) do also intervene. We estimate a measurable piezoelectric voltage of 1 mV to be generated at 1 Hz for a heating power of 0.3 mW. Together with κ_S(ω) and the longitudinal specific heat c_l(ω) which may also be found in the same setup a complete triple of thermoviscoelastic response functions may be determined when supplemented with shear modulus data.     

Electron transfer driven by proton fluctuations in a hydrogen-bonded donor-acceptor assembly

The temperature-isotope dependence of proton-coupled electron transfer (PCET) for a noncovalent molecular dyad is reported. The system consists of an excited-state Zn(II) porphyrin that transfers an electron to a naphthalene diimide acceptor through an amidinium-carboxylate interface. Two different isotope effects are observed for variant temperature regimes. A reverse isotope effect (i.e., kH/kD < 1) is observed as T approaches 120 K (kH/kD = 0.9, 120 K), whereas a normal isotope effect (i.e., kH/kD > 1) is recovered as the temperature is increased (kH/kD = 1.2, 300 K). The transition between these limits is smooth, with a crossover temperature of T approximately 160 K. These observations are in accordance with charge-transfer dynamics that are susceptible to bath-induced fluctuations in the proton coordinate.