Analysis of High-order Explicit LES Dynamic Modeling Applied to Airfoil Flows

A high-order low dissipative numerical framework is discussed to tackle simultaneously the modeling of unresolved sub-grid scale flow turbulence and the capturing of shock waves. The flows around two different airfoil profiles are simulated using a Spectral Difference discretisation scheme. First, a transitional, almost incompressible, low Reynolds number flow over a Selig-Donovan 7003 airfoil. Second, a high Reynolds number flow over a RAE2822 airfoil under transonic conditions. These flows feature both laminar and turbulent flow physics and are thus particularly challenging for turbulence sub-grid scale modeling. The accuracy of the recently developed Spectral Element Dynamic Model, specifically capable of detecting spatial under-resolution in high-order flow simulations, is evaluated. Concerning the test in transonic conditions, the additional complexity due to the presence of shock waves has been handled using an artificial viscosity shock-capturing technique based on bulk viscosity. To mitigate the impact of the shock-capturing on turbulence dissipation, it was necessary to combine the high-order modal-type shock detection with a usual sensor measuring the local flow compressibility.

     

Examining Trichloroisocyanuric Acid and Oxalyl Chloride in Complementary Approaches to Fluorination of Group 15 Heteroatoms

A mild, oxidative fluorination approach to a variety of fluorinated phosphorus compounds using trichloroisocyanuric acid (TCICA) and KF was developed as a complement to a recent study on deoxygenative fluorination using oxalyl chloride. Herein, the syntheses of several fluorinated organophosphorus compounds are reported, and both TCICA/KF and oxalyl chloride/KF conditions are compared and contrasted throughout. Initial investigations of the method on other group 15 heteroatoms (i. e., As, Sb, and Bi) are also reported, with varied success. This work notably extends the known TCICA/KF reactivity series to another group of elements beyond previously studied chalcogens (S, Se, and Te) and halogens (iodine) and expands the utility of the previously reported oxalyl chloride/KF method.     

Enantioselective Catalytic Addition of N-Acyl Radicals: In Batch and In Flow Organophotoredox α-Amination of Aldehydes

The organophotoredox catalytic enantioselective addition of N-acyl radicals to aldehydes, to afford enantioenriched N-acyl 1,2 aminoalcohols was studied. Under the best conditions, in batch, the product was isolated in up to 52 % yield and 85 % e.e., using a low cost and commercially available chiral imidazolidinone as organocatalyst. The reaction was then studied in flow, exploring different experimental setups and photoreactors. Although modest yields were obtained, the in-flow process afforded the product in higher productivities (up to 60 times higher) and improved space time yields (increased up to 113 times) compared to the batch reaction, with no loss of stereoselectivity.