排序方式: 共有68条查询结果,搜索用时 31 毫秒
31.
Daniel Polyak Ngan Phung Jian Liu Robert Barrows Thomas J. Emge Spencer Knapp 《Tetrahedron letters》2017,58(40):3879-3883
Homophthalic anhydride (HPA) typically reacts rapidly with benzalimines to afford the formal [4+2] adduct, a 1,2,3,4-tetrahydroisoquinolin-1-one-4-carboxylic acid. The stereochemical outcome of this reaction is consistent with an open transition state comprising an iminium species and enolized HPA, leading to a short-lived amino-anhydride intermediate. In the case of N-tert-butylbenzalimine, this Mannich-type intermediate, which would normally cyclize at low temperature to a single isomer of the delta-lactam, is intercepted by base treatment to afford beta-lactam products. A pathway featuring ketene formation followed by ring closure is implicated. 相似文献
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The subsequent sliding behaviour of the initially elastic, submicron contacts between a diamond tip and bulk polycrystalline Ni3Al was investigated by nano-scratch tests. Scratches are made under constant normal loads otherwise too low to trigger crystal plasticity in uniaxial nanoindentation experiments. Three types of behaviour are observed: (i) the entire scratch is purely elastic with a sliding coefficient of friction (μ) of about 0.086; (ii) a sudden strain burst in the normal direction, commonly known as pop-in, occurs at the onset of sliding and the subsequent sliding is plastic with μ typically a few times larger than 0.086; and (iii) an intermediate case in which the scratch is initially elastic followed by a pop-in beyond which the sliding becomes plastic. The intermediate case occurs rather randomly. The μ for elastic sliding is found to be load- or size-independent, but that for plastic sliding exhibits a strong size effect, i.e. it is small at small loads, but increases towards a steady value at larger loads. 相似文献
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Vu T. Nguyen Viet D. Nguyen Graham C. Haug Ngan T. H. Vuong Hang T. Dang Dr. Hadi D. Arman Dr. Oleg V. Larionov 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):7995-8001
The development of efficient and selective C−N bond-forming reactions from abundant feedstock chemicals remains a central theme in organic chemistry owing to the key roles of amines in synthesis, drug discovery, and materials science. Herein, we present a dual catalytic system for the N-alkylation of diverse aromatic carbocyclic and heterocyclic amines directly with carboxylic acids, by-passing their preactivation as redox-active esters. The reaction, which is enabled by visible-light-driven, acridine-catalyzed decarboxylation, provides access to N-alkylated secondary and tertiary anilines and N-heterocycles. Additional examples, including double alkylation, the installation of metabolically robust deuterated methyl groups, and tandem ring formation, further demonstrate the potential of the direct decarboxylative alkylation (DDA) reaction. 相似文献
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Micro-pillars of anodic aluminium oxide with nano-sized honeycomb channels along the pillar axis exhibit compressive stress-strain response with large excursions corresponding to discrete, inhomogeneous deformation events. Each excursion is found to associate with the severe distortion of a material layer at the pillar’s head, whereas the remaining of the pillar remains intact. The stresses at which these excursions occur do not exhibit any significant dependence on the pillar size. A simple model is proposed to describe the response of pillars under compression, which energetically, as well as kinetically, explains as to why the localized deformation always takes place at the pillar head. Predictions on the occurrence of instability events from this model also quantitatively agree with the experimental observations. 相似文献
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Ngui Khiong Ngan Chee Seng Wong Kong Mun Lo 《Journal of chemical crystallography》2011,41(11):1700-1706
Abstract
Three dioxomolybdenum complexes namely dioxo(5-chlorosalicylaldehyde thiosemicarbazonato) dimethylsulfoxide molybdenum(VI) (C1), dioxo(5-chlorosalicylaldehyde 2-ethylthiosemicarbazonato) dimethylsulfoxide molybdenum(VI) (C2) and dioxo(5-chlorosalicylaldehyde N-phenylthiosemicarbazonato) dimethylsulfoxide molybdenum(VI) (C3) were prepared. The compounds all crystallize in the triclinic space group P-1 with a = 7.3184(3) ?, b = 7.5035(3) ?, c = 14.9713(6) ?, α = 85.005(2)°, β = 85.616(2)°, γ = 66.987(2)° for C1, a = 8.2339(1) ?, b = 10.1739(1) ?, c = 10.4017(1) ?, α = 78.486(1)°, β = 89.312(1)°, γ = 81.730(1)° for C2, a = 7.0591(1) ?, b = 9.5603(1) ?, c = 14.5762(2) ?, α = 76.280(1)°, β = 81.351(1)°, γ = 81.985(1)° for C3. In general, the overall geometry of these complexes can be regarded as a distorted octahedron with the tridentate thiosemicarbazonato ligands (L2−) bonded to the MoO2 2+ core, with the imine nitrogen, phenoxyl oxygen, sulfur atom and one of the terminal oxygen atoms of the dioxomolybdenum occupying the equatorial position. The sixth coordination site is occupied by the dimethylsulfoxide (DMSO) solvent molecules. The adjacent molecules of C1 are linked by N–H···N intermolecular hydrogen bonding, forming polymeric chains that run parallel to the bc plane. On the other hand, C2 is a discrete molecule while the molecules of C3 associate via weak N–H···O hydrogen bonding interaction to form a polymeric chain that runs along the a-axis. 相似文献36.
Chi Nguyen Thi Thanh Ngan Nguyen Bich Luc Van Meervelt 《Acta Crystallographica. Section C, Structural Chemistry》2014,70(3):297-301
The crystal structures of cis‐dichlorido(ethylamine‐κN)(piperidine‐κN)platinum(II), [PtCl2(C2H7N)(C5H11N)], (I), cis‐dichlorido(3‐methoxyaniline‐κN)(piperidine‐κN)platinum(II), [PtCl2(C5H11N)(C7H9NO)], (II), and cis‐dichlorido(piperidine‐κN)(quinoline‐κN)platinum(II), [PtCl2(C5H11N)(C9H7N)], (III), have been determined at 100 K in order to verify the influence of the nonpiperidine ligand on the geometry and crystal packing. The crystal packing is characterized by N—H...Cl hydrogen bonding, resulting in the formation of chains of molecules connected in a head‐to‐tail fashion. Hydrogen‐bonding interactions play a major role in the packing of (I), where the chains further aggregate into planes, but less so in the case of (II) and (III), where π–π stacking interactions are of greater importance. 相似文献
37.
Van Thuan Le Thi Kieu Ngan Tran Dai Lam Tran Hoang Sinh Le Van Dat Doan Quang Dung Bui 《Journal of Dispersion Science and Technology》2013,34(12):1761-1776
AbstractIn the present work, a novel composite consisting of magnetite, activated carbon from spent coffee grounds and natural clay (MACCC) was prepared by a one-pot synthesis method via a simultaneous activation and magnetization processes. Various techniques (XRD, FTIR, SEM, TEM, EDX, BET) were utilized to characterize the synthesized composite before utilizing it as an adsorbent for removal of Cu(II), Ni(II) and Pb(II) ions from aqueous solutions. Conditions for removal of heavy metals were thoroughly optimized as 25?°C, pH of 5.5, adsorbent dosage of 2?g L?1, and a contact time of 60?min. Three models of pseudo first-, second-order and intraparticle diffusion as well as three models of Langmuir, Freundlich, and Temkin were used to analyze kinetics and isotherms of the adsorption process. Thermodynamics was discussed completely. Regeneration and recyclability of the adsorbent were also evaluated. Based on the analysis of experimental results, a possible adsorption mechanism of heavy metals onto the synthesized composite was proposed. The maximum capacities caculated from Langmuir model followed the order of Pb(II) > Cu(II) > Ni(II) as 143.56, 96.16 and 84.86?mg·g?1, respectively. The overall results indicated that MACCC is a potential adsorbent for removal of toxic Pb(II), Cu(II) and Ni(II) ions from wastewater due to simple preparation, high removal efficiency and good recyclability. 相似文献
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Positivity - We investigate the Courrège theorem in the context of linear operators that satisfy the positive maximum principle on a space of continuous functions over a symmetric space.... 相似文献
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Vu Thi Ngan Jorg De Haeck Hai Thuy Le G. Gopakumar Peter Lievens Minh Tho Nguyen 《ChemInform》2009,40(44):no-no
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献