首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   31492篇
  免费   180篇
  国内免费   279篇
化学   11939篇
晶体学   312篇
力学   1461篇
综合类   13篇
数学   9475篇
物理学   8751篇
  2021年   75篇
  2020年   69篇
  2019年   78篇
  2018年   1261篇
  2017年   1530篇
  2016年   828篇
  2015年   644篇
  2014年   577篇
  2013年   910篇
  2012年   3284篇
  2011年   2469篇
  2010年   1908篇
  2009年   1622篇
  2008年   653篇
  2007年   692篇
  2006年   641篇
  2005年   4468篇
  2004年   3936篇
  2003年   2335篇
  2002年   525篇
  2001年   345篇
  2000年   125篇
  1999年   201篇
  1998年   146篇
  1997年   92篇
  1996年   67篇
  1995年   67篇
  1994年   75篇
  1993年   44篇
  1992年   201篇
  1991年   172篇
  1990年   162篇
  1989年   140篇
  1988年   126篇
  1987年   80篇
  1986年   63篇
  1985年   71篇
  1984年   58篇
  1983年   57篇
  1982年   45篇
  1979年   55篇
  1978年   55篇
  1976年   112篇
  1975年   56篇
  1974年   69篇
  1973年   69篇
  1972年   51篇
  1969年   47篇
  1968年   46篇
  1966年   53篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
T. Laffey showed (Linear and Multilinear Algebra6(1978), 269–305) that a semigroup of matrices is triangularizable if the ranks of all the commutators of elements of the semigroup are at most 1. Our main theorem is an extension of Hthis result to semigroups of algebraic operators on a Banach space. We also obtain a related theorem for a pair {A, B} of arbitrary bounded operators satisfying rank (ABBA)=1 and several related conditions. In addition, it is shown that a semigroup of algebraically unipotent operators of bounded degree is triangularizable.  相似文献   
102.
The hyperspaces of strongly countable dimensional compacta of positive dimension and of strongly countable dimensional continua of dimension greater than 1 in the Hilbert cube are homeomorphic to the Hurewicz set of all nonempty countable closed subsets of the unit interval [0,1]. These facts hold true, in particular, for covering dimension dim and cohomological dimension dimG, where G is any Abelian group.  相似文献   
103.
Let B^α = {B^α(t),t E R^N} be an (N,d)-fractional Brownian motion with Hurst index α∈ (0, 1). By applying the strong local nondeterminism of B^α, we prove certain forms of uniform Hausdorff dimension results for the images of B^α when N 〉 αd. Our results extend those of Kaufman for one-dimensional Brownian motion.  相似文献   
104.
The interaction of the synthetic oligonucleotide d(C-G-C-G-A-A-T-T-C-G-C-G)2 with two different transition-metal ions has been investigated in aqueous solution by means of 1H NMR spectroscopy. The effects on the DNA due to the presence of manganese(II) or zinc(II) have been monitored by observing the paramagnetic broadening and diamagnetic shifts of the non-exchangeable proton resonance lines, respectively. The 1H NMR spectra acquired during the course of the manganese(II) titration show very distinct broadening effects on certain DNA resonance lines. Primarily, the H8 resonance of G4 is affected, but also the H5 and H6 resonances of C3 are clearly affected by the metal. The results imply that the binding of manganese(II) to DNA is sequence specific. The 1H spectra obtained during the zinc(II) titration reveal diamagnetic shift effects which largely conform with the paramagnetic broadening effects due to the presence of manganese(II), although this picture is somewhat more complex. The H8 resonance of G4 displays a clearly visible high-field shift, while for the other guanosine H8 protons this effect is absent. The H1' and H2' protons of C3 show an effect of similar strength, although in the opposite direction, while H5 and H6 of C3 are only slightly affected. Local differences in the structure of the DNA and the basicities of potential binding sites on different base steps in the sequence might account for the observed sequence selectivity.  相似文献   
105.
In the title compound, [Ni(N3)2(C6H6N2O)2], the NiII atom lies on an inversion centre. The distorted octahedral nickel(II) coordination environment contains two planar trans-related N,O-chelating picolinamide ligands in one plane and two monodentate azide ligands perpendicular to this plane. Molecules are linked into a three-dimensional framework by N—H...N hydrogen bonds.  相似文献   
106.
In 1983 Morse proved, for unknown scalar one-dimensional linearsystems, the nonexistence of rational or polynomial universalstabilizers (UAS). In 1983, Nussbaum gave an example of an analyticUAS. In our paper, it is shown that there exist time-invariantpolynomial UAS's with multidimensional gain adaptation. Thedesign procedure is developed for linear, minimum-phase systemsof relative degree one. Convergence of the closed-loop systemis proved. Some numerical simulations are provided.  相似文献   
107.
In the crystal structures of two cyclic trihydroxamic acid derivatives containing the same substructure unit, viz. 1,3,5‐trihydroxy‐1,3,5‐triazinane‐2,4,6‐trione dihydrate, C3H3N3O6·2H2O, (I), and 1,3,5‐benz­yloxy‐1,3,5‐triazinane‐2,4,6‐trione, C24H21N3O6, (II), there is no significant difference in the geometric parameters. In (I), there are 11 hydrogen bonds of the O—H⋯O type inter­connecting the mol­ecules in a three‐dimensional network, while in (II) there are only two weak C—H⋯O hydrogen bonds. The results of IR spectroscopic analysis are in good agreement with the crystallographic study.  相似文献   
108.
109.
110.
A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert1increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号