全文获取类型
收费全文 | 127篇 |
免费 | 8篇 |
专业分类
化学 | 61篇 |
晶体学 | 1篇 |
力学 | 4篇 |
物理学 | 69篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2017年 | 7篇 |
2016年 | 6篇 |
2015年 | 5篇 |
2014年 | 2篇 |
2013年 | 10篇 |
2012年 | 9篇 |
2011年 | 6篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 1篇 |
2007年 | 1篇 |
2006年 | 3篇 |
2005年 | 1篇 |
2004年 | 3篇 |
2003年 | 2篇 |
2002年 | 5篇 |
2001年 | 4篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 5篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 1篇 |
1987年 | 5篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1982年 | 2篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有135条查询结果,搜索用时 281 毫秒
81.
J. Eickmeyer S. Michalowski N. Mistry R. Talman K. Ueno 《Physics letters. [Part B]》1976,63(1):104-106
The total cross-section for production of hadrons by inelastic electron scattering at 3.2° from hydrogen and deuterium has been measured in the Q2 range 0.015 GeV2 to 0.1 GeV2, at virtual photon energies ranging from 2 GeV to 8.5 GeV. The transition to photoproduction is observed to be smooth, the ratio σD/σH being about 1.85 in this range. No evidence is seen for a conjectured rapid Q2-dependence of this ratio at low Q2. 相似文献
82.
Syntheses,Structures, and Magnetic Behavior of New Azide Linked Compounds with One‐ and Two‐Dimensional Structures 下载免费PDF全文
Three azide based compounds were synthesized employing aliphatic amines as site blocking agents: [Ni(N3)(C6H16N2)2]ClO4 ( I ) [C6H16N2 = N,N′‐diethylethylenediamine (DEDA)], [Cu8(N3)16(C6H18N4)2] ( II ) [C6H18N4 = tris(2‐aminoethyl) amine (TREN)], and [Cu7(N3)14(C7H19N3)2] · 2H2O ( III ) [C7H19N3 = 3,3′‐diamino‐N‐methyldipropylamine (DMDA)]. The compounds I and II have one‐dimensional structure and III has a two‐dimensional structure. Compound I is a simple linear cationic Ni–azide chain and compound II has Cu6 azide units forming a column terminated by the copper‐metalloligand generated in‐situ during the course of the reaction. The charge compensation perchlorate anions occupy spaces in between the chains in I . Compound II packs in a herringbone arrangement, which is not commonly observed in low‐dimensional structures. Compound III has one‐dimensional copper‐azide chains connected through copper‐metalloligand forming the two‐dimensional structure. All the three compounds exhibit anti‐ferromagnetic behavior. 相似文献
83.
Bortoletto D Goldberg M Horwitz N Jain V Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Thulasidas M Csorna SE Letson T Alexander J Artuso M Bebek C Berkelman K Cassel DG Cheu E Coffman DM Crawford G DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Katayama N Kreinick DL Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M Riley D Sapper M Silverman A Stone S Worden H Worris M Sadoff AJ 《Physical review letters》1990,64(18):2117-2120
84.
Bortoletto D Brown DN Dominick J McIlwain RL Miller DH Modesitt M Shibata EI Schaffner S Shipsey IP Battle M Kroha H Sparks K Thorndike EH Wang C Goldberg M Haupt T Horwitz N Jain V Moneti GC Rozen Y Rubin P Skwarnicki T Sharma V Stone S Thusalidas M Yao W Zhu G Barnes AV Bartelt J Csorna SE Letson T Mestayer MD Alexander J Artuso M Bebek C Berkelman K Besson D Browder TE Cassel DG Cheu E Coffman DM Drell PS Ehrlich R Galik RS Garcia-Sciveres M Geiser B Gittelman B Gray SW Halling AM Hartill DL 《Physical review D: Particles and fields》1992,45(1):21-35
85.
86.
Mistry MK Choudhury NR Dutta NK Knott R 《Langmuir : the ACS journal of surfaces and colloids》2010,26(24):19073-19083
The high-temperature morphology of supported liquid membranes (SLMs) prepared from perfluorinated membranes such as Nafion and Hyflon and hydrophobic ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMI-TFSI) has been investigated by small-angle X-ray scattering (SAXS). Proton conductivity results of SLMs before and after leaching show an increase in conductivity with temperature up to 160 °C in an anhydrous environment. DSC results show that crystallites within perfluorinated membranes are thermally stable up to 196 °C. High-temperature SAXS results have been used to correlate structure and morphology of supported liquid membranes with high-temperature conductivity data. The ionic liquid essentially acts as a proton solvent in a similar way to water in hydrated Nafion membranes and increases size of clusters, which allow percolation to be achieved more easily. The cation of the ionic liquid interacts with sulfonate groups within ionic domains through electrostatic interactions and displaces protons. Protons can associate with free anions of the ionic liquid, which are loosely associated with cations and can transport by hopping from anion sites within the membrane. The ionic liquid contributes to proton conductivity at high temperature through achievement of long-range ordering and subsequent percolation. 相似文献
87.
88.
Bhupendra M. Mistry Niketan S. Patel Mayank J. Patel Smita Jauhari 《Research on Chemical Intermediates》2011,37(6):659-671
The inhibition effect of 1,3,5-triazinyl urea derivatives, viz. 1-(4-cyclohexyl amino)-6-(3,4-dimethoxy phenyl ethyl amino)-1,3,5-triazin-2-yl)-3-p-tolyurea (4-CADT) and 1-(4-chlorophenyl)-3-(4-(cyclohexyl amino)-6-(3,4-dimethoxy phenyl ethyl amino)-1,3,5-triazin-2-yl) urea (4-CCADT), were evaluated against mild steel (MS) corrosion in 1 N HCl solutions using conventional weight loss, potentiodynamic polarization, linear polarization, electrochemical impedance spectroscopy, and scanning electron microscopic studies. The losses in weights of MS samples have proved that both were efficient corrosion inhibitors. The mixed mode of inhibition was confirmed by electrochemical polarizations and the results of electrochemical impedance spectroscopy have shown the changes in the impedance parameters like charge transfer resistance and double-layer capacitance to confirm the strong adsorption on the MS surface inhibition of MS. The changes in concentrations of the inhibitors were due to the adsorption of the molecules evaluated leading to the formation of a protective layer on the surface of MS. The inhibition action of these compounds was assumed to occur via adsorption on the steel surface through the active centers contained in the molecules. 相似文献
89.
Sebastian Kunze Philipp Grosse Dr. Miguel Bernal Lopez Dr. Ilya Sinev Dr. Ioannis Zegkinoglou Dr. Hemma Mistry Dr. Janis Timoshenko Michael Y. Hu Jiyong Zhao Ercan E. Alp Dr. See Wee Chee Prof. Beatriz Roldan Cuenya 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(50):22856-22863
Operando nuclear resonant inelastic X-ray scattering (NRIXS) and X-ray absorption fine-structure spectroscopy (XAFS) measurements were used to gain insight into the structure and surface composition of FeCu and FeAg nanoparticles (NPs) during the electrochemical CO2 reduction (CO2RR) and to extract correlations with their catalytic activity and selectivity. The formation of a core–shell structure during CO2RR for FeAg NPs was inferred from the analysis of the operando NRIXS data (phonon density of states, PDOS) and XAFS measurements. Electrochemical analysis of the FeAg NPs revealed a faradaic selectivity of 36 % for CO in 0.1 M KHCO3 at −1.1 V vs. RHE, similar to that of pure Ag NPs. In contrast, a predominant selectivity towards H2 evolution is obtained in the case of the FeCu NPs, analogous to the results obtained for pure Fe NPs, although small Cu NPs have also been shown to favor H2 production. 相似文献
90.