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91.
The application of Co(Ⅲ)/Al2O3 catalyst in Fischer-Tropsch synthesis(FTS)was studied in a wide range of synthesis gas conversions and compared with Fuzzy Simulation results.Present study applies fuzzy model to predicting the product composition of CH4,CO2 and CO in Fischer-Tropsch process for natural gas synthesis,in which the input vector was 4-dimension including four variables(operating pressure, operating temperature,time and CO/H2 ratio)of 70 different experiments and the output product is a composition of CO2,CO and CH4. The Mamdani algorithm has been applied to the training of the fuzzy system and the test set was used to evaluate the performance of the system including R2,ARE,AARE and SD.The results demonstrated that the predicted values from the model were in good consistency with the experimental data.The work indicates how fuzzy inference system(FIS),as a promising predicting technique,would be effectively used in FTS. 相似文献
92.
Ali Ramazani Morteza Rouhani Aram Rezaei Nahid Shajari Ali Souldozi 《Helvetica chimica acta》2011,94(2):282-288
Reactions of biacetyl (=butane‐2,3‐dione) with (N‐isocyanimino)triphenylphosphorane in the presence of aromatic carboxylic acids proceed smoothly at room temperature and under neutral conditions to afford 3‐(5‐aryl‐1,3,4‐oxadiazol‐2‐yl)‐3‐hydroxybutan‐2‐one derivatives in high yields. 相似文献
93.
Laleh Torkian Minoo Dabiri Peyman Salehi Morteza Bararjanian 《Helvetica chimica acta》2011,94(8):1416-1425
The 1‐{[(1H‐1,2,3‐Triazol‐4‐yl)methoxy]phenyl}‐1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives 5 were synthesized by a simple and efficient method, i.e., by the four‐component, one‐pot condensation reaction of phthalohydrazide 4 , a (propargyloxy)benzaldehyde 1 , an active methylene compound 3 (malononitrile or ethyl cyanoacetate), and an azide 2 in the presence of Cu(OAc)2/sodium L ‐ascorbate as catalyst and 1‐methyl‐1H‐imidazolium trifluoroacetate ([Hmim](CF3COO)) as an ionic‐liquid medium in good to excellent yields (Scheme 1). 相似文献
94.
A series of allylpalladium dimers having metals connected by binucleating dialkyldithiooxamidate [N(R)SC-CS(R)N](2-) [R = methyl, ethyl, isopropyl, benzyl, isoamyl, (S)-1-(1-phenyl)ethyl, meso-(1-phenyl)ethyl, and rac-(1-phenyl)ethyl] were prepared by reacting the monochelate [(η(3)-allyl)Pd(N(R)SC-CS(R)NH κ-S,S Pd)] with [(η(3)-allyl)PdCl](2) in chloroform. At low temperature (20 °C), the bimetallic complexes [(η(3)-allyl)Pd](2)(μ-dialkyldithiooxamidate κ-N,N' Pd, κ-S,S' Pd') (kinetic compounds) are formed in a short reaction time (10 min). At a higher temperature (50 °C) and a longer reaction time (24 h), the corresponding bimetallic isomers [(η(3)-allyl)Pd](2)(μ-dialkyldithiooxamidate κ-N,S Pd, κ-N',S' Pd') (thermodynamic compounds) are obtained. Both kinetic and thermodynamic compounds can exist as endo or exo isomers, depending on the reciprocal orientation of the allyl cuspids. Both endo and exo isomers are only detectable in solution when the alkyl substituents are chiral alkyl groups. Moreover, diffractometric modeling agrees with the presence of both isomers in the solid state even when the alkyl substituent is an achiral alkyl group. In a chloroform solution, endo and exo isomers undergo isomeric conversion owing to the apparent allyl rotation that follows the Pd-N bond rupture in the (η(3)-allyl)Pd(N^N) frame of kinetic compounds or in the (η(3)-allyl)Pd(N^S) frame of thermodynamic compounds. The dithiooxamidate [N(R)SC-CS(R)N](2-), when engaged in a κ-N,S Pd, κ-N',S' Pd' coordination mode, behaves as a hybrid hemilabile binucleating ligand. At room temperature and in a chloroform solution, the kinetic compounds rearrange into the thermodynamically more stable isomers in about 3 or 4 days. The higher stability of the thermodynamic species was evaluated by means of computational studies in accordance with the maximum hardness principle. Finally, the crystal structures of [(η(3)-allyl)Pd](2)(μ-diethyldithiooxamidate κ-N,S Pd, κ-N',S' Pd'), [(η(3)-allyl)Pd](2)(μ-meso-(1-phenyl)ethyldithiooxamidate κ-N,S Pd, κ-N',S' Pd'), and [(η(3)-allyl)Pd](2)(μ-rac-(1-phenyl)ethyldithiooxamidate κ-N,N' Pd, κ-S,S' Pd') are reported. 相似文献
95.
Mahmoudi M Amiri H Shokrgozar MA Sasanpour P Rashidian B Laurent S Casula MF Lascialfari A 《Chemical communications (Cambridge, England)》2011,47(37):10404-10406
The creation of novel engineered multimodal nanoparticles (NPs) is a key focus in bionanotechnology and can lead to deep understanding of biological processes at the molecular level. Here, we present a multi-component system made of gold-coupled core-shell SPIONs, as a new nanoprobe with signal enhancement in surface Raman spectroscopy, due to its jagged-shaped gold shell coating. 相似文献
96.
Habibi MH Mokhtari R Mikhak M Amirnasr M Amiri A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,79(5):1524-1527
Cu(II) and Ni(II) complexes of the general type [M(N2O2)] are described. The N2O2 ligands used are [N,N'-bis(2-hydroxy-6-methoxybenzylidene)propane-1,3-diamine] (HOMeSalpn) and [N,N'-bis(2-hydroxy-6-methoxybenzylidene)propane-1,2-diamine (HOMeSalpr). These complexes have been characterized by IR, UV-vis, CV, TG-DTA and 1H NMR spectroscopy. The electrochemical behavior of these complexes at a glassy carbon electrode in acetonitrile solution indicates that the first reduction process corresponding to Cu(II)-Cu(I) and Ni(II)-Ni(I) is electrochemically irreversible. The new copper complexes have been applied for the preparation of copper nanoparticles using non-ionic surfactant (Triton X-100) by thermal reduction. The copper nanoparticles with average size of 48nm were formed by thermal reduction of [N,N'-bis(2-hydroxy-6-methoxybenzylidene)propane-1,3-diamine]copper(II) in the presence of triphenylphosphine thus releasing the reduced copper and affording the high-purity copper nanoparticles. 相似文献
97.
Morteza Garshasbi 《Numerical Methods for Partial Differential Equations》2019,35(6):2000-2016
This study deals with the numerical investigation of a mathematical model of breast cancer at the initial growth stage known as ductal carcinoma in situ. This model considered as an inverse problem and the uniqueness of solution of this inverse problem is proved. To solve this problem, a computational approach is developed based on an iterative procedure and space marching and mollification methods. The stability and convergence results are given to support the method theoretically. Two test problems are considered to demonstrate the efficiency and ability of the proposed numerical approach. 相似文献
98.
Nonlinear vibration mitigation of a flexible rotor shaft carrying a longitudinally dispositioned unbalanced rigid disc 总被引:1,自引:0,他引:1
Nonlinear Dynamics - This study is dedicated to investigate the nonlinear dynamics of a system composed of a flexible rotor shaft carrying a longitudinally dispositioned unbalanced rigid disc. The... 相似文献
99.
Morteza Moniri 《Archive for Mathematical Logic》2002,41(1):101-105
For a classical theory T, ℋ(T) denotes the intuitionistic theory of T-normal (i.e. locally T) Kripke structures. S. Buss has asked for a characterization of the theories in the range of ℋ and raised the particular
question of whether HA is an ℋ-theory. We show that T
i
∈ range(ℋ) iff T
i
= ℋ(T). As a corollary, no fragment of HA extending iΠ
1 belongs to the range of ℋ. A. Visser has already proved that HA is not in the range of H by different methods. We provide more examples of theories not in the range of ℋ. We show PA-normality of once-branching Kripke models of HA + MP, where it is not known whether the same holds if MP is dropped.
Received: 15 August 1999 / Published online: 3 October 2001 相似文献
100.
Oxidative deprotection of a variety of trimethylsilyl ethers were performed by Fe(NO3)3.9H2O in the presence of H3PMo12O40.xH2O as catalyst at room temperature in good to high yields under solvent‐free conditions. 相似文献