Two New Pseudoguaianolides from the Flowers of Parthenium hysterophorus

Chemical investigation on two samples of the flowers of Parthenium hysterophorus afforded two new pseudoguaianolides (one from each sample) together with several known constituents. The structures of the new compounds were established by extensive spectroscopic (1D‐ and 2D‐NMR) studies. The X‐ray crystallographic analysis of one of these compounds was also accomplished.     

Nonstatistical structures in the excitation functions of20Ne(16O,12C)24Mg and20Ne(16O,20Ne)16O reactions

The data on the excitation functions of²⁰Ne(¹⁶O,¹²C)²⁴Mg,²⁰Ne(¹⁶O,¹²C)²⁴Mg^*(1.37, 2⁺),²⁰Ne(¹⁶O,¹²C)²⁴Mg^*(4.12, 4⁺+4.24, 2⁺) +²⁰Ne(¹⁶O,¹²C^*(4.44, 2⁺))²⁴Mg,²⁰Ne(¹⁶O,¹²C)²⁴Mg^*(6.01, 4⁺+6.43, 0⁺),²⁰Ne(¹⁶O,²⁰Ne)¹⁶O,²⁰Ne(¹⁶O,²⁰Ne^*(1.63, 2⁺))¹⁶O, and²⁰Ne(¹⁶O,²⁰Ne^*(4.25, 4⁺))¹⁶O reactions atθ _lab=13° fromE _c.m.=22.8 to 38.6 MeV have been subjected to a statistical analysis comprising of the calculations of the distribution of cross sections, deviation functions, cross-correlation functions, summed excitation functions, cross-channel correlation coefficients and coherence widths. The analysis confirms the existence of nonstatistical structures atE _c.m.=24.6, 27.8, 31.7 and 35.5 MeV, and identifies a new structure of the same nature atE _c.m. =25.6 MeV.     

Plasma Maser Theory of Whistler Waves in the Presence of Ion Cyclotron Turbulence

In this paper we consider the plasma maser theory of whistler waves in the presence of ion cyclotron waves in a magnetized plasma. In a plasma with low frequency ion cyclotron turbulence and a high frequency test whistler wave, growth of the whistler wave takes place because of the turbulent bremsstrahlung interaction between the resonant electrons and the modulated electric fields. The growth rate of the whistler wave is calculated and the results discussed.     

Triply bridged (1,3,5) cyclophanes from cystine and lanthionine linkers—a comparison

The condensation of benzene 1,3,5-tricarbonylchloride with cystine-di-Me [H₂N-CH(COOMe)-CH₂-S-S-CH₂-CH(COOMe)-NH₂] yielded triply bridged (1,3,5) cyclophane 1, which was shown by detailed spectral studies and molecular orbital calculations to have a D₃ symmetry with conformationally identical linkers and a spherical topology. In sharp contrast, the (1,3,5) cyclophane 2 from the rarely studied lanthionine di-Me [H₂N-CH(COOMe)-CH₂-S-CH₂-CH(COOMe)-NH₂], showed only a equatorial twofold symmetry. This work highlights the special properties of the -S-S- bridge in cystine, which makes it an exceptional synthon in nature and organic synthesis.     

Structural Characterization of Coordination Polymers of Nickel(II) and Zinc(II) with Polycarboxylate Ligands

Abstract  

The structural aspects of one-dimensional coordination polymer (1) of nickel(II) with 1,3,5-benzene tricarboxylate and a three-dimensional interpenetrating coordination polymer (2) of zinc(II) with 1,4-benzenedicarboxylate ligand are studied by single crystal X-ray diffraction analysis. Coordination polymer (1) forms a hydrogen bonded three dimensional network structures. The coordination polymer 1 having a composition [Ni₃(TMA)₂(H₂O)₁₂] _n where (TMA = trimesate anion), crystallizes in monoclinic crystal system with C2 space group and has a/?, 17.3387(4); b/?, 12.8748(4); c/?, 6.5302(2); β/°111.620(2); V/?³, 1355.20(7). The zinc coordination polymer 2 crystal system is orthorhombic, with space group Pbca. It has a/?, 14.5049(3); b/?, 17.1616(3); c/?, 18.1389(4); V/?³, 4515.27(16). The 1,4-benzenedicarboxylate three dimensional coordination polymer of zinc(II) comprises of novel hydroxo bridged tetranuclear zinc(II) secondary building units and has a composition [Zn₂(C₆H₄C₂O₄)_1.5{(CH₃)₂SO}₂(OH)] _n . Topological analysis of the three dimensional coordination polymer 2 shows that it has a two fold interpenetrating net topology.     

Resonant structures in24Mg+28Si elastic and inelastic scattering

The data on the excitation functions of²⁴Mg+²⁸Si elastic and inelastic (2⁺ ?0⁺, 2⁺ ?2⁺, 4⁺ ?0⁺ and 4⁺ ?2⁺) scattering fromE _c.m.=48.97 to 57.21 MeV have been subjected to a statistical analysis consisting of the calculations of deviation function, cross-correlation function, summed excitation function, cross-channel correlation coefficients, coherence widths, and the distribution of cross sections. Based on the outcome of the analysis resonant structures atE _c.m.=49.23, 50.02, 50.51, 52.10, 52.53, 53.27 and 54.14 MeV have been confirmed and three new structures of the same nature have been identified atE _c.m.=51.42, 54.88 and 55.60 MeV.     

Edge transport in 2D cold atom optical lattices

We theoretically study the observable response of edge currents in two-dimensional cold atom optical lattices. As an example, we use Gutzwiller mean-field theory to relate persistent edge currents surrounding a Mott insulator in a slowly rotating trapped Bose-Hubbard system to time of flight measurements. We briefly discuss an application, the detection of the Chern number using edge currents of a topologically ordered optical lattice insulator.     

Intergranular magnetoresistance in Sr2FeMoO6 from a magnetic tunnel barrier mechanism across grain boundaries

We present magnetization (M) and magnetoresistance (MR) data for a series of Sr2FeMoO6 samples with independent control on antisite defect and grain-boundary densities, which reveal several unexpected features, including a novel switching-like behavior of MR with M. These, in conjunction with model calculations, establish that the MR in Sr2FeMoO6 is dominantly controlled by a new mechanism, derived from the magnetic polarization of grain-boundary regions acting like spin valves, leading to behavior qualitatively different from that usually encountered in tunneling MR. We show that a simple and useful experimental signature for the presence of this spin-valve-type MR (SVMR) is a wider hysteresis in MR compared to that in M.     

Bell's inequality and universal quantum gates in a cold-atom chiral fermionic p-wave superfluid

We propose and analyze a probabilistic scheme to entangle two spatially separated topological qubits in a p{x}+ip{y} superfluid using controlled collisions between atoms in movable dipole traps and unpaired atoms inside vortex cores in the superfluid. We discuss how to test the violation of Bell's inequality with the generated entanglement. A set of universal quantum gates is shown to be implementable deterministically using the entanglement despite the fact that the entangled states can be created only probabilistically.     

Quantum computation using vortices and majorana zero modes of a px + ipy superfluid of fermionic cold atoms

We propose to use the recently predicted two-dimensional "weak-pairing" px + ipy superfluid state of fermionic cold atoms as a platform for topological quantum computation. In the core of a vortex, this state supports a zero-energy Majorana mode, which moves to finite energy in the corresponding topologically trivial "strong-pairing" state. By braiding vortices in the "weak-pairing" state, unitary quantum gates can be applied to the Hilbert space of Majorana zero modes. For readout of the topological qubits, we propose realistic schemes suitable for atomic superfluids.