On the variation of the structure of liquid deuterium fluoride with temperature

The structure of liquid deuterium fluoride has been measured using pulsed neutron diffraction and high energy x-ray diffraction techniques as a function of temperature. The neutron experiments were performed at T=296+/-2 K, 246+/-2 K, and 193+/-2 K and the x-ray measurements carried out at 296+/-2 K and 195+/-2 K. The x-ray pair correlation functions, which are dominated by fluorine-fluorine interactions, show the first peak at approximately 2.53+/-0.05 A remains very nearly invariant with decreasing temperature. Peaks around 4.5 and 5.0 A also appear at both temperatures in the x-ray data. In contrast, the intermolecular peaks in the total neutron pair correlation function show that significant systematic local structural changes occur as the temperature is lowered. The first intermolecular peak position shortens from 1.64+/-0.05 A at 296 K to 1.56+/-0.05 A at 195 K. Although there are overlapping contributions from the intermolecular hydrogen-fluorine and hydrogen-hydrogen correlations, it is clear that the temperature dependent structural changes are largely due to a rearrangement of the deuterium atom positions in the fluid. By comparison with partial structure factor data the hydrogen bonds appear to become more linear at lower temperatures.     

非结构网格上一种新型的高分辨率高精度无波动的有限元格式

在非结构网格上构造出无波动无自由参数耗散性有限元格式 ,即NND有限元格式 .通过若干个典型二维跨音速和超音速可压缩无粘定常流动的算例证明这确是一个高精度的 ,对激波具有高分辨率的无波动的新型有限元格式 .特别与网格自适应相结合 ,可得到十分满意的结果     

Renormalization of the inverse square potential

The quantum-mechanical D-dimensional inverse square potential is analyzed using field-theoretic renormalization techniques. A solution is presented for both the bound-state and scattering sectors of the theory using cutoff and dimensional regularization. In the renormalized version of the theory, there is a strong-coupling regime where quantum-mechanical breaking of scale symmetry takes place through dimensional transmutation, with the creation of a single bound state and of an energy-dependent s-wave scattering matrix element.     

分子内结构环境对解离能的影响

为了理解化学键的这一结构效应, 本文对具有相同化学键而分子内结构环境不同的系列分子进行了计算研究, 讨论了化学键结构环境对解离能的影响.     

Saturation Effects and the Colored Pump Noise in a Dye Laser

We investigate the statistical properties of two single-mode dye-laser models-the colored-loss-noise model and the colored-gain-noise model. Analytic expressions of the probability,the mean and the variance of the steady-state laser intensity are obtained through the unified expansion theory [Phys. Rev. A43 (1991) 700]. By comparison we find that when the cavity decay rate for the electric field is large and the pump parameter a₀ is small, the differences of the results of the two laser models are small. Otherwise, the differences are large. And the correlation time of the noise has very obvious influence on the results of the two models.