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31.
N. I. Makarova E. N. Shepelenko A. V. Metelitsa V. A. Bren’ V. I. Minkin 《Russian Chemical Bulletin》2013,62(11):2424-2429
Novel asymmetric dihetarylethenes, viz., 3-(1-isopropyl-5-methoxy-2-methyl-1H-indol-3-yl)-4-(3-thienyl)furan-2,5-dione and 1-alkyl/aryl-3-(1-isopropyl-5-methoxy-2-methyl-1H-indol-3-yl)-4-(3-thienyl)-1H-pyrrole-2,5-diones, were obtained. These dihetarylethenes exhibit photochromism in solutions. Replacement of the N-methyl group in the indole fragment by the N-isopropyl group imparts photochromic properties to the resulting furan-2,5-dione derivative. The open forms of (N-isopropylindol-3-yl)pyrrole-2,5-diones are characterized by lower quantum yields of fluorescence, and their cyclic forms are thermally more stable. 相似文献
32.
A. S. Burlov V. G. Vlasenko D. A. Garnovskii N. V. Polosareva A. S. Antsyshkina G. G. Sadikov V. S. Sergienko A. V. Churakov Ya. V. Zubavichus E. I. Mal’tsev A. V. Dmitriev D. A. Lypenko A. S. Cheprasov G. S. Borodkin A. V. Metelitsa 《Russian Journal of Inorganic Chemistry》2014,59(7):721-732
Chemical and electrochemical syntheses of zinc(II) and cadmium(II) complexes based on tetradentate Schiff bases (H2L1 and H2L2) resulting from condensation of 2-tosylaminobenzaldehyde with 3,6-dioxa-1,8-octanediamine or 4,9-dioxa-1,12-dodecanediamine were performed. The structure, composition, and properties of the complexes were studied by elemental analysis, IR, 1H NMR, and UV spectroscopy, X-ray absorption spectroscopy, and X-ray diffraction. The zinc(II) and cadmium(II) complexes luminesce in a DMF solution in the blue spectral region (λPL = 425–433 nm), the photoluminescence quantum yield φ being 0.25–0.30. Multilayer zinc(II)- and cadmium(II)-based electroluminescent structures with green-blue emission of the exciplex nature were fabricated. 相似文献
33.
S. A. Nikolaevskii Yu. V. Koshchienko A. V. Chernyshev A. S. Burlov A. S. Cheprasov G. G. Aleksandrov M. A. Kiskin A. V. Metelitsa 《Russian Journal of Coordination Chemistry》2014,40(7):468-472
1-Alkyl-2-(2-tosylaminophenyl)-5-aminobenzimidazole and related zinc complexes are synthesized. The structure of the complex with zinc pivalate is determined by X-ray diffraction analysis. The fluorescence with the anomalous Stokes shift of the benzimidazole ligand system in solution is transformed into the fluorescence with the normal Stokes shift upon complex formation due to blocking the mechanism of intramolecular proton transfer in the excited state or upon the transition to the crystalline state formed by zwitterionic forms that are generated due to the proton transfer from the sulfonamide group to the amino group. 相似文献
34.
Ivakhnenko T. E. Makarova N. I. Burlov A. S. Ivakhnenko E. P. Knyazhanskii M. I. Metelitsa A. V. Garnovskii A. D. 《Russian Journal of Organic Chemistry》2002,38(7):1018-1022
Study of the absorption and luminescence spectra of Schiff bases derived from o-(p-tolylsulfonylamino)benzaldehyde has shown that these systems, like those derived from salicylaldehyde, are characterized by intramolecular proton transfer in the excited and ground electronic states. This process is responsible for the appearance at 77 K of fluorescence with an anomalous Stokes shift and formation of ketone structures. Unlike o-[alkyl(or aryl)iminomethyl]phenols, o-[alkyl(or aryl)iminomethyl]anilines do not give rise to acoplanarization of the ketone fragment, which could follow intramolecular proton transfer in the excited state and is responsible for fluorescence with an anomalous Stokes shift and formation of colored structures. 相似文献
35.
R Nirmala V Sankaranarayanan K Sethupathi AV Morozkin T Geethakumary Y Hariharan 《Pramana》2002,58(5-6):1101-1104
New R
2Ti3Ge4 (R=Dy, Ho and Er) intermetallic compounds have been synthesized and characterized by X-ray diffraction and low temperature ac
magnetic susceptibility, electrical resistivity and thermoelectric power measurements were carried out. The compounds crystallize
in the parent, Sm5Ge4-type orthorhombic structure (space group Pnma) and lanthanide contraction is observed as one moves along the rare-earth series.
The changeover from paramagnetic to antiferromagnetic phase happens at low temperatures and the ordering temperature scales
with the de Gennes factor. The electrical resistivity is metallic with a negative curvature above 100 K. Thermopower displays
a weak maximum at temperatures less than 50 K signifying the possible phonon and magnon drag effects. 相似文献
36.
A. V. Chernyshev V. V. Tkachev I. A. Rostovtseva N. A. Voloshin E. V. Solov’eva A. V. Metelitsa S. M. Aldoshin V. I. Minkin 《Doklady Chemistry》2016,471(2):368-372
8-(1,3-Benzoxazol-2-yl)-substituted spirobenzopyran is a new chromogenic system in which complexation with metal ions accompanied by a change in color can be controlled by photoirradiation. According to X-ray crystallography, the merocyanine ligand in the zinc complex has the TTT conformation. 相似文献
37.
O. G. Nikolaeva A. V. Metelitsa A. S. Cheprasov O. Yu. Karlutova A. G. Starikov A. D. Dubonosov V. A. Bren´ V. I. Minkin 《Russian Chemical Bulletin》2016,65(4):944-951
A computer search for new photoactive compounds among indoline spiropyrans of coumarin series was carried out using DFT B3LYP/6-31G(d,p) method. Based on the data obtained, the spiropyrans containing a formylcoumarin fragment annulated to the 2H-pyran ring and possessing photochromic properties were synthesized. The structure and photochromism of these compounds were studied by 1H NMR, IR, and UV/Vis spectroscopy. The introduction of a formyl group into the coumarin moiety of spiropyrans led to a bathochromic shift of the long wavelength absorption maxima of merocyanine isomers, as well as to a considerable increase in their lifetime. 相似文献
38.
Yu. V. Koshchienko A. S. Burlov N. I. Makarova V. G. Vlasenko S. A. Nikolaevskii M. A. Kiskin G. G. Alexandrov D. A. Garnovskii A. V. Metelitsa V. I. Minkin 《Russian Journal of General Chemistry》2017,87(1):76-85
N-{2-[5-(2-Hydroxyphenylmethyleneamino)-1-alkylbenzimidazol-2-yl]phenyl}-4-methyl-benzenesulfamides (H2L) and their zinc complexes Zn2L2 were synthesized. The structure of the ligands and complexes was studied by IR, UV, 1Н NMR, X-ray absorption spectroscopy, and X-ray diffraction analysis. The complexes show green photoluminescence (λfl = 492 nm) with quantum yields φ = 0.07–0.17. 相似文献
39.
N. A. Voloshin A. V. Chernyshev A. V. Metelitsa E. B. Gaeva V. I. Minkin 《Russian Chemical Bulletin》2011,60(9):1921-1926
Novel photochromic 5??-(1,3-benzothiazol-2-yl)-substituted spiro[indoline-2,3??-naphthopyrans] possessing luminescence properties in both the cyclic and merocyanine forms were synthesized. Unlike the 8??-(1,3-benzothiazol-2-yl)-substituted benzopyran analogs, the synthesized compounds are characterized by the lower relative stability of the merocyanine isomers. 相似文献
40.
A. V. Chernyshev I. V. Dorogan N. A. Voloshin A. V. Metelitsa V. I. Minkin 《Russian Chemical Bulletin》2011,60(3):456-464
The spectral and kinetic properties of 5-(4,5-diphenyl-1,3-oxazol-2-yl)spiro[indoline-naphthopyran] derivatives were studied
by experimental and theoretical methods. The additional long-wavelength maximum in the absorption spectra of compounds studied
is due to the introduction of a diphenyloxazole fragment and corresponds to a π-π* electronic transition with a partial charge
transfer character. Substituents have little effect on the kinetic parameters of the spironaphthopyrans studied. 相似文献