Separation and determination of the valence states of metal ions by ring colorimetry incorporating tropolone: Application to chromium and vanadium

Microchimica Acta - Rapid separation and determination of chromium and vanadium valence states inμg quantities from their mixed solutions have been accomplished by the Weisz ring oven. Aqueous...     

Electrical transport in bulk amorphous selenium

D.C. conductivity measurements have been made as a function of temperature and external electric field on bulk amorphous selenium. A decrease in the activation energy with increase of electric field has been observed. This has been interpreted in terms of a mixed, thermally activated and trap limited conduction process.     

Portfolio selection with a minimax measure in safety constraint

In this paper, we attempt to design a portfolio optimization model for investors who desire to minimize the variation around the mean return and at the same time wish to achieve better return than the worst possible return realization at every time point in a single period portfolio investment. The portfolio is to be selected from the risky assets in the equity market. Since the minimax portfolio optimization model provides us with the portfolio that maximizes (minimizes) the worst return (worst loss) realization in the investment horizon period, in order to safeguard the interest of investors, the optimal value of the minimax optimization model is used to design a constraint in the mean-absolute semideviation model. This constraint can be viewed as a safety strategy adopted by an investor. Thus, our proposed bi-objective linear programming model involves mean return as a reward and mean-absolute semideviation as a risk in the objective function and minimax as a safety constraint, which enables a trade off between return and risk with a fixed safety value. The efficient frontier of the model is generated using the augmented -constraint method on the GAMS software. We simultaneously solve the ratio optimization problem which maximizes the ratio of mean return over mean-absolute semideviation with same minimax value in the safety constraint. Subsequently, we choose two portfolios on the above generated efficient frontier such that the risk from one of them is less and the mean return from other portfolio is more than the respective quantities of the optimal portfolio from the ratio optimization model. Extensive computational results and in-sample and out-of-sample analysis are provided to compare the financial performance of the optimal portfolios selected by our proposed model with that of the optimal portfolios from the existing minimax and mean-absolute semideviation portfolio optimization models on real data from S&P CNX Nifty index.     

Efficient design of perovskite solar cell using mixed halide and copper oxide

Solar cells based on perovskites have emerged as a transpiring technology in the field of photovoltaic. These cells exhibit high power conversion efficiency. The perovskite material is observed to have good absorption in the entire visible spectrum which can be well illustrated by the quantum efficiency curve. In this paper, theoretical analysis has been done through device simulation for designing solar cell based on mixed halide perovskite. Various parameters have efficacy on the solar cell efficiency such as defect density, layer thickness, doping concentration, band offsets, etc. The use of copper oxide as the hole transport material has been analyzed. The analysis divulges that due to its mobility of charge carriers, it can be used as an alternative to spiro-OMeTAD. With the help of simulations, reasonable materials have been employed for the optimal design of solar cell based on perovskite material. With the integration of copper oxide into the solar cell structure, the results obtained are competent enough. The simulations have shown that with the use of copper oxide as hole transport material with mixed halide perovskite as absorber, the power conversion efficiency has improved by 6%.The open circuit voltage has shown an increase of 0.09 V, short circuit current density has increased by 2.32 m A/cm~2, and improvement in fill factor is 8.75%.     

The Calculations that Gave Einstein “Heart Palpitations”

In what follows, I reply to the preceding article by Michel Janssen and Robert Schulmann, which itself was a response to my article on One month in the history of the discovery of general relativity theory, published in the February 1998 issue of this journal. I stand by the historical analysis and conclusions presented in my original article.     

Conduction mechanism in amorphous Si films

dc conductivity as a function of temperature has been measured for as-evaporated and annealed films of amorphous Si, grown by the vacuum evaporation technique. The experimental data suggest that conduction in the higher temperature range (～175–300 K) is by the thermally activated holes in the localized states near the valence band edge while conduction in the lower temperature range (～77–175 K) is found to be thermally assisted tunnelling in the localized states near the Fermi level. The activation energy for both the processes is found to increase with an increase in the annealing temperature. The average hopping distance, calculated for conduction near the Fermi level, is also found to increase with an increase in the annealing temperature.     

Study of dielectric properties of styrene-acrylonitrile graphite sheets composites in low and high frequency region

Conducting polymer composites should have a high dielectric constant and a high dissipation factor in the low and high frequency regions if they are to be used in charge storing devices, decoupling capacitors and electromagnetic interference shielding applications. Currently, extensive research is being carried out to enhance the dielectric constants of graphite-polymer, ceramic powder-polymer, metal powder-polymer and nanotube-polymer composites in the low frequency region. In this paper, we present the dielectric properties of styrene-acrylonitrile (SAN)-graphite sheets (GS) composites in the low and high frequency ranges. SAN-GS composites were prepared by the mixing process and by the hot compression mold technique. The composites showed a high dielectric constant and a high dissipation factor in the low and radio frequency region. Furthermore, the EMI shielding properties of these composites are evaluated in the radio frequency range. The conductivity and the dielectric constant of the SAN/GS composites increased with the addition of GS composites, and followed the power law model of percolation theory. The dielectric constant and the dissipation factor of the composites were analyzed according to the low and high frequency region.     

Superposition of Quantum Confinement Energy (SQCE) model for estimating shell thickness in core-shell quantum dots: validation and comparison

A novel theoretical model based on superposition of core and shell band-gaps, termed as SQCE model, is developed and reported here, which enables one to estimate the shell thickness in a core-shell quantum dot (QD), which is critically important in deciding its optical and electronic properties. We apply the model to two experimental core-shell QD systems, CdSe-CdS and CdSe-ZnS, which we synthesize by microemulsion method. We synthesize and study two series of samples, R and S to study the optical properties. The core size is varied in the R-series (by varying water-to-surfactant ratio, R) whereas the shell thickness is varied in the S-series (by varying the shell-to-core precursor molar ratio, S). The core and core-shell QDs from R-series and S-series are characterized for particle size, shape and crystallographic information. The shell thickness for all core-shell QD samples is estimated by SQCE model, and experimentally measured with TEM and SAXS. A close match is observed between experimental values and model predictions, thus validating the model. Further, the optimum shell thickness (corresponding to maximum quantum yield) values for CdS and ZnS over a 4.26 nm CdSe core have been estimated as 0.585 nm and 0.689 nm, respectively, from the SQCE model. The SQCE model developed in this work is applicable to other core-shell quantum dots also, such as CdTe-CdS, CdTe-CdSe and CdS-ZnS, and will serve as a useful complement to experimental measurement.     

Application of Atanassov’s I-fuzzy set theory to matrix games with fuzzy goals and fuzzy payoffs

We aim to extend some results in [6, 7, 8, 2] on two person zero sum matrix games (TPZSMG) with fuzzy goals and fuzzy payoffs to I-fuzzy scenario. Because the payoffs of the matrix game are fuzzy numbers, the aspiration levels of the players are fuzzy as well. It is reasonable to believe that there is some indeterminacy in estimating the aspiration levels of both players from their respective expected pay offs. This situation is modeled in the game using Atanassov??s I-fuzzy set theory. A new solution concept is proposed for such games and a procedure is outlined to obtain the degrees of suitability of the aspiration levels for each of the two players.