Evaluation of formant-like features on an automatic vowel classification task

Numerous attempts have been made to find low-dimensional, formant-related representations of speech signals that are suitable for automatic speech recognition. However, it is often not known how these features behave in comparison with true formants. The purpose of this study was to compare two sets of automatically extracted formant-like features, i.e., robust formants and HMM2 features, to hand-labeled formants. The robust formant features were derived by means of the split Levinson algorithm while the HMM2 features correspond to the frequency segmentation of speech signals obtained by two-dimensional hidden Markov models. Mel-frequency cepstral coefficients (MFCCs) were also included in the investigation as an example of state-of-the-art automatic speech recognition features. The feature sets were compared in terms of their performance on a vowel classification task. The speech data and hand-labeled formants that were used in this study are a subset of the American English vowels database presented in Hillenbrand et al. [J. Acoust. Soc. Am. 97, 3099-3111 (1995)]. Classification performance was measured on the original, clean data and in noisy acoustic conditions. When using clean data, the classification performance of the formant-like features compared very well to the performance of the hand-labeled formants in a gender-dependent experiment, but was inferior to the hand-labeled formants in a gender-independent experiment. The results that were obtained in noisy acoustic conditions indicated that the formant-like features used in this study are not inherently noise robust. For clean and noisy data as well as for the gender-dependent and gender-independent experiments the MFCCs achieved the same or superior results as the formant features, but at the price of a much higher feature dimensionality.     

Reduced Load Equivalence under Subexponentiality

The stationary workload W _A+B ^φ of a queue with capacity φ loaded by two independent processes A and B is investigated. When the probability of load deviation in process A decays slower than both in B and $e^{ - \sqrt x } $ , we show that W _A+B ^φ is asymptotically equal to the reduced load queue W _A ^φ?b , where b is the mean rate of B. Given that this property does not hold when both processes have lighter than $e^{ - \sqrt x } $ deviation decay rates, our result establishes the criticality of $e^{ - \sqrt x } $ in the functional behavior of the workload distribution. Furthermore, using the same methodology, we show that under an equivalent set of conditions the results on sampling at subexponential times hold.     

Perturbation analysis of quasi-static behavior of brush-type super flywheels

The purpose of this paper is to present an improved analysis of the quasi-static behavior of a typical radial filament in a brush-type super flywheel. The material is assumed to be perfectly elastic with a finite Poisson's ratio. It is shown that the rotational speed at which tensile instability resulting in filament necking occurs can be considerably lower than that predicted by previous analyses reported in the literature. Numerical results are presented in dimensionless form for ranges of parameters of current design interest.     

Spontaneous coherent phase transition of polaritons in CdTe microcavities

We report on evidence for polariton condensation out of a reservoir of incoherent polaritons. Polariton population and first-order coherence are investigated by spectroscopic imaging of the far-field emission of a CdTe-based microcavity under nonresonant pumping. With increasing pumping power, stimulated emission with thresholdlike behavior and spectral narrowing is observed in the strong exciton-photon coupling regime. We show that it comes from a narrow ring in k space, exhibiting enhanced spatial and angular coherence at the stimulation onset.     

Cascade of bulk magnetic phase transitions in NaxCoO2 as studied by muon spin rotation

Using muon spin rotation, well-defined bulk approximately 100% magnetic phases in NaxCoO2 are revealed. A novel magnetic phase is detected for x=0.85 with the highest transition temperature ever observed for x>or=0.75. This stresses the diversity of x>or=0.75 magnetic phases and the link between magnetic and structural degrees of freedom. For the charge-ordered x=0.50 compound, a cascade of transitions is observed below 85 K. From a detailed analysis of our data, we conclude that the ordered moment varies continuously with temperature and suggest that the two secondary transitions at 48 and 29 K correspond to a moderate reorientation of antiferromagnetically coupled moments.     

Noninvasive in situ visualization of supported catalyst preparations using multinuclear magnetic resonance imaging

Multinuclear magnetic resonance imaging (MRI) is employed as a new noninvasive tool for monitoring supported catalyst preparation by visualizing precursor transport within the porous support. In particular, liquid phase 31P MRI experiments were used to visualize the dynamics of H3PO4 penetration into an alumina pellet and have revealed a strong interaction of H3PO4 with the support. Solid state 31P MRI was applied to map the distribution of the adsorbed phosphate inside the support after its drying. Comparison of the liquid phase and solid phase MRI results confirms the correlation of the phosphate distribution in the liquid phase during impregnation and the phosphate adsorbed on the support. The possibility to monitor the transport of metal atoms within the support by a direct detection of their NMR signal is demonstrated for 195Pt nucleus during impregnation of an alumina pellet with an aqueous solution of H2PtCl6. Other possible strategies for the utilization of MRI to characterize in situ the preparation of supported catalysts and other supported materials are briefly discussed.     

Modeling the electric field third-order nonlinear responses of an infinite aggregate of hexatriene chains using the electrostatic interaction model

A classical electrostatic polarization scheme using the additive distribution procedure has been applied to determine the static longitudinal polarizability and second hyperpolarizability of a all-trans hexatriene molecule in an infinite stretched fiber. The parameters have been derived from ab initio coupled-perturbed Hartree-Fock calculations and the electrostatic scheme has been validated via comparison with ab initio results on small clusters. Upon packing, the polarizability of all-trans hexatriene increases by 7% whereas the second hyperpolarizability increases by as much as 61%. These increases result from the balance between the enhancement of the (hyper)polarizability due to collinear packing and the reduction associated with lateral packing.     

Synchrotron radiation effects on catalytic systems as probed with a combined in-situ UV-vis/XAFS spectroscopic setup

UV-vis spectroscopy was used in a combined in-situ UV-vis/XAFS spectroscopic setup to study the synchrotron radiation effect on aqueous homogeneous copper solutions. Two different systems were studied. In the first study, the focus was on a copper bipyridine-catalyzed oxidation of benzyl alcohol to benzaldehyde with 2,2,6,6- tetramethylpiperidinyl-1-oxy and base as cocatalysts. It was found that when the reaction mixture is exposed to the X-ray beam, the features present in the in-situ UV-vis spectrum develop differently compared to the situation when the reaction mixture is not exposed to the X-ray beam. Besides a temperature effect of the X-ray beam, both the UV-vis analysis and the XAFS analysis showed a reducing influence of the X-ray beam on the sample. To investigate this in more detail, we studied a series of dilute aqueous copper solutions from different precursor salts, viz., Cu(NO3)2.3H2O, CuSO4.5H2O, CuCl2, and CuBr2. It was found that the different aqueous copper solutions have different stabilities under the influence of the X-ray beam. Especially the solution from the CuCl2 precursor salt was found to be unstable and to be subjected to reduction. These examples illustrate the need for a second technique, such as in-situ UV-vis spectroscopy, to evaluate the effect of synchrotron radiation used to measure in-situ XAFS on catalytic systems.     

New synthesis of imidazole derivatives from cyanobenzenes

An efficient access to 4-aryl imidazole scaffolds is described in two steps and one operation. Cyanoaryl-imidazolines are easily obtained by a (3?+?2) heterocyloaddition involving cyanobenzenes as dipolarophiles and a non-stabilized azomethine ylide as an electron-rich 1,3-dipole. Oxidation of the crude mixture affords an efficient two-steps access to the corresponding imidazoles.     

Uniformly Oriented Zeolite ZSM‐5 Membranes with Tunable Wettability on a Porous Ceramic

Facile fabrication of well‐intergrown, oriented zeolite membranes with tunable chemical properties on commercially proven substrates is crucial to broadening their applications for separation and catalysis. Rationally determined electrostatic adsorption can enable the direct attachment of a b‐oriented silicalite‐1 monolayer on a commercial porous ceramic substrate. Homoepitaxially oriented, well‐intergrown zeolite ZSM‐5 membranes with a tunable composition of Si/Al=25–∞ were obtained by secondary growth of the monolayer. Intercrystallite defects can be eliminated by using Na⁺ as the mineralizer to promote lateral crystal growth and suppress surface nucleation in the direction of the straight channels, as evidenced by atomic force microscopy measurements. Water permeation testing shows tunable wettability from hydrophobic to highly hydrophilic, giving the potential for a wide range of applications.