全文获取类型
收费全文 | 1744篇 |
免费 | 49篇 |
国内免费 | 14篇 |
专业分类
化学 | 1383篇 |
晶体学 | 21篇 |
力学 | 10篇 |
数学 | 137篇 |
物理学 | 256篇 |
出版年
2021年 | 12篇 |
2020年 | 17篇 |
2019年 | 28篇 |
2018年 | 17篇 |
2017年 | 18篇 |
2016年 | 28篇 |
2015年 | 26篇 |
2014年 | 42篇 |
2013年 | 83篇 |
2012年 | 90篇 |
2011年 | 100篇 |
2010年 | 50篇 |
2009年 | 65篇 |
2008年 | 86篇 |
2007年 | 86篇 |
2006年 | 92篇 |
2005年 | 91篇 |
2004年 | 93篇 |
2003年 | 75篇 |
2002年 | 76篇 |
2001年 | 43篇 |
2000年 | 56篇 |
1999年 | 26篇 |
1998年 | 28篇 |
1997年 | 21篇 |
1996年 | 34篇 |
1995年 | 16篇 |
1994年 | 24篇 |
1993年 | 20篇 |
1992年 | 18篇 |
1991年 | 12篇 |
1990年 | 19篇 |
1989年 | 24篇 |
1988年 | 18篇 |
1987年 | 13篇 |
1986年 | 16篇 |
1985年 | 19篇 |
1984年 | 27篇 |
1983年 | 13篇 |
1982年 | 16篇 |
1981年 | 20篇 |
1980年 | 12篇 |
1979年 | 11篇 |
1978年 | 12篇 |
1977年 | 20篇 |
1976年 | 14篇 |
1975年 | 18篇 |
1974年 | 12篇 |
1973年 | 10篇 |
1967年 | 6篇 |
排序方式: 共有1807条查询结果,搜索用时 257 毫秒
991.
992.
Molecular-dynamics studies of binary mixtures of Lennard-Jones fluids with differing component sizes
Molecular-dynamics calculations have been carried out for six pure liquids and three binary mixtures of Lennard-Jones fluids with differing component sizes and attractive interactions. Internal energies, radial-distribution functions, velocity autocorrelation functions and self-diffusion coefficients have been calculated and are discussed together with our previous results. The three mixtures obey the Lorentz-Berthelot rules and show endothermic mixing. The excess internal energy ΔUE of mixtures with equal-sized components is symmetrical with respect to the mole fraction, but those for mixtures of different-sized components become asymmetrical. A comparison is made between the present ΔUE data and those for real mixtures. 相似文献
993.
Hiizu Nakanishi Kiyoshi Hayashi Hiroyuki Mori 《Communications in Mathematical Physics》1988,117(2):203-213
Unknotted ring defects in ordered media are classified in terms of the homotopy theory. It is also investigated what type of point defects will appear when a radius of the ring defect tends to zero. 相似文献
994.
Six steroid itN-acctylglueosaminides, pavoninins-1 to -6, have been isolated from the defense secretion of the sole P. pavoninus guided by ichthyotoxicity and hemolytic activity, and their structures determined to be 1–6 by spcctroscopic studies and chemical correlations. The pavoninins are considered to be the factors responsible for the repellent property of the sole against predatory fishes. 相似文献
995.
Y. Tanaka H. Sakuraba Y. Oka H. Nakanishi 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(3-4):841-850
The gas-solid halogenation and hydrohalogenation using microcrystalline cyclodextrin complexes are found to be efficient for production of the optical active halides of ethyltrans-cinnamate in moderate optical yields: On exposure to HBr at 20°C for 15–20 hr, the cinnamate in solid - and -cyclodextrin complexes yields ethyl R-(+)-3-bromo-3-phenylpropanoate in 46% e.e., and S-(–)-enantiomer in 31% e.e., respectively. No addition nor substitution products are obtained with HC1 vapor at 0–50°C for 15–65 hr. Bromination of the -cyclodextrin complex results in the formation of optical active ethylerythro-2,3-dibromo-3-phenylpropanoate, while chlorination gives the optical active mixture oftrans andcis addition products, ethylerythro- andthreo-2,3-dichloro-3-phenylpropanoates in 60–80% yields. Mechanism of chiral induction in the present gas-solid reaction has been proposed on the basis of the crystal structure of the complex. 相似文献
996.
The present study discusses the results of theoretical calculations obtained at the B3LYP/ 6-31G level on the structural, electronic, and energetic properties of Ti-silicalites. Particularly, the relevance of 5T cluster models, either H- or OH-terminated, in large-scale calculations has been critically considered. It was shown that an open surface structure with one OH group and a closed-bulk structure with no bonded OH group at the Ti site are responsible for the observed UV-vis properties of Ti-silicalite materials. Both water and methanol can preferably interact with Ti-silicalites through the H-bonding mechanism, while ammonia can form either H-bonded or coordination complexes. The calculations support the existence of highly dispersed Ti sites in a tetrahedral environment only in Ti-silicalites because an increase in the coordination number of the Ti site by next-neighbor lattice oxygens is the energetically less favorable process. 相似文献
997.
998.
999.
Hoon Park HyunSeock Jie Keun-Hwa Chae Jong-Ku Park Masakazu Anpo Dok-Yol Lee 《Current Applied Physics》2008,8(6):778-783
Anatase-type TiO2 nanopowders less than 10 nm in average diameter were synthesized by a chemical vapor synthesis method. The TiO2 nanopowders showed very poor photocatalytic properties, in spite of their large surface area. With subsequent heat treatment of the TiO2 powders, their photocatalytic properties determined by measuring the degradation of 2-propanol were improved at temperatures up to 600 °C and then diminished along with formation of a rutile phase. This improvement in the photocatalytic properties of TiO2 nanopowders was attributed to both a morphology change and a change in the electronic surface characteristics of TiO2 particles during heat treatment. 相似文献
1000.
Z.-B. Sun X.-Z. Dong S. Nakanishi W.-Q. Chen X.-M. Duan S. Kawata 《Applied Physics A: Materials Science & Processing》2007,86(4):427-431
A log-pile photonic crystal of CdS nanoparticles–polymer nanocomposites was successfully fabricated by a novel method combining
the two-photon polymerization technique and in situ synthesis of CdS nanoparticles in a polymer matrix. The photonic band
gap of the three-dimensional (3D) log-pile photonic crystal is confirmed and becomes more effective for CdS nanoparticles–polymer
nanocomposites than polymer doped with Cd2+ ions, because the nanocomposites possess a higher refractive index than the polymer. The proposed concept in the new fabrication
method for a 3D microstructure of polymer nanocomposites should be of critical importance in providing a general methodology
for functionalization of materials via functional nanocomposites used in the field of laser microstructure fabrication.
PACS 42.70.Qs; 78.66.Sq; 81.40.Tv; 82.35.Np; 82.50.Pt 相似文献