Extensive quinoidal oligothiophenes with dicyanomethylene groups at terminal positions as highly amphoteric redox molecules

A series of highly extensive quinoidal oligothiophenes carrying a dicyanomethylene group at both terminal positions is synthesized. As the quinoidal structures extend, they have highly amphoteric abilities and show strong electronic absorptions in the visible to near-infrared region. The higher homologues, quinquethiophene and sexithiophene, exist as equilibrium mixtures with the biradical species.     

Studies on the syntheses of azole derivatives. Part I. Formation of 1-substituted-3-hydroxy-1H-indazole and I-substituted benzimidazolin-2-one derivatives by thermal reaction of N-substituted-N-arylcarbamoyl azides.

The formation of 1-substituted-3-hydroxy-1H-indazole and 1-substituted-benzimidazolin-2-one derivatives by thermal reaction of N-substituted-N-arylcarbamoyl azides was examined.     

Dependence of tracking error characteristics on objective lens shift for in-line-type differential push-pull methods using segmented gratings

In this paper, we present the validity of in-line-type differential push-pull methods using segmented gratings with respect to the radial shift of an objective lens by numerical calculation for the first time. In these differential push-pull methods, the segmented gratings for generating sub spots are divided into two to four regions each with a specific phase value and a width. Tracking error signals are calculated with respect to the objective lens shift under parameter conditions of the widths of the segmented regions. The obtained results show that the grating of the simpler configuration with two regions reveals good compatibility between DVD-R and DVD-RAM compared with those with three or four regions     

Synthetic studies on taxol: highly stereoselective construction of the taxol C-ring via SN2' reduction of an allylic phosphonium salt

[reaction: see text] The highly stereoselective construction of the C3 stereogenic center of the taxol C-ring is described. The trans isomer at the C3-C8 position of the taxol C-ring, which is required for the total synthesis, as well as its diastereomeric cis isomer were successfully synthesized with highly diastereoselective S(N)2' reduction of the allylic phosphonium salts.     

Research on Liebeskind-Srogl coupling/intramolecular Diels-Alder reaction cascade

The Liebeskind-Srogl coupling/intramolecular Diels-Alder (IMDA) reaction cascade that stereoselectively affords a tricarbocyclic compound with a trans–trans-cis fused ring system including an all-carbon quaternary stereogenic center at the ring junction is described. The cascade reactions proceed quickly and stereoselectively afford the products within 2?h at room temperature in the presence of a suitable thioester. The developed protocol as well as the prepared chiral compounds are useful for the enantioselective total synthesis of terpenoids with the trans–trans-cis fused ring system.     

Photoluminescent properties and molecular structures of [NaphAu(PPh(3))] and [mu-Naph {Au(PPh(3))}(2)] ClO(4) (Naph = 2-naphthyl)

The complexes [NaphAu(PPh(3))], and [mu-Naph{Au(PPh(3))}(2)]ClO(4), having the Au-C (aromatic) bond have been synthesized and characterized. The unique structure of with two gold atoms bridged by a naphthyl group has been determined by X-ray crystallography. The intramolecular Au-Au separation in is 2.7731(4) A. Upon excitation at 266 nm, both complexes display intraligand phosphorescence at room temperature in solution and in solid state.