全文获取类型
收费全文 | 1512篇 |
免费 | 93篇 |
国内免费 | 6篇 |
专业分类
化学 | 1192篇 |
晶体学 | 4篇 |
力学 | 27篇 |
数学 | 173篇 |
物理学 | 215篇 |
出版年
2023年 | 16篇 |
2022年 | 21篇 |
2021年 | 52篇 |
2020年 | 31篇 |
2019年 | 40篇 |
2018年 | 27篇 |
2017年 | 32篇 |
2016年 | 74篇 |
2015年 | 64篇 |
2014年 | 58篇 |
2013年 | 104篇 |
2012年 | 86篇 |
2011年 | 101篇 |
2010年 | 58篇 |
2009年 | 56篇 |
2008年 | 80篇 |
2007年 | 95篇 |
2006年 | 64篇 |
2005年 | 76篇 |
2004年 | 67篇 |
2003年 | 48篇 |
2002年 | 46篇 |
2001年 | 15篇 |
2000年 | 19篇 |
1999年 | 15篇 |
1998年 | 18篇 |
1997年 | 13篇 |
1996年 | 20篇 |
1995年 | 15篇 |
1994年 | 15篇 |
1993年 | 12篇 |
1992年 | 12篇 |
1991年 | 8篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1987年 | 13篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1978年 | 9篇 |
1977年 | 8篇 |
1975年 | 6篇 |
1973年 | 7篇 |
1972年 | 5篇 |
1969年 | 5篇 |
1966年 | 5篇 |
排序方式: 共有1611条查询结果,搜索用时 31 毫秒
91.
Pol Besenius 《Journal of polymer science. Part A, Polymer chemistry》2017,55(1):34-78
The self‐assembly into supramolecular polymers is a process driven by reversible non‐covalent interactions between monomers, and gives access to materials applications incorporating mechanical, biological, optical or electronic functionalities. Compared to the achievements in precision polymer synthesis via living and controlled covalent polymerization processes, supramolecular chemists have only just learned how to developed strategies that allow similar control over polymer length, (co)monomer sequence and morphology (random, alternating or blocked ordering). This highlight article discusses the unique opportunities that arise when coassembling multicomponent supramolecular polymers, and focusses on four strategies in order to control the polymer architecture, size, stability and its stimuli‐responsive properties: (1) end‐capping of supramolecular polymers, (2) biomimetic templated polymerization, (3) controlled selectivity and reactivity in supramolecular copolymerization, and (4) living supramolecular polymerization. In contrast to the traditional focus on equilibrium systems, our emphasis is also on the manipulation of self‐assembly kinetics of synthetic supramolecular systems. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 34–78 相似文献
92.
93.
Desaktivierung von Pd‐Katalysatoren zur Acetoxylierung: direkte Beobachtung durch XPS‐Untersuchungen
94.
95.
Vlasta Závišová Martina KonerackáMarta Mú?ková Jana LazováAlena Juríková Gábor LanczNatália Tomašovi?ová Milan TimkoJozef Ková? Ivo VávraMartin Fabián Artem V. Feoktystov Vasil M. GaramusMikhail V. Avdeev Peter Kop?anský 《Journal of magnetism and magnetic materials》2011,323(10):1408-1412
Poly(ethylene glycol) (PEG)-containing magnetic fluids - magnetite (Fe3O4) stabilized by sodium oleate - were prepared. Magnetic measurements confirmed superparamagnetic behaviour at room temperature. The structure of that kind of magnetic fluid was characterized using different techniques, including electron microscopy, photon cross correlation spectroscopy and small-angle neutron scattering, while the adsorption of PEG on magnetic particles was analyzed by differential scanning calorimetry and Fourier transform infrared spectroscopy. From the in vitro toxicity tests it was found that a magnetic fluid containing PEG (MFPEG) partially inhibited the growth of cancerous B16 cells at the highest tested dose (2.1 mg/ml of Fe3O4 in MFPEG). 相似文献
96.
Alexandru Vlasceanu Dr. Søren L. Broman Anne S. Hansen Anders B. Skov Prof. Dr. Martina Cacciarini Prof. Dr. Anders Kadziola Prof. Dr. Henrik G. Kjaergaard Prof. Dr. Kurt V. Mikkelsen Prof. Dr. Mogens Brøndsted Nielsen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(31):10796-10800
The conversion and efficient storage of solar energy is recognized to hold significant potential with regard to future energy solutions. Molecular solar thermal batteries based on photochromic systems exemplify one possible technology able to harness and apply this potential. Herein is described the synthesis of a macrocycle based on a dimer of the dihydroazulene/vinylheptafulvene (DHA/VHF) photo/thermal couple. By taking advantage of conformational strain, this DHA–DHA macrocycle presents an improved ability to absorb and store incident light energy in chemical bonds (VHF–VHF). A stepwise energy release over two sequential ring‐closing reactions (VHF→DHA) combines the advantages of an initially fast discharge, hypothetically addressing immediate energy consumption needs, followed by a slow process for consistent, long‐term use. This exemplifies another step forward in the molecular engineering and design of functional organic materials towards solar thermal energy storage and release. 相似文献
97.
98.
9-Methylfluorene was tested as an indicator in the titration of commonly used organometallic reagents. This indicator is readily prepared in three steps from fluorenone. In THF solution the deprotonated indicator is red and exhibits a sharp endpoint. The highly basic reagents sec-butyllithium and tert-butyllithium can be titrated in ether solution, where the color of the deprotonated indicator is yellow. 相似文献
99.
Antibacterial drug trimethoprim [2,4-diamino-5-(3,4,5-trimethoxybenzyl)-pyrimidine] (I) was determined in pharmaceutical formulations by using a lab-made PC-controlled SIA analyser linked to conventional HPLC fluorimetric detector equipped with a chemiluminescence module. The chemical principle is the oxidation of I by KMnO(4) in acid medium; the reaction is accompanied by the emission of chemiluminescence, which is enhanced in the presence of hexametaphosphate (HMP). The optimum sequence and the flow parameters and concentrations and volumes of reagents aspirated optimised by a computer-aided simplex method were, 100 mul of 5 mM HMP, 40 mul of a test solution of I, 2 mul of 0.5 M H(2)SO(4) and 20 mul of 1 mM KMnO(4); the luminescing zone was pushed into the detector at a flow rate of 49 mul s(-1). The calibration graph relating the intensity of luminescence to concentration of I was parabolic (r=0.9994) in the range 0.5-100 mug ml(-1) of I with rectilinear part (r=0.9999) in the range 20-100 mug ml(-1) of I; the limit of detection was 0.1 mug ml(-1) of I. The method was used for the assay of Triprim(R) tablets (with nominal content 100 or 200 mg of I) for the active substance as well as for content uniformity tests; the R.S.D. values did not exceed 1% (n=5). The SIA results did not show statistical difference from those obtained by pharmacopoeial acidimetric titration in non-aqueous medium; the excipients such as microcrystalline cellulose, maze starch, povidone, talc, magnesium stearate and gelatin did not interfere. 相似文献
100.
Schulman LS Mihóková E Scardicchio A Facchi P Nikl M Polák K Gaveau B 《Physical review letters》2002,88(22):224101
Millisecond crystal relaxation has been used to explain anomalous decay in doped alkali halides. We attribute this slowness to Fermi-Pasta-Ulam solitons. Our model exhibits confinement of mechanical energy released by excitation. Extending the model to long times is justified by its relation to solitons, excitations previously proposed to occur in alkali halides. Soliton damping and observation are also discussed. 相似文献