Fast image-processing technique in phase-shifting holographic interferometry

A fast image-processing method in phase shifting holographic interferometry is proposed, in which the complicated phase calculation is completed with a logic circuit and look-up table. An electronic circuit was designed for the purpose. With these techniques, the processing time can be greatly reduced.     

Highly efficient polymer supported phase-transfer catalysts containing hydrogen bond inducing functional groups

Merrifield resin supported cinchona ammonium salts bearing 2′-fluorobenzene, 2′-cyanobenzene and 2′-N-oxypyridine groups were prepared and applied to the phase-transfer catalytic alkylation of N-(diphenylmethylene)glycine tert-butyl ester for the enantioselective synthesis of α-amino acids (76-96% ee).     

Precision synthesis of sustainable thermoplastic elastomers from lysine‐derived monomers

Novel renewable thermoplastic elastomers were synthesized by sequential polymerization of lysine‐ and itaconic acid‐derived monomers. Ring‐opening polymerization of lysine‐based O‐carboxyanhydride monomer using diethylene glycol as an initiator gave well‐defined α,ω‐dihydroxy functionalized lysine‐derived polyesters. The M _n of these polyesters increased with the monomer conversion while retaining relatively narrow molecular weight distributions. Based on the successful controlled polymerization and esterification of α,ω‐dihydroxy with 2‐bromoisobutyryl bromide, the resultant Br‐PL‐Br macroinitiator was used for the atom transfer radical polymerization of N‐phenylitaconimide (PhII). Three poly(N‐phenylitaconimide)‐b‐polyester‐b‐poly(N‐phenylitaconimide) triblock copolymers were prepared containing 12 ? 25 mol% PPhII, as determined by ¹H NMR spectroscopy. The properties of the obtained triblock copolymer are evaluated as high‐performance and renewable thermoplastic elastomer materials. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 349–355     

Convenient preparation of pinometostat and related 5′-deoxy-5′-amino adenosine derivatives as well as their activity against DOT1L

From adenosine and 2′-C-Me adenosine, a 3-step route towards nucleoside DOT1L inhibitors, including pinometostat, EPZ5677, and FED1, was established. With useful structural-activity relationship information, the newly prepared 2′-C-Me adenosine derivatives contribute to the limited repertoire of ribose-modified nucleoside DOT1L inhibitors. In general, this new synthetic method will facilitate not only the study of nucleoside DOT1L inhibitors, but also the synthetic and medicinal chemistry research of 5′-deoxy-5′-amino adenosine derivatives.     

叶片转动对涡轮间隙内部流动影响的数值研究

机匣与叶片的相对转动是影响涡轮叶顶间隙流动的重要冈素之一.对LISA 1.5级轴流涡轮间隙内部流动的数值计算结果表明:叶片转动对涡轮间隙流动有阻塞作用.叶片静止时,由于阻塞作用消失,导致间隙入口速度增大,间隙流鼍增加,并且通过间隙的流体全部卷起形成间隙涡.同时在叶片顶部吸力面侧前缘、中部各形成一个间隙涡,使得间隙流动损失增加.而且转速下降会加剧动叶出口截面气流过偏/偏转不足现象.同时叶片静止时,间隙前部各个弦长截面内静压自间隙入口开始一直呈增加趋势,直到叶片尾缘附近截面,间隙截面内静压才逐渐稳定.     

Pair correlation of rationals with prime denominators

We prove that the pair correlation of the sequence of rational numbers in the unit interval with prime denominators is Poissonian. The result is also true for rational numbers with denominators having exactly two distinct prime factors.     

Determination of L‐trantinterol in rat plasma by using chiral liquid chromatography‐tandem mass spectrometry

A simple, sensitive, and rapid method for determination of L‐trantinterol in rat plasma was developed for the first time by using LC coupled to MS/MS based on chiral stationary phase. A baseline separation of the enantiomers of trantinterol was achieved on a Chirobiotic V column, using a mixture of acetonitrile–methanol–ammonia–acetic acid (80:20:0.01:0.02, v/v/v/v) as the mobile phase. The detection was performed on a triple‐quadrupole tandem mass spectrometer by multiple reaction monitoring mode via ESI. The calibration curve was linear in concentration range from 0.270 to 108 ng/mL in plasma with the lower limit of quantification of 0.270 ng/mL. The intra‐ and interday precision (relative standard deviation) values were within 10.9% and the accuracy (relative error) was from 2.6 to 9.2% at all quality control levels. The method has been successfully applied to a study of L‐trantinterol pharmacokinetics in rats.     

Theoretical analysis of 2D laser angle sensor and several design parameters

Having adopted several sets of new technology and techniques, such as cube-corner prism of higher refractive index, orthogonal holographic grating, non-linear compensation, and fringe fractionization, etc., we have developed a new type of laser angle sensor that can be used to measure two-dimensional angle of moving target. The sensor has high sensitivity, high precision and longer measuring range compared with the original sensor, and its measuring range will achieve ±35°, while its minimum resolution angle is 0.004°. The experimental results show that the measuring error is not greater than ±0.01°. In this paper, several design parameters and measuring results for 2D laser angle sensor are given.     

掺杂铬对NiFe2O4的磁性和结构稳定性影响

利用物理特性测试仪对共沉淀法制备的Cr3 + 掺杂NiFe2 O4的磁性能进行测试 ,发现掺杂Cr3 + 并经 35 0、6 0 0℃焙烧的NiFe2 O4样品 ,饱和磁化强度Ms和剩磁Mr随掺杂量的增加而下降 ,矫顽磁场强度Hc随掺杂量的增加而增加 .XRD平均晶粒测试结果显示 ,样品的平均晶粒大小随掺杂量的增加而减小 .在共沉淀过程掺杂的Cr3 +经 6 0 0℃热处理后已进入NiFe2 O4晶格 .晶格中的Cr3 + 对NiFe2 O4分解CO2 的H2 /CO2 循环反应性能产生很大影响 ,纯NiFe2 O4循环反应 15次失活 ,而掺 4 %Cr3 + 的NiFe2 O4循环反应 5 0次仍然具有活性