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In chemical analysis and XRPA studies, it has been found that the products of fluorination of graphite, graphite bifluoride,
and tetracarbon polyfluoride with gaseous and liquid fluorooxidants (ClF3, ClF5, XeF2, and FNO3) and their solutions in anhydrous hydrogen fluoride and freon-113 at 20–100°C, having a limiting composition, are second
stage intercalated compounds based on dicarbon polyfluoride with the corresponding fluorooxidant, or the reduced form of fluorooxidant,
or a fluorooxidant and a solvent. The degree of C-F bond ionicity in C2F was higher than in CF, but lower than in C4F. However, the bond is closer in character to the covalent C-F bond in monocarbon polyfluoride. 相似文献
23.
A double complex salt [Co(N2C2H8)3][AuBr4]2Br is obtained and characterized using single crystal X-ray diffraction analysis. The crystallographic data of C6H24Au2Br9CoN6 are as follows: a = 21.6479(17) ?, b = 14.9085(12) ?, c = 8.2676(7) ?, β = 110.820(2)°, V = 1538.92(12) ?3, C2/c space group, Z = 4, d
x = 3.602 g/cm3. Square planar coordination of the gold atom in the complex anion is completed to a tetragonal pyramid by an additional bromine
atom of the adjacent complex anion at the Au... Br distance of 3.677 ?. 相似文献
24.
Effect of fluorination on the surface properties of carbon materials as probed by gas chromatography
T. M. Roshchina S. V. Glazkova A. D. Khrycheva V. G. Makotchenko M. L. Pantyukhin 《Moscow University Chemistry Bulletin》2007,62(2):67-71
The surface properties of graphite, carbon fiber, and their fluorination products were studied using gas chromatography. The retention volumes and Kovatz indices for saturated and aromatic hydrocarbons and oxygenated and nitrogenated compounds were determined. Regardless of the properties of the matrix, fluorination produces materials with chemically homogeneous and apolar surfaces. For fluorinated graphite, the decrease in the retention of branched alcohols compared to that of linear alcohols is more significant than for fluorinated carbon fiber. 相似文献
25.
The equilibria AuCl4−+jOH−+kH2O⇌AuCl4−j−k
(OH)
j
(H2O)
k
k−1+(j+k)Cl−, β
jk
(0≤j,k≤4) have been studied spectrophotometrically at 20 °C in aqueous solution. For I=2 mol⋅dm−3(HClO4) the conventional constants, β
i
*, of the equilibria, Au*+iCl−
⇌AuCl
i
*, are equal to log 10
β
1*=(6.98±0.08); log 10
β
2*=(13.42±0.05); log 10
β
3*=(19.19±0.09); and log 10
β
4*=(24.49±0.07), where [AuCl
i
*]=∑[AuCl
i
(OH)
j
(H2O)4−i−j
] at i=const. The hydrolysis and other transformations of AuCl4− in aqueous solution are discussed. On the basis of new and known data, a full set of equilibrium constants, β
jk
, or their estimates has been obtained. 相似文献
26.
B.?Ch.?KholkhoevEmail author A.?S.?Buinov M.?N.?Kozlova V.?G.?Makotchenko V.?E.?Fedorov V.?F.?Burdukovskii 《Russian Journal of Applied Chemistry》2018,91(3):392-395
New composite materials based on polylactide and graphene, suitable for creating three-dimensional objects using the 3D printing technology, were prepared. Introduction of the nanoadditive into the matrix of the biodegradable polymer enhances the tensile strength of the materials by more than 57%. In addition, the composites exhibit high electrical conductivity, reaching 0.9 S cm–1 for the composite with 3 wt % filler, which determines the possibility of using them for the development of various electrotechnical devices and tissue engineering structures. 相似文献
27.
E. V. Makotchenko I. A. Baidina P. E. Plusnin L. A. Sheludyakova Yu. V. Shubin S. V. Korenev 《Russian Journal of Coordination Chemistry》2007,33(1):45-52
The complex salts ((DienH3)[IrCl6](NO3) (I), (DienH3)[PtCl6](NO3) (II), and (DienH3)[IrCl6]0.5[PtCl6]0.5(NO3) (III) (where Dien is NH2(CH2)2NH(CH2)2NH2) were synthesized and characterized by elemental, X-ray diffraction, and thermal analyses and by electronic and IR spectroscopies.
Solid solution of the composition Ir0.35Pt0.65 was obtained by decomposition of compound III in the atmosphere of hydrogen.
Original Russian Text ? E.V. Makotchenko, I.A. Baidina, P.E. Plusnin, L.A. Sheludyakova, Yu.V. Shubin, S.V. Korenev, 2007,
published in Koordinatsionnaya Khimiya, 2007, Vol. 33, No. 1, pp. 47–54. 相似文献
28.
Bogdanov S. G. Valiev . Z. Dorofeev Yu. A. Pirogov A. N. Skryabin Yu. N. Makotchenko V. G. Nazarov A. S. Fedorov V. E. 《Crystallography Reports》2006,51(1):S12-S15
The subatomic structure of expanded graphite has been investigated by small-angle neutron scattering. Samples were synthesized during quick thermal decomposition of intercalated compounds based on oxidized graphite. They had a low bulk density (up to 0.1 g/cm3) and were characterized by considerable small-angle scattering. It has been established that majority of the volume of expanded graphite samples is occupied by participles with characteristic sizes in two ranges: from 6 to 8 nm and from 20 to 30 nm. Small particles have properties of a surface fractal with the dimension D s = 2.4–2.6, whereas the larger particles are mainly smooth and have the dimension D s = 2.0–2.1. The specific surface of the samples studied was determined from the small-angle scattering data. 相似文献
29.
Dr. Nitin A. Kaskhedikar Guanglei Cui Joachim Maier Vladimir Fedorov Victor Makotchenko Arndt Simon 《无机化学与普通化学杂志》2011,637(5):523-529
A superfine expanded graphite (s‐EG) fiber material was investigated as an anode material for lithium‐based batteries. The fibers were prepared by decomposition of dicarbon monofluoride‐intercalated graphite. The high resolution transmission electron microscopy (HRTEM) images showed the fiber thickness in range of 2–3 nm with several microns in length. Lithium storage capacity in this material was measured in lithium half cells. High lithium storage capacity of about 1000 mAh · g–1 at a rate of C/10, corresponding to Li3C6 composition was obtained. The material showed fairly good rate capability exhibiting lithium storage capabilities even at 60C. As a effect of ball milling, the s‐EG showed crystallographic ordering in the sample with reduced the lithium storage capacity corresponding to composition of LiC6. A simple mathematical relation to account for the excess lithium storage capacity in this material is put forward. 相似文献
30.
Novel complex salts [Au(en)2]Cl(ReO4)2 (I) and [Au(en)2](ReO4)3 (II), en = ethylenediamine, are obtained. Their crystal structures are determined by single crystal X-ray diffraction. Complex I crystallizes in the triclinic crystal system: a = 6.2172(7) Å, b = 7.1644(8) Å, c = 8.8829(8) Å, α = 96.605(4)°, β = 110.000(4)°, γ = 97.802(4)°, P-1 space group, Z = 1, d x = 3.905 g/cm3; complex II crystallizes in the monoclinic crystal system: a = 15.244(2) Å, b = 7.6809(8) Å, c = 9.3476(12) Å, β = 127.004(3)°, C2 space group, Z = 4, d x = 4.057 g/cm3. 相似文献