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991.
Multivariate spectrophotometric calibration and liquid chromatography (LC) methods were used for the simultaneous determination of the active ingredients in 2 multicomponent mixtures containing chlorpheniramine maleate and phenylpropanolamine hydrochloride with ibuprofen and caffeine (mixture 1) or with propyphenazone (mixture 2). For the multivariate spectrophotometric calibration methods, principal component regression (PCR) and partial least squares (PLS-1), a calibration set of the mixtures consisting of the components of each mixture was prepared in distilled water. A leave-1-out cross-validation procedure was used to find the optimum numbers of latent variables. Analytical parameters such as sensitivity, selectivity, analytical sensitivity, limit of quantitation, and limit of detection were determined for both PLS-1 and PCR. The LC method depends on the use of a cyanopropyl column with the mobile phase acetonitrile-12 mM ammonium acetate, pH 5.0 (25 + 75, v/v), for mixture 1 or acetonitrile-10 mM potassium dihydrogen phosphate, pH 4.7 (45 + 55, v/v), for mixture 2; the UV detector was set at 212 nm. In spite of the presence of a high degree of spectral overlap of these components, they were rapidly and simultaneously determined with high accuracy and precision, with no interference from the matrix excipients. The proposed methods were successfully applied to the analysis of pharmaceutical formulations and laboratory-prepared mixtures containing the 2 multicomponent combinations. 相似文献
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995.
M. S. Mahmoud W. G. Vogt M. H. Mickle 《Journal of Optimization Theory and Applications》1979,28(4):549-584
Decomposition and coordination methods based on the utilization of the Lagrangian generalized gradients in multilevel control structures have been developed successfully to handle the class of constrained optimization problems with nonseparable performance indices. Introducing proper intervention parameters, the overall problem is decomposed into a group of lower-dimensional constrained problems. A class of three-level control structures is thus proposed to coordinate the local solutions via two coordinating levels. While the first coordinating level is basically designed to adjust the state and control constraint violations, the second coordinating level is responsible mainly for manipulating the subsystems interactions in different ways. Salient features, advantages, and limitations of the developed control structures are pointed out. 相似文献
996.
Mohamed Ahmed Mahmoud 《Journal of Saudi Chemical Society》2018,22(2):229-238
The adsorption kinetics for removal of uranium (V1) from aqueous solution using silicon dioxide nanopowder (nano-SiO2) was investigated in batch and continuous techniques. Pseudo-first order and pseudo-second order were used to analyze the kinetics of batch experiments. In continuous technique the important parameters (initial concentration, flow rate and bed height) on the breakthrough curves were studied and the adsorption kinetics was analyzed using Thomas and Yoon and Nelson kinetic models. The comparison between the kinetic models was evaluated by the correlation coefficients (r2). The results indicated that the batch experiments fitted well with pseudo second-order kinetic model. The comparison of the experimental breakthrough curve to the breakthrough profile obtained from Thomas and Yoon and Nelson methods showed a satisfactory fit for silicon dioxide nanopowder. 相似文献
997.
Abdulmujeeb T. Onawole Mahmoud Abdul Halim Nisar Ullah Abdulaziz A. Al-Saadi 《Structural chemistry》2018,29(2):403-414
Structural and vibrational properties of resorcinol, its -OD isotopomer and dianion salt were compared with the help of quantum-chemical and spectroscopic techniques. The relative stability computed at the MP4/6-311++G(d,p) level predicted that the syn-syn rotameric form of the resorcinol molecule is about 0.7 kcal/mol higher in energy than the more stable anti-syn and anti-anti forms. Vibrational frequencies calculated for the optimized α-resorcinol and its -OD isotopomer unit cells showed that out-of-plane bending vibrations tend to shift to higher wavenumbers for the solid phase compared to the non-condensed phase indicating strong intermolecular packing forces. OH/OD isotopic shifts were identified for stretching and binding modes, which supported by DFT findings. Infrared, Raman and proton NMR data confirmed a notable change in the overall electronic properties of resorcinol upon the abstraction of the hydroxyl protons. In addition, resorcinol, in its three rotameric configurations, exhibited a stable complexation with keratin-7. While the highly electronegative nature of oxygen atoms contributed effectively to the binding affinity of resorcinol towards keratin-7, careful docking analysis showed that the steric factor play the major role in the keratolytic activity of resorcinol. 相似文献
998.
The thermochemistry of the reaction of the microsolvated Na+ such as [Na(H2O) n ; n?=?1?6]+, [Na(NH3) n ; n?=?1?6]+ and [Na(H2O) n (NH3) m ; n?+?m?=?2?6]+ with thymine (Thy), as an example of a reaction in the microcosmic environment, have been studied in this work, theoretically. It was found that the increase of the number of solvent molecules in the structure of microsolvated Na+ is accompanied by the decrease of the standard enthalpy (\(\Delta H_{r}^{^\circ }\)) and Gibbs free (\(\Delta G_{r}^{^\circ }\)) energies of the reaction (Thy?+?[Na(X) n ]+→Thy-Na(X) n + ; X?=?solvent molecule). Also, the calculations showed that the electronic intermolecular interaction (?Eint) between the Thy and microslovated Na+ decreased with the increase of solvent molecules. For the interaction of the [Na(H2O) n ; n?=?4, 5 and 6]+ ions with the Thy, there was the probability of forming of the hydrogen bond between water molecules in the structure of solvated Na+ and the Thy. The gas phase infrared (IR) spectra of the complexes of the microsolvated Na+ with the Thy for different values of n were calculated and compared with each other to follow the change in the frequency of the stretching vibration of the interaction path between the C=O group of the Thy and Na (O…Na) with n. Using the calculated values of \(\Delta G_{r}^{^\circ }\) of the reactions, the mole fractions of the complexes of microsolvated Na+ ions with the Thy were calculated at different humidity. 相似文献
999.
Five homologous series of the four-ring 4-substituted phenylazo phenyl 4?-(4?-alkoxy phenylazo) benzoates (Ina–e) were prepared and their mesophase behaviour investigated by differential scanning calorimetry (DSC) and phases identified by polarised light microscopy (PLM). Compounds prepared were structurally characterised via infrared, 1H-NMR, mass spectroscopy, thermogravimetric and elemental analysis. Transition temperatures were first correlated with the alkoxy-chain length (n, that varies between 6, 8, 10, 14, and 16 carbons) within each homologous series, and again with the polarisability anisotropy (ΔαX) of the Ar-X bond, where X changes between CH3O, CH3, H, Br, and CN groups . Comparative studies were made to investigate the effect of introducing the extra phenyl azo moiety into the previously investigated three-ring compounds, 4-substituted phenyl 4′-(4″-alkoxyphenylazo) benzoates (IIna–e), 4-substituted phenylazo 4′-(4″- alkoxy phenyl) benzoates (IIIna–e), and 4-(4′-alkoxy phenylazo) phenyl 4″-substituted benzoates (IVna–e), each bear the same polar group, X, and the alkoxy group, n . 相似文献
1000.
Laila H. Abdel-Rahman Luigi Pietro Battaglia Paolo Sgarabotto Mohamed R. Mahmoud 《Journal of chemical crystallography》1994,24(9):567-571
A series of ternary complexes of copper(II), cobalt(II) and zinc(II) with L-histidine, 1,10-phenanthroline, 2,2-dipyridyl or imidazole having perchlorate or acetate as counterions were synthesized and characterized by conventional methods and for [Cu(bipy)(L-hist)]ClO4·1.5H2O and X-ray crystal structure was determined. The crystals belong to the monoclinic space groupC2 witha=18.843(3),b=10.582(2),c=11.020(2), =115.20(10)°,Z=4,R=0.0535. The structure is consistent of [Cu(bipy)(L-hist)]+ cations, perchlorate ions and water molecules. The geometry around copper is trigonal bipyramidal with one N,N,O tridentate L-histidine molecule and one 2,2-dipyridyl ligand, the apical sites are occupied by the -amino nitrogen [Cu–N(71) 1.995(8)] and by N(11) of 2,2-dipyridyl [Cu–N(11) 1.983(7)], the equatorial plane is formed by the N(3) imidazole -nitrogen [Cu–N(3) 2.140(6)], O(82) carboxylic oxygen [Cu–O(82) 2.009(5)] and N(22) [Cu–N(22) 2.010(7)]. 相似文献