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61.
The hydrogen-bonded complexes between methylacetate (MeAc) and water or hydrochloric acid have been studied by infrared spectrometry in a low temperature Argon matrix. The νCO, νCC and νCC ional modes of MeAc show a splitting to the low and to the high frequency side of the free molecule. This suggests that water and HCl interact with the keto and ether oxygens. This conclusions is supported by the appearance of two main absorptions in the νHCl region. These results are discussed as a function of the gas-phase basicity of the two oxygen atoms, derived from the O(1s) core electron binding energies and from the ionization potentials.  相似文献   
62.
Baths produce friction and random forcing on particles suspended in them. The relation between noise and friction in (generalized) Langevin equations is usually referred to as the second fluctuation–dissipation theorem. We show what is the proper nonequilibrium extension, to be applied when the environment is itself active and driven. In particular we determine the effective Langevin dynamics of a probe from integrating out a steady nonequilibrium environment. The friction kernel picks up a frenetic contribution, i.e., involving the environment’s dynamical activity, responsible for the breaking of the standard Einstein relation.  相似文献   
63.
64.
The heteracalixarene series (N/O/S) has been expanded with Se-bridged cyclotrimeric macrocycles. Selenacalix[3]triazines were synthesized by convenient one-pot nucleophilic aromatic substitution reactions and they showed peculiar supramolecular features. The N tridentate binding pocket was capable of coordinating both copper ions and anions.  相似文献   
65.
66.
Dinaburg  E.  Maes  C.  Pirogov  S.  Redig  F.  Rybko  A. 《Journal of statistical physics》2004,117(1-2):179-198
We consider theq = 4 Potts model on the square lattice with an additional nonlocal interaction. That interaction arises from the choice of the reference measure taken to be the uniform measure on the recurrent configurations for the abelian sandpile model. In that reference measure some correlation functions have a power-law decay. We investigate the low-temperature phase diagram and we prove the existence of a single stable phase with exponential decay of correlations. For all boundary conditions the density of 4 in the infinite volume limit goes to one as the temperature tends to zero.  相似文献   
67.
We study local transformations of Gibbs measures. We establish sufficient conditions for the quasilocality of the images and obtain results on the existence and continuity properties of their relative energies. General results are illustrated by simple examples. Received: 11 November 1997 / Revised version: 20 February 1998  相似文献   
68.
The lattice approximation to a time-dependent Ginzburg-Landau equation is investigated in the presence of a small external field. The evolution law conserves the spin, but is not reversible. A nonlinear diffusion equation of divergence type is obtained in the hydrodynamic limit. The proof extends to certain stochastically perturbed Hamiltonian systems.  相似文献   
69.
 We consider expansive homeomorphisms with the specification property. We give a new simple proof of a large deviation principle for Gibbs measures corresponding to a regular potential and we establish a general symmetry of the rate function for the large deviations of the antisymmetric part, under time-reversal, of the potential. This generalizes the Gallavotti-Cohen fluctuation theorem to a larger class of chaotic systems. Received: 6 March 2002 / Accepted: 16 September 2002 Published online: 8 January 2003  相似文献   
70.
We investigate the validity of a Markov approach for the motility of kinesin. We show in detail how the various mechanochemical states and reaction rates that are experimentally measured, can be used to create a Markov-chain model. We compare the performance of this model to motility data and we find global similarities in the load and ATP-concentration dependency of speed and mean run length. We also discuss the relation between the experimentally found stalling behavior and thermodynamic expectations. Finally, the Markov chain modelling provides a way to calculate the mean entropy production and the (power) efficiency.  相似文献   
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