Synthesis of 4-Alkyl-4-alkoxybutenolides Having Unsaturated Side Chains via Chromium Carbene Complex Photochemistry: (+)-Cerulenin

The photochemical reaction between optically active ene carbamates and chromium alkoxycarbene complexes containing unsaturated aliphatic side chains was further developed. Although remote olefinic groups, including conjugated dienes, were tolerated, a homoallylic side chain underwent intramolecular reaction to give a strained cyclobutanone. (+)-Cerulenin was synthesized utilizing the photochemical reaction of an alkynylcarbene complex with an optically active ene carbamate and the bis(pi-crotyl)nickel halide alkylation of a vinyl bromide as key steps.     

Diffractive production of ρ-mesons and of ρπ-systems by neutrinos and antineutrinos on protons

Evidence is presented for diffractive production of -mesons and of -systems invp and chargedcurrent interactions. In the (anti-)neutrino energy range 10 GeVE _v <60 gev=" the=" cross=" sections=" for=" diffractive="> and diffractive production are found to be (0.64±0.14 (stat.)±0.08 (syst.))% and (0.28±0.08 (stat.)±0.04 (syst.))% of the charged-current cross section. The diffractive signal is consistent with being entirely due to diffractivea ₁ production. However, the data cannot distinguish between diffractivea ₁ and diffractive nonresonant production. The experimental distributions ofW, Q ²,x _Bj andy _Bj for diffractive and events are consistent with model predictions.