全文获取类型
收费全文 | 95篇 |
免费 | 1篇 |
国内免费 | 2篇 |
专业分类
化学 | 76篇 |
数学 | 7篇 |
物理学 | 15篇 |
出版年
2022年 | 1篇 |
2020年 | 2篇 |
2018年 | 1篇 |
2017年 | 1篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 7篇 |
2012年 | 2篇 |
2011年 | 2篇 |
2009年 | 1篇 |
2008年 | 3篇 |
2007年 | 2篇 |
2005年 | 5篇 |
2004年 | 2篇 |
2003年 | 6篇 |
2002年 | 2篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1997年 | 4篇 |
1993年 | 1篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 7篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 1篇 |
1977年 | 5篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 4篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1969年 | 2篇 |
排序方式: 共有98条查询结果,搜索用时 15 毫秒
81.
It is shown that a Banach space satisfies Clarkson's inequalities if and only if its “type or cotype constant” is 1, which implies in particular that the notions of Go - and Gn - Fourier type by Milman [16] are equivalent. A sequence of related results is also given. 相似文献
82.
Irradiation of N-methylacridone (NMA) in an acetone solution at ?78°C in the argon atmosphere afforded light emission (φCL: 10?6 - 10?8 einstein/mol) upon warming-up to room temperature. The final products were NMA acetone exclusively. 相似文献
83.
Tateaki Wakamiya Yasuyuki Ueki Tetsuo Shiba Yasuji Kido Yoshinobu Motoki 《Tetrahedron letters》1985,26(5):665-668
The structure of ancovenin, a new peptide inhibitor of angiotensin I converting enzyme, was determined to be a unique tricyclic peptide which comprises sixteen amino acid residues including dehydroalanine and three sulfide amino acids as unusual components. 相似文献
84.
Yasuji Kida Yuichi Miura Kazuo Shikata Keiichi Azuma 《Journal of polymer science. Part A, Polymer chemistry》1975,13(12):2835-2842
Polymerization of epichlorohydrin (ECH) and copolymerization of propylene oxide–allyl glycidyl ether were studied by using a catalyst consisting of aluminum alkyl–strong phosphoric acid–Lewis base. This system showed high polymerization activity for alkylene oxides, and it was elucidated by x-ray diffraction analysis that the resultant ECH polymer was completely amorphous. The polymerization was presumed to be of the coordinated anionic type. The physical properties of the vulcanized polymers were studied. 相似文献
85.
Yasuji Yamada Shintaro Nakamura Kazuo Iguchi Kunio Hosaka 《Tetrahedron letters》1981,22(14):1355-1356
Olefinic cyclization of -prenylphenols (), () and () induced by thallium(III) trifluoroacetate was performed. 相似文献
86.
Substituted (p-MeO, p-Me, H, p-Cl, p-Br, m-Br, m-MeO, 3,4-Cl2, p-CO2Me, m-CN and p-CN) monophenylcarbenes are generated in a binary mixture of substrates (methanol, cis-4-methyl-2-pentene and cyclohexane) and the relative rate of O—H insertion into methanol to stereospecific cyclopropanation of the olefin to C—H insertion into cyclohexane are calculated from the ratios of products and substrates. It is found (i) that the reactivities of the substrates decrease in the order of methanol, olefin and cyclohexane and (ii) that electron-donating substituents generally lead to reaction with the more reactive substrates while the reaction with the less reactive substrates is favoured in the case of electron-withdrawing substituents. These results are interpreted in terms of the change in the electrophilicity of the singlet arylcarbene by the substituents rather than the change in the singlet-triplet equilibrium. 相似文献
87.
Harada H Hirokawa Y Suzuki K Hiyama Y Oue M Kawashima H Kato H Yoshida N Furutani Y Kato S 《Chemical & pharmaceutical bulletin》2005,53(2):184-198
In search for potent and selective beta3-adrenergic receptor (beta3-AR) agonists as potential drugs for the treatment of type II diabetes and obesity, a novel series of 1-(3-chlorophenyl)-2-aminoethanol derivatives were prepared and evaluated for their biological activity at human beta1-, beta2-, and beta3-ARs and rat beta3-AR expressed in Chinese hamster ovary (CHO) cells. Replacement of the right-hand side (RHS, benzene ring) in the 'first generation' beta3-AR agonists BRL 37344 and CL 316243 with a 1H-indole ring gave compound 31 with unique pharmacological properties among beta3-AR agonists. Initial in vitro assays showed that 31 possesses modest rat and human beta3-ARs agonistic activity. Introduction of various substituent into the indole nucleus of 31 afforded a number of compounds with good beta3-ARs agonistic activity. In particular, 90 having a carboxylic acid functionality at the 7-position of the indole nucleus showed the most potent human beta3-AR agonistic activity. Finally, optical resolution of 90 led to the identification of the most promising compound, [3-[(2R)-[[(2R)-(3-chlorophenyl)-2-hydroxyethyl]amino]propyl]-1H-indol-7-yloxy]acetic acid (96, AJ-9677). This compound exhibited potent human beta3-AR agonistic activity (EC50=0.062 nM, IA=116%) with 210- and 103-fold selectivity over human beta2-AR and beta1-AR, respectively. Compound 96 also exhibited potent rat beta3-AR agonistic activity (EC50=0.016 nM, IA=110%). Moreover, repeated oral administration of 96 inhibited body weight gain and significantly decreased glucose, insulin, free fatty acid, and triglyceride concentrations in plasma in KK-Ay/Ta mice. On the basis of this pharmacological profile, 96 entered clinical development as a drug for the treatment of type II diabetes and obesity. 相似文献
88.
Hiroto Nagaoka Kazunori Ohsawa Takeshi Takata Yasuji Yamada 《Tetrahedron letters》1984,25(47):5389-5392
The bicyclo[5.3.1]undecane derivative 19, which was referred to the A,b ring system of taxane diterpenes, was synthesized by a base-induced fragmentation reaction of the tricyclic diol monomesylate 18 derived highly stereoselectively from 5-methyl-1,3-cyclohexadione. 相似文献
89.
Adsorption of CO on Pt(211) and Pt(311) surfaces has been investigated by the density functional theory (DFT) method (periodic DMol3) with full geometry optimization. Adsorption energies, structures, and C-O stretching vibrational frequencies are studied by considering multiple possible adsorption sites and comparing them with the experimental data. The calculated C-O stretching frequencies agree well with the experimental ones, and precise determination of adsorption sites can be carried out. For Pt(211), CO adsorbs at the atop site on the step edge at low coverage, but CO adsorbs at the atop and bridge sites simultaneously on both the step edge and the terrace with further increasing CO coverage. The present results interpret the reflection adsorption infrared (RAIR) spectra of Brown and co-workers very well from low to high coverage. For Pt(311), CO adsorbs also at the atop site on the step edge at low coverage. The lifting of reconstruction by CO adsorption occurs also for Pt(311), whereas the energy gain for lifting the reconstruction of the Pt(311) surface is smaller than that for Pt(110). The largest difference between the stepped Pt(211)/Pt(311) and Pt(110) surfaces is the occupation on the edge sites at higher coverage. For the stepped surfaces, the bridge site begins to be occupied at higher coverage, whereas the atop site is always occupied for the Pt(110) surface. 相似文献
90.
An approximate method is extended for analyzing the free vibration problem of orthotropic square plate with a square hole. In this paper, a square plate with a square hole is transformed into an equivalent square plate with non-uniform thickness by considering the hole as an extremely thin part of the equivalent plate. Therefore, the dynamic characteristics of a plate with a hole can be obtained by analyzing the equivalent plate. The Green function, which is the discrete solution for the deflection of the equivalent plate, is used to obtain the characteristic equation of the free vibration. The effects of the side to thickness ratio, hole side to plate side ratio and the variation of the thickness on the frequencies are considered. Some numerical analyses are carried out for the simply supported orthotropic square plate with a square hole. The efficiency and accuracy of the numerical solutions by the present method are investigated. 相似文献