Nonlinear stability of incoherence and collective synchronization in a population of coupled oscillators

A mean-field model of nonlinearly coupled oscillators with randomly distributed frequencies and subject to independent external white noises is analyzed in the thermodynamic limit. When the frequency distribution isbimodal, new results include subcritical spontaneous stationary synchronization of the oscillators, supercritical time-periodic synchronization, bistability, and hysteretic phenomena. Bifurcating synchronized states are asymptotically constructed near bifurcation values of the coupling strength, and theirnonlinear stability properties ascertained.     

The electrochemical reduction of perezone in the presence of benzoic acid in acetonitrile

An electrochemical study using transient techniques of a quinone-type natural product, perezone, has been performed in acetonitrile and in the presence of benzoic acid. Using linear sweep voltametry and single potential step chronoamperometry, it was possible to establish that the reduction mechanism of perezone involves a monoelectronic charge-transfer step, followed by a protonation step and homogeneous charge transfer due to disproportionation of the protonated intermediate. The mechanism for the homogeneous charge-transfer step was found to be of the type DISP1 (disproportionation order one) from the results of double potential step chronoamperometry experiments. The occurrence of the DISP1 mechanism was provoked by the mildly acidic medium used in this study.     

Cosmological models in the scalar-tetradic theory B

We present two methods for solving the cosmological equations of the scalar-tetradic theory B [19] when a Friedmann-Robertson-Walker (FRW) geometry is assumed. Among the many solutions found there are several physically meaningful ones including inflationary universe solutions.     

Boundaries for algebras of holomorphic functions

Let A_u(B_G) be the Banach algebra of all complex valued functions defined on the closed unit ball B_G of a complex Banach space G which are uniformly continuous on B_G and holomorphic in the interior of B_G, endowed with the sup norm. A characterization of the boundaries for A_u(B_G) is given in case G belongs to a class of Banach spaces that includes the pre-dual of a Lorentz sequence space studied by Gowers in Israel J. Math. 69 (1990) 129-151. The non-existence of the Shilov boundary for A_u(B_G) is also proved.     

An analytical proof of Hardy-like inequalities related to the Dirac operator

We prove some sharp Hardy-type inequalities related to the Dirac operator by elementary, direct methods. Some of these inequalities have been obtained previously using spectral information about the Dirac-Coulomb operator. Our results are stated under optimal conditions on the asymptotics of the potentials near zero and near infinity.     

C D : a computer program to generate 1D, 2D and 3D grids of functions dependent on the molecular ab initio electron density

A program to compute many functions dependent on the electron density ρ(r) from the results of ab initio molecular calculations is presented. The program allows the generation of different one-, two-, and three-dimensional grids for further graphical representation or numerical analysis. Other options like extracting separate atom contributions to the function computed or locating maximum and minimum values are also implemented. A number of illustrative applications regarding different ρ(r)-dependent functions are presented and the performance and portability of the program is discussed.     

<Emphasis FontCategory="NonProportional">L</Emphasis>-Matrices and solvability of linear complementarity problems by a linear program-Matrices and solvability of linear complementarity problems by a linear program

The classes ofL ₁-matrices,L ₂-matrices,L ₃-matrices andW-matrices are introduced to study solvability of a linear complementarity problem via solving a linear program. Three sufficient conditions are presented to guarantee that a linear complementarity problem is solvable via a linear program. The new sufficient conditions are weaker than the ones introduced by Mangasarian. This fact is also illustrated by an example. Partially supported by NSFC. This author is also with College of Business Administration of Human University as a Lotus chair professor.     

Dihydropyridine-based MCRs. New reaction pathways in the interaction with ethyl glyoxalate and non-aromatic amines

The Lewis acid-catalyzed interaction of dihydropyridines with ethyl glyoxalate and primary aliphatic amines yields, depending on the reaction conditions, bicyclic aminals or rearranged tetrahydropyridines in one-pot multicomponent reactions.     

On the evolution of sharp fronts for the quasi‐geostrophic equation

We consider the problem of the evolution of sharp fronts for the surface quasi‐geostrophic (QG) equation. This problem is the analogue to the vortex patch problem for the two‐dimensional Euler equation. The special interest of the quasi‐geostrophic equation lies in its strong similarities with the three‐dimensional Euler equation, while being a two‐dimen‐sional model. In particular, an analogue of the problem considered here, the evolution of sharp fronts for QG, is the evolution of a vortex line for the three‐dimensional Euler equation. The rigorous derivation of an equation for the evolution of a vortex line is still an open problem. The influence of the singularity appearing in the velocity when using the Biot‐Savart law still needs to be understood. We present two derivations for the evolution of a periodic sharp front. The first one, heuristic, shows the presence of a logarithmic singularity in the velocity, while the second, making use of weak solutions, obtains a rigorous equation for the evolution explaining the influence of that term in the evolution of the curve. Finally, using a Nash‐Moser argument as the main tool, we obtain local existence and uniqueness of a solution for the derived equation in the C^∞ case. © 2004 Wiley Periodicals, Inc.