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51.
52.
In this paper, we introduce the class of hypersurfaces of finitegeometric type. They are defined as the ones that share the basicdifferential topological properties of minimal surfaces of finite totalcurvature. We extend to surfaces in this class the classical theorem ofOsserman on the number of omitted points of the Gauss mapping ofcomplete minimal surfaces of finite total curvature. We give aclassification of the even-dimensional catenoids as the only even-dimensional minimal hypersurfaces of R
n
of finite geometric type. 相似文献
53.
Margarita Surez Estael Ochoa Beatriz Pita Remberto Espinosa Leandro Gonzlez Nazario Martín Margarita Quinteiro Carlos Seoane Jose L. Soto 《Journal of heterocyclic chemistry》1997,34(3):931-935
Novel 4,7-dihydrothieno[2,3-b]pyridines 10a-d have been prepared in a one step procedure from the readily available o-chloroformyl substituted 1,4-dihydropyridines 9a-d and ethyl mercaptoacetate in good yields. Semiempirical calculations reveal a favoured geometry with a boat conformation in the dihydropyridine system and a planar thieno ring. The calculated charge density values for the olefmic carbons (C5 and C6) are in agreement with the experimental push-pull effect observed in the 13C nmr. 相似文献
54.
Synthesis and structural study of novel 5-aryl substituted 2-amino-4,7-dioxopyrido[2,3-d]pyrimidines
Ren Rodríguez Margarita Surez Estael Ochoa Beatriz Pita Remberto Espinosa Nazario Martín Margarita Quinteiro Carlos Seoane Jose L. Soto 《Journal of heterocyclic chemistry》1997,34(3):957-961
The tide compounds 4a-c have been prepared in a one-step procedure from 2,4-diamino-6-hydroxy-pyrimidine (1) and the corresponding arylidene substituted Meldrum's acids 2a-e in very good yields. Semiempirical theoretical calculations (AMI) reveal two favoured conformations ( A and B ) for compounds 4a-e. The 1H-nmr determinations, by using Karplus and Altona equations, clearly indicate that conformation A, with the aryl group on C5 in a pseudoaxial position, is that predominant in solution. The calculated charge density values for the olefinic carbons are in agreement with the experimental push-pull effect observed in the 13C-nmr spectra. 相似文献
55.
Synthesis, characterization and thermal (TG, DSC, GC-MS) study of the coordination compounds La(MS)3·(pyNO)2, La(MS)3·(2-picNO)2, La(MS)3·(3-picNO)2 and La(MS)3·(4-picNO)1.5·H2O are reported. The observed thermal stability trend is 2-picNO<pyNO<3-picNO<4-picNO. Under heating, the rupture of the La-N-oxide bond is promoted, together with fragmentation of the N-oxide molecule. 相似文献
56.
F. Mercuri M. Marinelli U. Zammit S. Foglietta F. Scudieri 《Journal of Thermal Analysis and Calorimetry》1996,47(1):87-92
High resolution measurements have been performed with a photopyroelectric (PPE) technique to study the static and dynamic thermal parameters behaviour in the critical region of different liquid and solid samples. In particular the specific heat (c), the thermal diffusivity (D) and the thermal conductivity (k) have been simultaneously determined in the critical region around the antiferromagnetic/paramagnetic (AP) phase transition occurring in FeF2 and around the Smectic-A/Nematic (AN) phase transition occurring in the 8S5 liquid crystal.The high resolution of the measuring technique has allowed the determination of thec andD critical exponents and amplitude ratio of their critical terms. 相似文献
57.
Curreli S Deplano P Mercuri ML Pilia L Serpe A Schlueter JA Whited MA Geiser U Coronado E Gómez-García CJ Canadell E 《Inorganic chemistry》2004,43(6):2049-2056
We report the synthesis, structure, and physical properties of (BEDT-TTF)[Ni(tdas)2] [BEDT-TTF, or ET, is bis(ethylenedithio)tetrathiafulvalene; tdas is 1,2,5-thiadiazole-3,4-dithiolate], which is the first example of a salt containing monomeric [Ni(tdas)2]- monoanions. This salt, which crystallizes in the monoclinic space group P2(1)/c with a = 17.2324(6) A, b = 13.2740(5) A, c = 10.9467(4) A, beta = 96.974(2) degrees, and V = 2485.5(2) A(3), forms a layered structure. One layer contains dimerized BEDT-TTF electron donor molecules and isolated [Ni(tdas)2]- monoanions, while the second layer contains chains of [Ni(tdas)2]- monoanions. Conductivity measurements show that (BEDT-TTF)[Ni(tdas)2] has a semiconductor-to-semiconductor transition near 200 K, while magnetic measurements indicate that it is an S = 1/2 paramagnet with weak antiferromagnetic coupling. Reflectance spectra reveal bands in the near-infrared region (6.6 x 10(3) and 10.6 x 10(3) cm(-1)) which are typical of (BEDT-TTF)2(2+) dimers. From these data, we can conclude that the unpaired electron lies on the [Ni(tdas)2]- anions. Tight-binding band structure calculations were used to analyze the electronic structure of this salt. 相似文献
58.
Khayyami M Pérez Pita MT Peña Garcia N Johansson G Danielsson B Larsson PO 《Talanta》1998,45(3):557-563
A new type of amperometric biosensor based on immobilised acetylcholine esterase was designed and constructed. The enzyme was immobilised on a flow-through working electrode, which was prepared from reticulated vitreous carbon (RVC) or from a composite material consisting of RVC and superporous agarose. The sensor was operated in FIA mode using acetylthiocholine as a substrate. The sensor responded to inhibitors such as paraoxon-10(-9) mol was detected by the sensor in a non-optimised configuration. The practical lifetime of the sensor was at least 1 month. 相似文献
59.
Magneto‐controlled OR, AND and INHIB logic gates were designed using cobalt ferrite magnetic nanoparticles (CoFe2O4, saturated magnetization ca. 70 emu g?1, 17±2 nm diameter) functionalized with microperoxidase‐11. Tunable magnetic field generated by three external permanent magnets (NdFeB) upon moving them below the electrochemical cell resulted in translocation of the biofunctionalized magnetic nanoparticles between conductive and nonconductive domains of a solid plate. This resulted in electrochemically readable output signals with the Boolean logic controlled by the magnetic input signals. The current corresponding to the reversible redox process of the heme measured at ?0.4 V (vs. SCE) was considered as “1” output signal, while a small background current obtained from the conducting interface in the absence of the magnetic nanoparticles was considered as “0” output signal. Addition of H2O2 to the solution resulted in the generation of a cathodic catalytic current when the microperoxidase‐11‐functionalized magnetic nanoparticles are associated with the conductive domain of the support. This resulted in the amplification of “1” output signal and the increased difference between “1” and “0” signals generated by the cell, thus reducing the possibility of errors in the Boolean logic operations. 相似文献
60.
Mariana Mandelli de Almeida Nádia Araci Bou-Chacra Cibele Rosana Ribeiro de Castro Lima Jivaldo do Rosário Matos Elder Moscardini Filho Lucildes Pita Mercuri André Rolim Baby Telma Mary Kaneko Maria Valéria Robles Velasco 《Journal of Thermal Analysis and Calorimetry》2014,115(3):2401-2406
The ursolic acid (UA) increases the skin’s barrier function and acts in epidermal differentiation of keratinocytes in the epidermis, promoting cell renewal. Besides the mentioned properties UA also has antioxidant, antimicrobial, and anti-irritant functions to cosmetic formulations. Thus, it is necessary formulation studies to insure the development of quality cosmetic products containing this active, increasing its antioxidant potential within nanoparticles. This study aims to characterize and evaluate the thermal behavior of UA in free and nanostructured forms, and both incorporated into a cosmetic base formulation, using thermogravimetry and differential scanning calorimetry. Through the study were observed that free UA, in the embedded nanoparticles and in base formulation exhibited different behavior in similar thermal profile and relative to the presence of UA. The UA remained stable to a temperature of 250 °C and the technique has been shown to be effective for characterizing UA, evaluate water content, and stability of the formulation base. 相似文献