Glass melting and its innovation potentials: The combination of transversal and longitudinal circulations and its influence on space utilisation

This work deals with the increase of the space utilisation caused by changes in glass circulations resulting from different temperature gradients in the melting channel. The space utilisation values were calculated by mathematical modelling of particle dissolution and bubble rising in a model melting channel. It has been found that for a given sand-dissolution time and bubble-growth rate, the space utilisation value was determined as the ratio between transversal and longitudinal temperature gradients. The highest space utilisation values for both dissolution and bubble removal are reached when both types of temperature gradients are combined and the transversal temperature gradient is 5–10 times higher than the longitudinal one. A cautious application of optimal conditions in the model glass furnace leads to an increase in the furnace space utilisation.     

The optimal parameters of bubble centrifuging in glass melts

The mathematical model of a multicomponent bubble in a glass melt under the influence of gravitational and centrifugal fields has been applied in the model TV glass. The optimal fining conditions have been examined in a rotating cylinder with the aim of determining their general features. All of the dependences between the bubble-removal time and the rotational velocity showed the region of bubble removal by centrifuging at low cylinder rotational velocities and the region of complete bubble dissolution when the rotation was intensive. The low rotational velocities, characterised by the minimal bubble-centrifuging time, appeared to be suitable for industrial application. Consequently, the influence of temperature, pressure and glass-layer thickness on the value of the optimal rotational velocity and optimal fining time of small-critical bubbles has been investigated in detail in a glass melt containing fining agent. The significant role of temperature and minor role of pressure have been proved and the identical features of bubble removal have been identified in cylinders with different radii and filling by glass but with the same average thickness of the glass layer on the cylinder walls.     

Alkaloids from some amaryllidaceae species and their cholinesterase activity

Alkaloid extracts of four Amaryllidaceae species were studied with respect to their acetylcholinesterase and butyrylcholinesterase inhibitory activity and alkaloid patterns. Twenty-one alkaloids were determined by GC/MS, and seventeen of them identified from their mass spectra and retention times. The GC/MS analysis of the alkaloid extract of Nerine filamentosa is the first phytochemical investigation of this species. Promising erythrocytic acetylcholinesterase inhibitory activity was demonstrated by the alkaloid extracts of Narcissus poeticus var recurvus, Nerine filifolia and N. filamentosa (IC(50,HuAChE) = 6.0 +/- 0.1 microg/mL; IC(50,HuAChE) = 18.5 +/- 0.8 microg/mL, IC(50,HuAChE) = 21.6 +/- 1.1 microg/mL). The most potent inhibitory activity against serum butyrylcholinesterase was shown by extracts of Sternbergia lutea and Nerinefilamentosa (IC(50,HuBuChE) = 3.7 +/- 0.1 microg/mL; IC(50.HuBuChE) = 13.0 +/- 0.7 microg/mL).     

XRD,SAXS, and PALS investigations of three different polymers reinforced with tetraoctylammonium exchanged montmorillonite

Three different polymer nanocomposites were prepared using clay modified with tetraoctylammonium (4C8) surfactant. The dispersion of clay silicate layers was studied using X-ray diffraction and small-angle scattering. Free-volume cavity sizes were studied with positron annihilation lifetime spectroscopy. Scattering methods confirmed disruption of all polymer lamellae organization upon organoclay addition and the creation of partially intercalated systems for polyamide and polycaprolactone. The presence of organoclay in the polymers enlarges the lower value of average positronium lifetime τ₃ of polyamide and reduces the higher value of τ₃ for polycaprolactone and polyethylene.     

Two stage regression model with constraints; admissible second stage parameter estimation

If a regression experiment is realized in two stages, then two possibilities can occur in the second stage. Estimates of the first stage parameters either may be corrected by use of second stage measurements or they must stay unchanged. In the latter case, this requirement must be taken into account when estimating the second stage parameters. The situation is a little more complicated when constraints on both groups of parameters are imposed.     

Micro-hydration of the MgNO3+ cation in the gas phase.

Coordination complexes of the magnesium nitrate cation with water [MgNO(3)(H(2)O)(n)](+) up to n=7 are investigated by experiment and theory. The fragmentation patterns of [MgNO(3)(H(2)O)(n)](+) clusters generated via electrospray ionization indicate a considerable change in stability between n=3 and 4. Further, ion-molecule reactions of mass-selected [MgNO(3)(H(2)O)(n)](+) cations with D(2)O reveal the occurrence of consecutive replacement of water ligands by heavy water, and in this respect the complexes with n=4 and 5 are somewhat more reactive than their smaller homologs with n=1-3 as well as the larger clusters with n=6 and 7. For the latter two ions, the theory suggests the existence of isomers, such as complexes with monodentate nitrato ligands as well as solvent-separated ion pairs with a common solvation shell. The reactions observed and the ion thermochemistry are discussed in the context of ab initio calculations, which also reveal the structures of the various hydrated cation complexes.     

Linearized Regression Model with Constraints of Type II

A linearization of the nonlinear regression model causes a bias in estimators of model parameters. It can be eliminated, e.g., either by a proper choice of the point where the model is developed into the Taylor series or by quadratic corrections of linear estimators. The aim of the paper is to obtain formulae for biases and variances of estimators in linearized models and also for corrected estimators.     

Partial Molar Volumes of l-Serine and l-Threonine in Aqueous Ammonium Sulfate Solutions at (278.15, 288.15, 298.15, and 308.15) K

In this study, the partial molar volumes of l-serine and l-threonine in aqueous solutions of ammonium sulfate at (0.0, 0.1, 0.3, 0.7, and 1.0) mol·kg^?1 are reported between 278.15 and 308.15 K. Transfer volumes and hydration numbers were obtained, which are larger in l-serine than in l-threonine. Dehydration of the amino acids is observed, rising with the temperature and salt molality. The data suggest that interactions between ions and charged/hydrophilic groups are predominant, and by applying the McMillan and Mayer formalism, it was concluded that they are mainly pair wise. The combination of the data presented in this study with solubility and molecular dynamics data suggests a stronger interaction of the ammonium cation with the zwitterionic centers of the amino acids when compared to the interactions of those centers with the sulfate anion.     

Direct Arylation of Adenine by Fluoro- and Chloronitrobenzenes: Effect of Microwaves

Direct arylation of adenine with fluoro- and chloronitrobenzenes leads to mixtures of N9 and N7 substituted adenines. After separation by column chromatography, the individual isomers can be efficiently hydrogenated on Pd to give the corresponding aminophenyladenines. A significant enhancement of the reaction rate by microwave irradiation was observed. This two-step procedure was found to be a feasible route to otherwise hardly available 7-aminophenyladenines. Correlation between calculated shielding constants and experimental values of chemical shifts in ¹³C and ¹⁵N NMR was used for assignment of the site of substitution.

[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.]