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161.
One new saponin named davuricoside N (1) was isolated from the whole plants of Lysimachia davurica, the structure was determined by 1D and 2D NMR, ESI-MS techniques, and chemical methods. 相似文献
162.
Rongxiang He Prof. Aifeng Lv Xingyu Jiang Chang Cai Yazhou Wang Prof. Wan Yue Prof. Lizhen Huang Prof. Xue-Bo Yin Prof. Lifeng Chi 《Angewandte Chemie (International ed. in English)》2023,62(37):e202304549
Hydrophobic conjugated polymers have poor ionic transport property, so hydrophilic side chains are often grafted for their application as organic electrochemical transistors (OECTs). However, this modification lowers their charge transport ability. Here, an ionic gel interfacial layer is applied to improve the ionic transport while retaining the charge transport ability of the polymers. By using the ionic gels comprising gel matrix and ionic liquids as the interfacial layers, the hydrophobic polymer achieves the OECT feature with high transconductance, low threshold voltage, high current on/off ratio, short switching time, and high operational stability. The working mechanism is also revealed. Moreover, the OECT performance can be tuned by varying the types and ratios of ionic gels. With the proposed ionic gel strategy, OECTs can be effectively realized with hydrophobic conjugated polymers. 相似文献
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He Cui Qianlin Zhu Lizhen Dong Baotian Shan Tingting Han Huixin Li 《Analytical letters》2017,50(6):1040-1048
Arsenic speciation in rice has received attention due to its impact on food safety and human health. In this study, a sensitive method was developed for the determination of inorganic arsenic in rice using online anion suppression with ion chromatography and inductively coupled plasma mass spectrometry. HCl of 0.01?mol/L was the optimal extracting agent, and 38?mmol/L sodium carbonate and 15?mmol/L sodium acetate were used as the mobile phase to separate dimethylarsinic acid (DMA), arsenite, monomethylarsonic acid (MMA), and arsenate. The results showed that there were no significant losses or transformations with the anion suppressor and an improvement in sensitivity. The limits of quantification were 0.1?µg/L for DMA, As(III) and MMA, and 0.2?µg/L for As(V). The procedure was used to determine inorganic arsenic in rice; As(III) and DMA were the primary forms present. The reproducibility from seven measurements showed that the relative standard deviation was less than 1.68%. The recoveries were from 99.76 to 110.42%. The present work offers a new approach for the determination of inorganic arsenic in rice. 相似文献
165.
Chenyang Cui Huiying Chen Tongtong Zuo Xiaotao Fu Lizhen Chen Junfeng Geng Hua Li Xuan Xing 《Crystal Research and Technology》2016,51(1):94-98
Due to size‐dependent catalytic selectivity, the size and special morphology are of great importance to applications of TiO2. The synthesis method of size and morphology control has been in need of innovation. In this study, TiO2 nanoparticles(TiO2‐NPs) with well‐defined morphology and homogenous size were synthesized using a novel method, in which bamboo substrate, dielectrophoresis (DEP) technology and a sol‐gel process were combined(substrate/ DEP/ sol‐gel). Powder X‐ray diffraction (XRD) and scanning electron microscopy (SEM) techniques were used to characterize the TiO2‐NPs. Further study showed that, with this combined method, the size and the uniformity of TiO2‐NPs can be controlled by changing the voltage of DEP. The number and arrangement of TiO2 nanorods can be controlled by changing the voltage. Substrate/ DEP/ sol‐gel proved to be an efficient way to form special morphologies of TiO2‐NPs. A visible‐light catalytic activity experiment showed that among three preparation methods, the substrate/ DEP/ sol‐gel method made TiO2‐NPs with the highest catalytic activity for degradation of methyl orange. TiO2‐NPs produced by the DEP/ sol‐gel process presented higher catalytic activity than TiO2‐NPs produced by only a sol‐gel process. 相似文献
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167.
通过预还原的LaNiO3,La4Ni3O10,La3Ni2O7和La2NiO4催化分解CH4可以制备大量高度石墨化的碳纳米管。还原前后的催化剂的结构和组分通过X射线衍射(XRD)测定。所制得的碳纳米管由扫描电镜(TEM)、X射线光电子能谱(XPS)表征。碳纳米管在空气在的热氧化性由热重实验(TG)测定。实验结果表明不同催化剂前驱中的La/Ni比会影响碳纳米管的管径分布和石墨化程度。La/Ni比越小,碳纳米管的管径越大,石墨化程度越高。 相似文献
168.
制备了Cu-Zn-Al (4/50/5)催化剂(Cat)和Cu-Zn-Al-Li(40/50/5/5)催化剂(Cat-Li).并将其分别用于由CO/H_2和CO_2/H_2合成甲醇。诸如TPD、TPR、TPSR、脉冲、CD3I-捕获、同位素标记、EPR及原位DRIFT等技术和方法被用来表征这两种催化剂及研究反应机理,对处于去氢、含氢及含氧态催化剂进行了对比研究以期阐明表面氧和表面氢对CO_2和CO活化所起的作用。提出了一个由甲酸根和甲醛氢化及甲醇氧化结果为证的CO/CO_2氢化机理。由于通过Li 取代CuO晶格上的Cu2+形成的氢空位,在Cat中添加Li+改善了甲醇合成活性。CO_2能被一捕获的电子(F-中心)活化,生成的CO2-能容易地被氢化成甲酸根和亚甲基双草酰,后者分解生成H2CO和表面氧。CO能被表面氧活化,生成的CO2-将遵循CO_2氢化的途径。在CD3I-捕获的实验中,我们捕获了表面氧。在无表面氧时,CO可能直接氢化成甲酸基,即CO_2氢化中的一途径。由亚甲基双草酰产生的H2CO表面模型可能与由甲醛吸附或CO氢化生成的H2CO表面模型不同。 相似文献
169.
甲烷在预还原的LaCoO3催化剂上分解生成碳纳米管(CNTs)。研究了稳态下NO在CNTs,Rh/CNTs,Rh/A12O3上的分解,温度区间为573K~973K,原料气为6000ppm的NO,He为平衡气。程序升温还原结果表明:(1)Rh的负载显著降低了CNTs的氢吸收量;(2)负载于CNTs上的Rh比负载于A12O3上的Rh更易还原。在573K时NO即能与预还原后的CNTs,Rh/CNTS,Rh/Al2O3中存储的氢反应;随着氢的消耗,反应活性逐渐降低,当储存的氢消耗完后,NO的直接催化反应发生。在873 K及以上,Rh/CNTs中的CNTs能彼NO分解产生的氧氧化为CO。在973K时,NO在CNTs上几乎能100%分解,连续反应150min后其反应活性不降低,且未观察到CO或CO2的生成。在973K时CNTs本身可作为NO分解的催化剂,这是一个非常有意义的结果。 相似文献
170.