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71.
Collinear acousto-optic spectrometers with sound consisting of one frequency have a spectral transfer function with many good characteristics, such as a narrow bandwidth, ... the side lobes, however, are rather high. To reduce these side lobes, one can try to apodize the sound in the acousto-optic cell by using a sound wave consisting out of two frequencies. At certain times, this produces a more smoothened sound field in the cell than in the one-frequency case. The resulting transfer function will contain lower side lobes. Also, the influence of all the sound field parameters--the amplitude, frequency difference, and time--on the transmission function is studied. Out of these results, better-performing collinear spectrometers can be designed. 相似文献
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74.
Jamila Ghamri Herv Baussart Michel le Bras Jean-Marie Leroy 《Journal of Physics and Chemistry of Solids》1989,50(12):1237-1244
The mixed oxides BixEu1−xVO4 and BiyGd1−yVO4 crystallize in a zircon-type structure, for 0 <x < 0.6 and 0 < y < 0.64, and in a fergusonite-type structure, for 0.94 < x < 1 and 0.93 < y < 1. A process of competition between the dominant and the constrained effects of the lone-pair 6s2 of Bi3+ is discussed. The diffuse reflectance spectroscopic studies of these mixed oxides are presented. The observed broad bands are attributed to charge transfer processes and the sharp peaks in the BixEu1−xVO4 spectra are ascribed to intra-configurational 4f – 4ftransitions of the Eu3+ ion. The broad absorption shift in BiLnVO4 (Ln : Eu and Gd) compounds to the longer wavelengths range, when Bi is introduced in the LnVO4 lattice, is ascribed to charge transfer processes in a Bi-VO4 center and are interpreted assuming a Jahn-Teller effect in the excited state of Bi3+. The concept of an internal pressure of Bi3+ ions is also used to explain the broad A-band shifts. 相似文献
75.
Shan She Weimin Xuan Nicola L. Bell Robert Pow Eduard Garrido Ribo Zoe Sinclair De-Liang Long Leroy Cronin 《Chemical science》2021,12(7):2427
The precise control over the formation of complex nanostructures, e.g. polyoxometalates (POMs), at the sub-nanoscale is challenging but critical if non-covalent architectures are to be designed. Combining biologically-evolved systems with inorganic nanostructures could lead to sequence-mediated assembly. Herein, we exploit oligopeptides as multidentate structure-directing ligands via metal-coordination and hydrogen bonded interactions to modulate the self-assembly of POM superstructures. Six oligopeptides (GH, AH, SH, G2H, G4H and G5H) are incorporated into the cavities of Molybdenum Blue (MB) POM nanowheels. It is found that the helicity of the nanowheel can be readily switched (Δ to Λ) by simply altering the N-terminal amino acid on the peptide chain rather than their overall stereochemistry. We also reveal a delicate balance between the Mo-coordination and the hydrogen bonds found within the internal cavity of the inorganic nanowheels which results in the sequence mediated formation of two unprecedented asymmetrical nanowheel frameworks: {Mo122Ce5} and {Mo126Ce4}.Peptide sequence can be used to control the self-assembly and structures of nanoscale molybdenum blue polyoxometalate (POM) wheel-shaped clusters. 相似文献
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J. -P. Leroy J. Micholi G. -C. Rossi 《Zeitschrift fur Physik C Particles and Fields》1987,36(2):305-310
We prove that a complete fixing of the temporal gauge,A o =0, in which one imposesa subsidiary gauge condition, such as, for instance ?i A i (x,t 0) = 0 leads to consistent formulation of the theory with simple Feynman rulesand a well defined gluon propagator. The correct exponentiation of the time dependence of the Wilson loop has been checked to occur up to order g4. 相似文献
78.
79.
McGlone T Vilà-Nadal L Miras HN Long DL Poblet JM Cronin L 《Dalton transactions (Cambridge, England : 2003)》2010,39(48):11599-11604
Two titanium embedded polyoxometalates with unprecedented structural features are presented: a monotitanium containing tungstoantimonate Na(13)H(3)[TiO(SbW(9)O(33))(2)]·33 H(2)O featuring a {Ti=O}(2+) moiety (1) and a hexatitanium containing tungstoarsenate K(6)[Ti(4)(H(2)O)(10)(AsTiW(8)O(33))(2)]·30 H(2)O containing a {Ti(4)(H(2)O)(10)}(16+) moiety (2). Both compounds have been fully characterised by single crystal X-ray diffraction, elemental analysis, IR and TGA. 1 is constructed from two α-B-{Sb(III)W(9)O(33)} fragments linked by five sodium cations and an unprecedented square pyramidal Ti(O)O(4) group with a terminal Ti=O bond, and 2 exhibits a Krebs-type structure composed of two {AsTiW(8)O(33)} fragments, where one W(VI) centre has been substituted for a Ti(IV) centre in each, fused together via a belt of four additional Ti(IV) centres. This system represents the tungsten Ti-incorporated polyoxoanion with one of the highest Ti:W ratios so far reported. Additionally, 2 could also be isolated as an n-tetrabutylammonium salt and has been further characterised by electrochemistry and electrospray ionisation (ESI) MS studies. Due to the unique nature of these systems, both have been fully investigated using DFT calculations yielding highly interesting results. Structure 1 has been optimised with five sodium atoms in the belt position, which in addition to reducing the high charge of the cluster influence a stabilisation of the antimony lone pairs. Electrostatic potential calculations highlight the high electronegativity of the terminal oxygen on the titanium centre, enhancing real potentiality as a reactive site for catalysis. 相似文献
80.
R. Sokhoyan H. Azizbekyan C. Leroy A. Ishkhanyan 《Journal of Experimental and Theoretical Physics》2011,112(4):543-550
We discuss the strong-coupling regime of the nonlinear Landau-Zener problem occurring at coherent photo- and magneto-association of ultracold atoms. We apply a variational approach to an exact third-order nonlinear differential equation for the molecular state probability and construct an accurate approximation describing the time dynamics of the coupled atom-molecule system. The resultant solution improves the accuracy of the previous approximation [22]. The obtained results reveal a remarkable observation that in the strong-coupling limit, the resonance crossing is mostly governed by the nonlinearity, while the coherent atom-molecule oscillations occurring soon after crossing the resonance are principally of a linear nature. This observation is supposedly general for all nonlinear quantum systems having the same generic quadratic nonlinearity, due to the basic attributes of the resonance crossing processes in such systems. The constructed approximation turns out to have a larger applicability range than it was initially expected, covering the whole moderate-coupling regime for which the proposed solution accurately describes ail the main characteristics of the system evolution except the amplitude of the coherent atom-molecule oscillation, which is rather overestimated. 相似文献