全文获取类型
收费全文 | 169篇 |
免费 | 3篇 |
专业分类
化学 | 132篇 |
晶体学 | 2篇 |
数学 | 28篇 |
物理学 | 10篇 |
出版年
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2016年 | 2篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 9篇 |
2012年 | 12篇 |
2011年 | 6篇 |
2010年 | 12篇 |
2009年 | 14篇 |
2008年 | 10篇 |
2007年 | 10篇 |
2006年 | 3篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 10篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有172条查询结果,搜索用时 234 毫秒
21.
22.
23.
24.
R. A. A. Kubiak E. H. C. Parker S. Newstead J. J. Harris 《Applied Physics A: Materials Science & Processing》1984,35(1):61-66
An investigation of the growth of heteroepitaxial InAs by MBE is reported. The surface morphology and electrical properties are shown to be critically dependent on growth parameters and the conditions necessary to obtain good material quality are deduced. Analysis of the thickness dependence of the electrical properties of undoped, and Si- or Te-doped InAs shows that interfacial effects contribute to the measured properties. Material remote from the interfacial region compares favourably with VPE- and bulkgrown InAs. 相似文献
25.
26.
27.
The presence of parts per million (ppm) levels of impurities in the low-temperature arsenic charge used in molecular beam epitaxy (MBE) is shown to have a dramatic effect on the quality of GaAs grown. Source charge impurities play a vital role in determining the apparent variation in reported doping behaviour in MBE:GaAs. 相似文献
28.
The efficacy of fumed silica for removal of sorption interferences by organic surfactants in the anodic-stripping voltammetry of heavy metals is demonstrated. Appropriate addition of silica to the sample solution rapidly "purifies" it from interfering surfactants during the nitrogen purge step. Up to at least 6 ppm of gelatin, Triton X-100, albumin or Liqui-Nox then does not affect the stripping response of cadmium, lead and zinc at the hanging mercury drop electrode. A relative standard deviation of 5.5% is obtained for 20 successive measurements of 1 x 10(-7)M lead in the presence of 2 ppm Triton X-100. Analogous improvements are observed at the mercury film electrode (in the presence of up to 60 ppm of these surfactants). The use of silica thus possesses the advantages of speed, efficiency, simplicity and low cost compared to other schemes for dealing with surfactant interferences in anodic-stripping voltammetry. 相似文献
29.
A Series of Diamagnetic Pyridine Monoimine Rhenium Complexes with Different Degrees of Metal‐to‐Ligand Charge Transfer: Correlating 13C NMR Chemical Shifts with Bond Lengths in Redox‐Active Ligands 下载免费PDF全文
Dr. Daniel Sieh Prof. Dr. Clifford P. Kubiak 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(30):10638-10650
A set of pyridine monoimine (PMI) rhenium(I) tricarbonyl chlorido complexes with substituents of different steric and electronic properties was synthesized and fully characterized. Spectroscopic (NMR and IR) and single‐crystal X‐ray diffraction analyses of these complexes showed that the redox‐active PMI ligands are neutral and that the overall electronic structure is little affected by the choices of the substituent at the ligand backbone. One‐ and two‐electron reduction products were prepared from selected starting compounds and could also be characterized by multiple spectroscopic methods and X‐ray diffraction. The final product of a one‐electron reduction in THF is a diamagnetic metal–metal‐bonded dimer after loss of the chlorido ligand. Bond lengths in and NMR chemical shifts of the PMI ligand backbone indicate partial electron transfer to the ligand. Two‐electron reduction in THF also leads to the loss of the chlorido ligand and a pentacoordinate complex is obtained. The comparison with reported bond lengths and 13C NMR chemical shifts of doubly reduced free pyridine monoaldimine ligands indicates that both redox equivalents in the doubly reduced rhenium complex investigated here are located in the PMI ligand. With diamagnetic complexes varying over three formal reduction stages at the PMI ligand we were, for the first time, able to establish correlations of the 13C NMR chemical shifts with the relevant bond lengths in redox‐active ligands over a full redox series. 相似文献
30.
A sufficient condition for the strict insertion of a continuous function between two comparable upper and lower semicontinuous
functions on a normal space is given. Among immediate corollaries are the classical insertion theorems of Michael and Dowker.
Our insertion lemma also provides purely topological proofs of some standard results on closed subsets of normal spaces which
normally depend upon uniform convergence of series of continuous functions. We also establish a Tietze-type extension theorem
characterizing closed G
δ
-sets in a normal space.
This research was supported by the Ministry of Education and Science of Spain and FEDER under grant MTM2006-14925-C02-02.
The first named author also acknowledges financial support from the University of the Basque Country under grant UPV05/101. 相似文献