Current algebra and Wess-Zumino model in two dimensions

We investigate quantum field theory in two dimensions invariant with respect to conformal (Virasoro) and non-abelian current (Kac-Moody) algebras. The Wess-Zumino model is related to the special case of the representations of these algebras, the conformal generators being quadratically expressed in terms of currents. The anomalous dimensions of the Wess-Zumino fields are found exactly, and the multipoint correlation functions are shown to satisfy linear differential equations. In particular, Witten's non-abelean bosonisation rules are proven.     

The kinetics of carbon nanostructure 2D–3D transformation

The gas-phase process of formation of carbon nanostructures in an arc discharge plasma is considered. Most attention is paid to one of the key stages of the formation of these nanostructures, the transformation of plane structures into three-dimensional. The rolling up of a plane graphite sheet into a nanostructure similar to fullerene or a nanotube was simulated by the molecular dynamics method. The simulation data were described by a mechanism based on the generation of defects on the surface of the sheet. A set of elementary system structural transformations was determined, and the kinetic scheme describing the behavior of defects constructed. The lowest temperature of the observation of rolling up in practice was estimated.     

Synthetic magnetic opals

We present studies of novel nanocomposites of BiNi impregnated into the structure of opals as well as inverse opals. Atomic force microscopy and high resolution elemental analyses show a highly ordered structure and uniform distribution of the BiNi filler in the matrix. These BiNi-based nanocomposites are found to exhibit distinct ferromagnetic-like ordering with transition temperature of about 675 K. As far as we know there exists no report in literature on any BiNi compound which is magnetic.     

Temperature hysteretic effect and its influence on colossal magnetoresistance of La0.33Nd0.33Ca0.33MnO3

Electrical resistance (R) measurements of a bulk La_0.33Nd_0.33Ca_0.33MnO₃ perovskite in magnetic fields up to 40 kOe have revealed anomalous temperature hysteretic effects both in 0 Oe and 20 kOe magnetic fields. The sharp peak observed in the R vs. T plot indicates the occurrence of metal-to-insulator (M-I) transition at a temperature of T _MI=110 K and 140 K, for cooling and warming paths, respectively. An applied magnetic field of 20 kOe reduces the resistance and shifts T _MI to 160 K and 185 K for cooling and warming, respectively. We have observed a much higher resistance in the cooling path than in the warming path leading to the hysteretic resistance ratio (R _cool/R _warm) of 200 at 110 K and 1.8 at 160 K for 0 Oe and 20 kOe, respectively. Record values of colossal magnetoresistance (CMR) have been achieved. The CMR value reaches nearly 99% in the temperature ranges of 90 K to 140 K and 90 K to 170 K for 20 kOe and 40 kOe magnetic fields in the cooling mode, respectively. The observed unusual behavior is attributed to the co-existence of La-rich and Nd-rich domains assumed to be distributed randomly in the compound.     

Peak effect studies in single crystals CeRu2 and 2H-NbS2

We have studied the peak effect (PE) phenomenon in single crystals of weakly pinned superconductors CeRu₂ and 2H-NbS₂. 2H-NbS₂ is iso-structural and iso-electronic to 2H-NbSe₂, whose similarity with CeRu₂ as regards the PE representing the order-to-disorder transformation of the flux line lattice was claimed some time ago. We report on the step change in equilibrium magnetization across the peak effect in CeRu₂. We also present the vortex phase diagram of 2H-NbS₂ obtained from the magnetization data, and compare the PE phenomenon in 2H-NbS₂ and 2H-NbSe₂.     

Activation of molecular hydrogen by transition-metal complexes. 2. Formation of complexes,of palladium (O) and (+1) with a metal-metal bond during hydrogenolysis of [Ph3PPd(OAc)2]2

Conclusions The reaction of dipalladium -diacetatediacetatoditriphenylphosphine [Ph₃PPd(OAc)₂]₂ with hydrogen leads to formation of complexes of Pd(0), (Ph₃P)₂Pd₂, and of Pd(+l), (Ph₃PPd(OAc)₂, with a metal-metal bond.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1687–1690, August, 1979.     

Diffusion and drift of graphene flake on graphite surface

Diffusion and drift of a graphene flake on a graphite surface are analyzed. A potential energy relief of the graphene flake is computed using ab initio and empirical calculations. Based on the analysis of this relief, different mechanisms of diffusion and drift of the graphene flake on the graphite surface are considered. A new mechanism of diffusion and drift of the flake is proposed. According to the proposed mechanism, rotational transition of the flake from commensurate to incommensurate state takes place with subsequent simultaneous rotation and translational motion until a commensurate state is reached again, and so on. Analytic expressions for the diffusion coefficient and mobility of the flake corresponding to different mechanisms are derived in wide ranges of temperatures and sizes of the flake. The molecular dynamics simulations and estimates based on ab initio and empirical calculations demonstrate that the proposed mechanism can be dominant under certain conditions. The influence of structural defects on the diffusion of the flake is examined on the basis of calculations of the potential energy relief and molecular dynamics simulations. The methods of control over the diffusion and drift of graphene components in nanoelectromechanical systems are discussed. The possibility to experimentally determine the barriers to relative motion of graphene layers based on the study of diffusion of a graphene flake is considered. The results obtained can also be applied to polycyclic aromatic molecules on graphene and should be qualitatively valid for a set of commensurate adsorbate-adsorbent systems.     

Interlayer interaction and relative vibrations of bilayer graphene

The van der Waals corrected first-principles approach (DFT-D) is for the first time applied for investigation of interlayer interaction and relative motion of graphene layers. A methodological study of the influence of parameters of calculations with the dispersion corrected and original PBE functionals on characteristics of the potential relief of the interlayer interaction energy is performed. Based on the DFT-D calculations, a new classical potential for interaction between graphene layers is developed. Molecular dynamics simulations of relative translational vibrations of graphene layers demonstrate that the choice of the classical potential considerably affects dynamic characteristics of graphene-based systems. The calculated low values of the Q-factor for these vibrations Q≈ 10-100 show that graphene should be perfect for the use in fast-responding nanorelays and nanoelectromechanical memory cells.