ALP production through non-linear Compton scattering in intense fields

We derive production yields for massive pseudo-scalar and scalar axion-like-particles (ALPs), through non-linear Compton scattering of an electron in the background of low- and high-intensity electromagnetic fields. In particular, we focus on electromagnetic fields from Gaussian plane wave laser pulses. A detailed study of the angular distributions and effects of the scalar and pseudo-scalar masses is presented. It is shown that ultra-relativistic seed electrons can be used to produce scalars and pseudo-scalars with masses up to the order of the electron mass. We briefly discuss future applications of this work towards lab-based searches for light beyond-the-Standard-Model particles.     

Syntheses,Structures and Photoelectron Spectra of Phospha-Alkenes and Phospha-Alkynes and Their Transition Metal Complexes

Abstract

The chemistry of the novel phospha-alkenes RP[dbnd]CR'₂, and phospha-alkynes, RC[tbnd]P, containing 2pπ-3pπ bonds is of current interest.^1,2 Recent molecular orbital calculations,^3,4 suggest that the highest occupied molecular orbital in CH₂[dbnd]PH is of the π-type with the phosphorus lone pair ó-orbital only slightly more stable while the π? lumo orbital is relatively low lying. We now report He (I) photoelectron spectroscopic studies on a variety of RC[tbnd]P molecules^5,6 which indicate that the homo is also of the π-type and the π-σ separation is much greater than that found in the analogous RC[tbnd]N systems.     

An Efficient Synthesis of 15N-Hydroxyurea

Treatment of trimethylsilyl isocyanate with ¹⁵N-hydroxylamine hydrochloride produces ¹⁵N-hydroxyurea, a valuable pharmacological tool, in an efficient, one-pot procedure in 74% yield. Recrystallization of the crude product yields analytically pure material in 47% overall yield.     

Behaviour of polycyclic aromatic hydrocarbons in dissolved,colloidal, and particulate phases in sedimentary cores

Solid-phase microextraction (SPME) has been successfully used for extracting polycyclic aromatic hydrocarbons (PAHs) from porewater samples from the Mersey Estuary, UK. The majority of the PAHs in porewater samples are associated with colloids due to the high DOC concentrations. The truly dissolved PAH concentrations varied from 66 to 1050?ng?L^?1 in core 2 and from 95 to 740?ng?L^?1 in core 3, and were dominated by naphthalene, fluoranthene, and pyrene. Although absent in the dissolved phase, the high-molecular-mass compounds were found in the colloid-associated fraction of porewater. PAHs in sediments arose from a range of compounds with 4- and 5-ring PAHs dominating. The partitioning of PAHs between sediment and porewater shows that PAHs are enriched in the sediment phase. When the soot carbon content was considered, predictions of the partition behaviour were found to agree more closely with the observed distribution. The results reiterate the importance of evaluating the speciation of organic pollutants in both porewater and sediments in order to accurately predict their environmental fate and potential toxicity.     

New advancements in SERS dye detection using interfaced SEM and Raman spectromicroscopy (μRS)

In the past decade Surface Enhanced Raman Scattering (SERS) has emerged as a powerful technique for the analysis of artistic, historical and archaeological material culture. However, the identification of organic compounds in complex samples using SERS can be challenging owing to the complexity in optimizing the adsorption of target analytes onto the plasmonic substrate and the difficulty to identify proper areas on the sample for robust SERS analysis using optical systems. Scanning electron microscopy (SEM) interfaced with Raman spectromicroscopy (μRS) provides an ideal hyphenated system to overcome the last challenge by: (1) evaluating the nanoparticles coverage/distribution on the sample and (2) locating suitable areas for successful and reproducible SERS analysis. In this paper we demonstrate the potential of a system interfacing SEM and μRS for single fiber, extractionless analysis in the characterization of dyes from reference collections and archaeological textiles. Copyright © 2015 John Wiley & Sons, Ltd.     

Hysteresis of two interacting magnetic pairs with inequivalent perpendicular anisotropy

We consider a model for magnetic memory that consists of strongly coupled dipolar or antiferromagnetic (AF) pairs with inequivalent perpendicular anisotropy _K1$K_1$ and _K2$K_2$. For appropriate parameter values, determined in this work, they have two inequivalent storage states with zero net magnetic moment. Both analytical and numerical calculations are performed, in some cases yielding different results because of relaxation effects (i.e., a dependence on the damping parameter α$\alpha$). Hysteresis loops for a wide variety of parameter values are obtained, both for the AF case and the dipole case. An Appendix gives analytic results for slightly non-collinear spins in an applied field, which were used to test the numerical results.     

Threshold photoemission spectroscopy in solids

Threshold photoemission spectroscopy (TPES) is used to measure the Fe 2p spectrum of a stainless steel sample. The obtained spectrum is compared with analogous spectra measured by X-ray photoemission and absorption spectroscopies. The results of this comparison suggest that resonant two-electron autoionization processes, rather than direct photoemission from the core level, are the main mechanisms contributing to the signal. Limits and applicability of this experimental approach to investigate bulk electronic properties in solids are discussed.