A numerical study of double-leaf microperforated panel absorbers

Microperforated panel (MPP) absorbers are promising as a basis for the next-generation of sound absorbing materials. Typically, they are backed by an air-cavity in front of a rigid wall such as a ceiling or another interior surface of a room. Indeed, to be effective, MPP absorbers require the Helmholtz-type resonance formed with the backing cavity. Towards the creation of an efficient sound-absorbing structure with MPPs alone, the acoustical properties of a structure composed of two parallel MPPs with an air-cavity between them and no rigid backing is studied numerically. In this double-leaf MPP (DLMPP) structure, the rear leaf (i.e., the MPP remote from the incident sound) plays the role of the backing wall in the conventional setting and causes resonance-type absorption. Moreover, since a DLMPP can work efficiently as an absorber for sound incidence from both sides, it can be used efficiently as a space absorber, e.g., as a suspended absorber or as a sound absorbing panel. The sound absorption characteristics of the double-leaf MPP are analysed theoretically for a normally incident plane wave. The effects of various control parameters are discussed through a numerical parametric study. The absorption mechanisms and a possible design principle are discussed also. It is predicted that: (1) that a resonance absorption, similar to that in conventional type MPP absorbers, appears at medium-to-high frequencies and (2) that considerable “additional” absorption can be obtained at low frequencies. This low-frequency absorption is similar to that of a double-leaf permeable membrane and can be an advantage compared with the conventional type of MPP arrangement.     

Two-photon absorption properties of proquinoidal D-A-D and A-D-A quadrupolar chromophores

We report the synthesis, one- and two-photon absorption spectroscopy, fluorescence, and electrochemical properties of a series of quadrupolar molecules that feature proquinoidal π-aromatic acceptors. These quadrupolar molecules possess either donor-acceptor-donor (D-A-D) or acceptor-donor-acceptor (A-D-A) electronic motifs, and feature 4-N,N-dihexylaminophenyl, 4-dodecyloxyphenyl, 4-(N,N-dihexylamino)benzo[c][1,2,5]thiadiazolyl or 2,5-dioctyloxyphenyl electron donor moieties and benzo[c][1,2,5]thiadiazole (BTD) or 6,7-bis(3',7'-dimethyloctyl)[1,2,5]thiadiazolo[3,4-g]quinoxaline (TDQ) electron acceptor units. These conjugated structures are highly emissive in nonpolar solvents and exhibit large spectral red-shifts of their respective lowest energy absorption bands relative to analogous reference compounds that incorporate phenylene components in place of BTD and TDQ moieties. BTD-based D-A-D and A-D-A chromophores exhibit increasing fluorescence emission red-shifts, and a concomitant decrease of the fluorescence quantum yield (Φ(f)) with increasing solvent polarity; these data indicate that electronic excitation augments benzothiadiazole electron density via an internal charge transfer mechanism. The BTD- and TDQ-containing structures exhibit blue-shifted two-photon absorption (TPA) spectra relative to their corresponding one-photon absorption (OPA) spectra, and display high TPA cross sections (>100 GM) within these spectral windows. D-A-D and A-D-A structures that feature more extensive conjugation within this series of compounds exhibit larger TPA cross sections consistent with computational simulation. Factors governing TPA properties of these quadrupolar chromophores are discussed within the context of a three-state model.     

Reduction of sound radiation by using force radiation modes

The location of a vibration source within a machine is sometimes found to have a significant effect upon its radiated acoustic power. It is known that a simple reduction of vibration cannot always reduce the radiated acoustic power, so that treatments based on analysis of a structure’s vibration modes are not always effective. At the same time, radiation mode analysis is known to be a powerful tool for interpreting sound radiation since those modes are independent of a structure’s surface vibration. However, knowledge of the radiation modes alone cannot be used directly to understand the relationship between vibration source location and acoustic power radiation. In this paper, it is shown that the radiation mode concept can be extended to understand the relationship between acoustic power and driving force distribution by considering the product of the structure’s mobility matrix and the radiation modes: the resulting functions are here defined to be force radiation modes (f_rad-modes). An example is presented in which the acoustic power radiated by a simply-supported, baffled beam is reduced by using guidance provided by the structure’s force radiation modes. The results demonstrate that the force radiation modes can be used to guide the reduction of radiated acoustic power by changing the driving force location without the need to perform additional calculations or experiments.     

Effect of a honeycomb on the sound absorption characteristics of panel-type absorbers

Panel-type sound absorbers are commonly used to absorb low-frequency sounds. Recently, a new type of panel/membrane absorbers has been proposed as a next-generation sound absorber free from environmental problems. On the other hand, it is known that placing a honeycomb structure behind a porous layer can improve sound absorption performance and a similar effect can be obtained for microperforated-panel absorbers. Herein, the sound absorption characteristics of a panel sound absorber with a honeycomb in its back cavity are theoretically analyzed. The numerical results are used to discuss the variations in the sound absorption characteristics due to the honeycomb as well as the mechanism for sound absorption.     

Synthesis of alkali-metal cobalt kambaldaite by precipitation method

Alkali-metal cobalt kambaldaite (alkali-metal cobalt carbonate hydroxide hydrate; ideal structure, M₂Co₈(CO₃)₆(OH)₆ · 6H₂O; M-CoKBL) was prepared by the addition of a cobalt nitrate solution into a solution containing a large excess of alkali-metal bicarbonate followed by aging at 50 °C for 2–3 h. Hydrated alkali-metal ions are present in the channels of the kambaldaite structure; therefore, we tried to ion-exchange the K-CoKBL sample with various metals. However, collapse of the kambaldaite structure took place easily because of low pH of the ion-exchange solution. The catalytic activity of Co₃O₄ obtained by the calcination of “ion-exchanged” K-CoKBL was dependent on the residual potassium content in the catalyst.     

Ionic conductivities of Nasicon-type glass-ceramic superionic conductors in the system Na2O–Y2O3–XO2–SiO2 (X = Ti,Ge, Te)

Glass-ceramics of the titanium-, germanium- or tellurium-containing Na₅RSi₄O₁₂-type (R = rare earth; Y) Na⁺-superionic conductors (N5YXS) were prepared by crystallization of glasses with the composition Na_3+3xY_1 ? xX_ySi_3 ? yO₉ (X = Ti; NYTiS, Ge; NYGeS, X = Te; NYTeS), and the effects of X elements on the separation of the phase and the microstructural effects on the conduction properties of glass-ceramics were discussed. The combination of x and y was most varied in N5YGeS and more limited in the order of N5YTeS > N5YTiS. Their conductivities and activation energies are of the order of 10^? 2 S/cm at 300 °C and of 15 to 24 kJ/mol, respectively. The conductivity of the glass-ceramic N5YXS decreases giving the order N5YGeS > N5YTeS > N5YTiS. It is considered that this order corresponds to the N5 single phase region. Large enhancement of electrical conductivity was observed in the glass-ceramics as the grain growth was promoted with increase of heating temperature and heating time for crystallization.     

Study of tribochemical decomposition of ionic liquids on a nascent steel surface

Tribological properties and the decomposition process of ionic liquids (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide and 1-dodecyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide) on a nascent surface of bearing steel 52100 were investigated by a ball-on-disk friction tester in a vacuum chamber equipped with a quadrupole mass spectrometer (Q-MS). Ionic liquids exhibited better tribological properties than synthetic hydrocarbon oil (multialkylated cyclopentane (MAC)) in high vacuum conditions. The induction period for decomposition of MAC was about 10 km, while no obvious gaseous products were observed for ionic liquids even after a sliding distance of 22 km under the same mechanical conditions. The mass spectra indicated that both the anionic and cationic moieties of ionic liquids decomposed on the nascent steel surface during friction processes. The cationic moiety with a longer alkyl chain was more difficult to decompose on the nascent steel surface than that with a shorter alkyl chain. XPS analysis revealed that the tribofilm formed by ionic liquid was mainly composed of FeF₂ and FeS, which deactivated the nascent surface. As a result, desorption rate of gaseous products decreased appreciably comparing with MAC. The critical load for the mechanical activation of the decomposition correspondingly increased from 1.1 N of MAC to 8 N of ionic liquids.     

Effect of acoustical damping with a porous absorptive layer in the cavity to reduce the structure-borne sound radiation from a double-leaf structure

Structure-borne sound radiation from a double-leaf structure with a porous absorptive layer in the cavity is studied theoretically as well as experimentally. The study is for establishing a countermeasure to reduce the structure-borne noise radiated from an interior leaf into rooms and for clarifying its reduction effect. The sound field radiated from a double-leaf elastic plate with layers of arbitrary media in the cavity set into vibration by a point force excitation is theoretically analyzed. The effect of the bulk vibration of an absorptive layer is also considered by a simple model into the present theory. Radiation reduction of an inner-layer derived from the theory is experimentally validated. Parametric studies reveal that increasing the ratio of an absorptive layer thickness to the cavity depth is effective to reduce the structure-borne sound radiation but high flow resistivity of the absorbent material is not necessarily required. A practical equation to predict the mass-air-mass resonance frequency for absorbent cavity case is given in a simple form.     

In Situ Self-Assembly of Quantum Dots at the Plasma Membrane Mediates Energy Transfer-Based Activation of Channelrhodopsin

The use of nanoparticle (NP) bioconjugates to control the activity of membrane ion channels has recently emerged as a new paradigm for the activation of electrically excitable cells. An NP-based strategy is reported for the specific activation of channelrhodopsin C1V1 (ChR-C1V1) expressed in the plasma membrane of HEK 293T/17 cells. Hydrophilic CdSe/ZnS core–shell semiconductor quantum dots (QDs) are self-assembled to the exofacial face of recombinantly expressed ChR-C1V1 by metal affinity-driven interaction of the QD ZnS shell with an N-terminal hexahistidine tag displayed on ChR-C1V1. This configuration enables the Förster resonance energy transfer (FRET)-based excitation and activation of the 11-cis-retinal moiety of ChR-C1V1 using the QD as a light harvesting transducer/energy donor. It is shown that the specific laser-induced opening of the ChR-C1V1 channel wherein the photoexcited QD (405 nm excitation, 530 nm emission) iteratively activates ChR-C1V1 channels as confirmed using the voltage-sensitive dye (VSD) bis-(1,3-diethylthiobarbituric acid)trimethine oxonol (DiSBAC ₂ (3)). In the absence of the QD transducer, excitation of ChR-C1V1-expressing cells at 405 nm results in no activation of ChR-C1V1. The results demonstrate the ability to controllably interface QDs with living cells for the activation of ChR membrane proteins and detail a new NP-bioconjugate hybrid system for the specific activation of ion channels.