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71.
Selective N-monoalkylation of aromatic amines with 1° and 2° alcohols and conversion of aromatic amines to amides are performed immediately and in excellent yields using triphenylphosphine (PPh3) and 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) in dichloromethane at room temperature. Symmetrical and unsymmetrical N,N-dialkylation of aromatic amines are also carried out in modest yield at room temperature by this reagent system. 相似文献
72.
A green and convenient approach to the synthesis of 2-amino-4,6-diphenylnicotinonitriles via four-component reaction of malononitrile, aromatic aldehydes, acetophenone derivatives and ammonium acetate in water under ultrasound irradiation is described. The combinatorial synthesis was achieved for this methodology with applying ultrasound irradiation while making use of water as green solvent. In comparison to conventional methods, experimental simplicity, good functional group tolerance, excellent yields, short routine, and selectivity without the need for a transition metal or base catalyst are prominent features of this sonocatalyzed procedure. 相似文献
73.
Hadi Ebrahimi Akbar Zamaniyan Jafar S. Soltan Mohammadzadeh Ali Asghar Khalili 《Applied Mathematical Modelling》2013,37(16-17):8004-8015
The zonal analysis of industrial furnaces is considered with three-dimensional radiative heat transfer, incorporated with the mathematical zone method. In this method exchange areas are determined by simplified numerical integration in three dimensions for surface-surface, surface-gas and gas–gas zones for absorbing and emitting media. By focusing on new strategies to overcome the drawbacks of evaluating direct exchange areas, it is shown that the zone method is an effective numerical method for modeling three-dimensional thermal performance of gas-filled enclosures. Also the developed method for evaluating of exchange area is presented and compared with other methods in both sides of CPU time and accuracy. The method can decrease about 70% in error of calculation of some exchange areas as compared with the other numerical methods. 相似文献
74.
Xu G Narayan M Kurinov I Ripoll DR Welker E Khalili M Ealick SE Scheraga HA 《Journal of the American Chemical Society》2006,128(4):1204-1213
Reductive unfolding studies of proteins are designed to provide information about intramolecular interactions that govern the formation (and stabilization) of the native state and about folding/unfolding pathways. By mutating Tyr92 to G, A, or L in the model protein, bovine pancreatic ribonuclease A, and through analysis of temperature factors and molecular dynamics simulations of the crystal structures of these mutants, it is demonstrated that the markedly different reductive unfolding rates and pathways of ribonuclease A and its structural homologue onconase can be attributed to a single, localized, ring-stacking interaction between Tyr92 and Pro93 in the bovine variant. The fortuitous location of this specific stabilizing interaction in a disulfide-bond-containing loop region of ribonuclease A results in the localized modulation of protein dynamics that, in turn, enhances the susceptibility of the disulfide bond to reduction leading to an alteration in the reductive unfolding behavior of the homologues. These results have important implications for folding studies involving topological determinants to obtain folding/unfolding rates and pathways, for protein structure-function prediction through fold recognition, and for predicting proteolytic cleavage sites. 相似文献
75.
76.
Convenient and regioselective synthesis of indolizine and pyrrolo[2,1-a]isoquinoline/quinoline derivatives by one-pot multicomponent reaction of N-substituted pyridinium and isoquinolinum/quinolinium salts with alkyl propiolates in the presence triphenylphosphine is described. 相似文献
77.
Gholamhossein Khalili 《合成通讯》2013,43(23):3170-3174
A synthesis of functionalized N-arylsulfonyl pyrazoles from the multicomponent reaction of arylsulfonyl hydrazones and dialkyl acetylenedicarboxylates in the presence nucleophilic compounds such as pyridine, isoquinoline, or triphenylphosphine, in good yields, is described. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resources: Full experimental and spectral details.] 相似文献
78.
Hojjatollah Nazari Asieh Heirani‐Tabasi Maryam Hajiabbas Masoud Khalili Mohammadhossein Shahsavari Alavijeh Shadie Hatamie Armita Mahdavi Gorabi Elaheh Esmaeili Seyed Hossein Ahmadi Tafti 《先进技术聚合物》2020,31(2):248-259
Mimicking the extracellular matrix to have a similar nanofibrous structure regarding electrical conductivity and mechanical properties would be highly beneficial for cardiac tissue engineering. The molybdenum disulfide, MoS2, and reduced graphene oxide, rGO, nanosheets are two‐dimensional nanomaterials which can be considered as great candidates for enhancing the electrical and mechanical properties of biological scaffolds for cardiac tissue engineering applications. In this study, MoS2 and rGO nanosheets were synthesized and incorporated into silk fibroin nanofibers, SF, via electrospinning method. Then, the human iPSCs transfected with TBX‐18 gene, TBX18‐hiPSCs, were seeded on these scaffolds for in vitro studies. The MoS2 and rGO nanosheets were studied by Raman spectroscopy. After incorporation of the nanosheets into SF nanofibers, the associated characterizations were carried out including scanning electron microscopy, transmission electron microscopy, water contact angle, and mechanical test. Furthermore, SF, SF/MoS2, and SF/rGO scaffolds were used for in vitro studies. Herein, the scaffolds exhibited acceptable biocompatibility and considerable attachment to TBX18‐hiPSCs confirmed by 3‐(4, 5‐dimethylthiazol‐2‐yl)‐2, 5‐diphenyl tetrazolium bromide, MTT, assay, and scanning electron microscopy. Also, the real‐time PCR and immunostaining studies confirmed the maturity and upregulation of cardiac functional genes, including GATA‐4, c‐TnT, and α‐MHC in the SF/MoS2 and SF/rGO scaffolds compared with the bare SF one. Therefore, the reinforcement of these SF‐based scaffolds with MoS2 and rGO endues them as a suitable candidate for cardiac tissue engineering. 相似文献
79.
Javad Safari Hossein Naeimi Ali Akbar Khakpour Ramezan Sharifi Jondani Shiva Dehghan Khalili 《Journal of molecular catalysis. A, Chemical》2007,270(1-2):236-240
In this study we have described the synthesis of new 3-arylidene isobenzofuran-1(3H)-one derivatives. Condensation reaction of phthalic anhydride and quinoline derivatives under solvent-free condition and microwave irradiation in the presence of acetic anhydride as catalyst in good excellent yield is reported. 相似文献
80.
Malakhov I. Yu. Sveshnikov K. A. Fedorov S. M. Khalili M. F. 《Theoretical and Mathematical Physics》2002,132(2):1094-1118
We consider a three-phase modification of the hybrid chiral bag model involving the intermediate constituent quark phase along with the asymptotic freedom and hadronization phases. We find self-consistent solutions of the equations of the model in 1+1 dimensions with the fermion vacuum polarization effects taken into account. We study the renormalized total energy of the bag as a function of parameters characterizing the geometry of the bag and its topological (baryon) charge. We show that for a nonzero topological charge, there exists an entire series of configurations that are local minimums of the total energy of the bag and contain all the three phases, whereas in the nontopological case, the bag energy minimum corresponds to zero sizes of the domain of the asymptotic freedom phase. 相似文献