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991.
Kenji Machida 《Optical Review》1997,4(2):253-260
The image-processing system based on a two-dimensional Fourier transform is presented for the analysis of Young’s fringes pattern created from a double-exposure speckle photograph. The fringe spacing and orientation are determined using only one Young’s fringes pattern without any other diffraction halo patterns. The stress-intensity factors of a mixed-mode interface crack were measured by speckle photography. A compact normal and shear specimen with an interface crack was employed. This specimen enables us to carry out the experiment under various kinds of mixed-mode loading. A steel and an epoxy resin were used as dissimilar materials. The displacement along the crack lines at the free surface was measured by speckle photography. The K1 and K11 values were determined by a least squares method using displacement data along the crack lines. Three-dimensional finite element analysis was carried out on the same specimen. An accuracy of stress intensity factors obtained by the speckle photography was discussed by comparison of results obtained by the finite element analysis.Presented at 1996 International Workshop on Interferometry (IWI ‘96), August 27–29, Saitama, Japan. 相似文献
992.
Takeo Furukawa Yasuhiko Mukasa Toshikazu Suzuki Kenji Kano 《Journal of Polymer Science.Polymer Physics》2002,40(7):613-622
Broadband dielectric spectroscopy was used to examine ion‐conduction mechanisms in polypropylene oxide (PPO) with a molecular weight of 4000 complexed with LiClO4. Two distinct conduction mechanisms were proposed with respect to high and low salt concentration regions. In a concentrated regime (Li/O >10%), the segmental motion of PPO molecules is significantly slowed down by enhanced cation coordination that results in a marked decrease in molar conductivity. We found a linear relationship between the ionic diffusion coefficient and the relaxation frequency of slowed segmental motion over broad temperature and salt‐concentration ranges. The use of a random walk scheme revealed that ions hop around at the same rate as slowed segmental motion for a monomer length. In a dilute regime (Li/O <0.1%), ions are temporarily localized in a limited domain. The direct current conductivity is achieved by structural renewal that releases ions from such localization and provides a diffusional character. At intermediate salt concentrations, microphase separation into ion‐depleted and ion‐rich regions was evidenced by the coexistence of fast and slow segmental processes. The molar conductivity revealed a maximum at Li/O = 3%. Its decrease at higher salt concentrations was attributed to the slowing down of segmental motion, and that at lower salt concentrations was attributed to localization of ionic motion. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 613–622, 2002; DOI 10.1002/polb.10123 相似文献
993.
994.
Hideo Ohta Isao Ando Shoei Fujishige Kenji Kubota 《Journal of Polymer Science.Polymer Physics》1991,29(8):963-968
In order to obtain useful information about the molecular motion and structure of poly(N-isopropylacrylamide) (PNiPAM) in aqueous solution, proton spin-lattice relaxation times, proton spin-spin relaxation times, and volume changes were measured at pressures from 1 to 400 kg/cm2 as a function of temperature. We found that the molecular motion and the structure of water and PNiPAM in PNiPAM/water solution transitionally change at gelation temperature (31°C). The effect of pressure on such transitional changes is studied. It is suggested that application of pressure to the system prevents the gelation. 相似文献
995.
996.
Kenji Mori 《Journal of heterocyclic chemistry》1996,33(5):1497-1517
Chemistry and biology of oxygen heterocycles as insect pheromones are reviewed referring to exo-brevicomin, disparlure, japonilure and olean. Synthesis of koninginin A, a microbial metabolite, is discussed. Two azetidine alkaloids, penaresidin A and penazetidine A, were synthesized. 相似文献
997.
998.
Tetsuya Ikemoto Yoshitaka Kageyama Fumiko Onuma Yuriko Shibuya Kiyoshi Ichimura Keiichi Sakashita Kenji Mori 《Liquid crystals》1994,17(5):729-739
A series of new optically active δ-lactones were synthesized as chiral dopants for ferroelectric liquid crystals (FLCs). The response time of an FLC mixture containing 4 mol% (S)-2,2-dimethyl-5-[2-fluoro-4-(5-n-octylpyrimidin-2-yl)-phenoxy[methyl-δ-valerolactone was 25 μs at 25°C. (0-90 per cent change in light transmission, 10 V μm-1). The synthesis and properties of these materials as practical chiral dopants are reported. 相似文献
999.
Hideaki Matsuoka Kenji Hashimoto Shigetoshi Horikiri Mikako Saito Kimiko Yamamoto Joji Ando 《Analytical sciences》2002,18(11):1205-1208
The electric control of cellular functions via Ca2+ was formerly suggested. From this viewpoint, the involvement of a Ca2+ channel was studied using bovine fetal arterial endothelial (BFAE) cells in which P2X4, an ATP-operated and fluid shear stress sensitive Ca2+ channel, exists predominantly. An electric stimulus (sine wave, 10 Hz, 10 VPP, 30 s) caused a marked influx of Ca2+ into BFAE cells from an extracellular solution. The magnitude of the [Ca2+]i change increased with a decrease in the frequency in the range from 100 Hz to 5 Hz. Regarding the pathway of this Ca2+ influx, single-cell imaging and an ATP depletion experiment strongly suggested the involvement of a pathway different from P2X4. This pathway was thought to be a non-specific one, because typical Ca2+ channel blockers, such as verapamil, Gd3+, and Co2+, could not inhibit the Ca2+ influx. 相似文献
1000.
Kenji Yamaguchi 《Theoretical chemistry accounts》1978,49(2):151-160
A diagrammatic technique was developed for the estimation of the screened potential of -electron systems. The screened potential was expanded in terms of the polarization propagators which were constructed from either the singlet,
, or triplet vertex part,
. These vertex parts correspond to the singlet or triplet excitations, respectively, in the Random Phase Approximation (RPA) containing exchange diagrams. The excitation energies were calculated by using the screened potential in the framework of RPA with exchange. The excitation energies of several conjugated molecules with or without a hetero atom are in agreement with the experimental data. 相似文献