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81.
Tabanca N Demirci B Gürbüz I Demirci F Becnel JJ Wedge DE Başer KH 《Natural product communications》2011,6(5):701-706
The composition of the essential oils hydrodistilled from the aerial parts of five Achillea biebersteinii Afan samples, collected in central Turkey from Konya, Isparta and Ankara, were analyzed both by gas chromatography (GC-FID) and gas chromatography-mass spectrometry (GC-MS). Eighty-four components were identified, representing 87 to 99% of the total oil composition. The identified major components were 1,8-cineole (9-37%), camphor (16-30%) and p-cymene (1-27%). Two samples differed in piperitone (11%) and ascaridol (4%) content. The five A. biebersteinii essential oils were subsequently evaluated for their antifungal activity against the strawberry anthracnose-causing fungal plant pathogens Colletotrichum acutatum, C. fragariae and C. gloeosporioides using the direct overlay bioautography assay. The essential oils showed no antifungal activity at 80 and 160 microg/spot. In addition, A. biebersteinii oils and their major compounds were subsequently investigated against Aedes aegypti first instar larvae in a high throughput bioassay. Among the oils, only one sample from Ankara showed a notable larvacidal effect on Ae. aegypti larvae. The major compounds, 1,8-cineole, camphor and p-cymene, exhibited low mosquito larval activity, and thus the minor compounds are probably responsible for the observed activity against Ae. aegypti larvae. The oils showed weak activity against adult Ae. aegypti. 相似文献
82.
Hüseyin Deligöz Mesut Yılmazoğlu Serpil Yılmaztürk Yavuz Şahin Kemal Ulutaş 《先进技术聚合物》2012,23(8):1156-1165
The paper deals with the synthesis and characterization of a new series of anhydrous conducting acid‐doped complex membranes based on polyimide (PI) and ionic liquid (IL) for high‐temperature fuel cells via a new route. For this purpose, three imidazolium‐based ILs (RIm+BF4?) with different alkyl chain lengths (R=methyl, ethyl, and butyl) are added into polyamic acid (PAA) intermediate prepared from the reaction of benzophenonetetracarboxylic dianhydride and diaminodiphenylsulfone in different –COOH/imidazolium molar ratios (n = 0.5, 1, and 2). Then, the thermally imidized complex membrane was doped with H2SO4. The conductivities of acid‐doped PI/IL complex membranes prepared by taking n of 1 are found to be in the range of 10?4?10?5 S cm?1 at 180°C, whereas the acid‐free PI/IL complex membranes show the conductivity at around 10?9?10?10 S cm?1. Thermogravimetric analysis results reveal that the acid‐doped PI/IL complex membranes are thermally stable up to 250°C. Dynamic mechanical analysis results of the acid‐doped ionically interacted complex membrane show that the mechanical strengths of the PI/IL complex membranes including 1‐methyl imidazolium tetrafluoroborate (MeIm‐BF4) and 1‐ethyl 3‐methyl imidazolium tetrafluoroborate (EtIm‐BF4) are comparable with those of pristine PI until 200°C. Furthermore, it can be clearly emphasized that the ionic interaction between carboxylic acid groups of PAA's and IL's cations offers a positive role in long‐term conductivity stability by preventing the IL migration at high temperatures. On the other hand, preliminary methanol permeability tests of the acid‐doped membranes show that they can also be considered as an alternative for direct methanol fuel cells. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
83.
New, aminomethyldiphosphine (P C N) ligands, ((C6H5)2PCH2)2NR (R = C6H3 (CH3)(OH) ( 1a ), C6H4OC6H5( 1b ), C6H4SC6H5) ( 1c )) and their Pd(II) complexes have been synthesized and characterized. These complexes were found to be efficient catalysts in the Heck reaction of activated and deactivated aryl halide with a variety of olefins. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:466–471, 2012; View this article online at wileyonlinelibrary.com . DOI 10.1002/hc.21038 相似文献
84.
Steven T. Dougherty Suat Karadeniz Bahattin Yildiz 《Designs, Codes and Cryptography》2012,63(1):113-126
Cyclic codes over an infinite family of rings are defined. The general properties of cyclic codes over these rings are studied,
in particular nontrivial one-generator cyclic codes are characterized. It is also proved that the binary images of cyclic
codes over these rings under the natural Gray map are binary quasi-cyclic codes of index 2
k
. Further, several optimal or near optimal binary codes are obtained from cyclic codes over R
k
via this map. 相似文献
85.
The electrical and interface state properties of Au/perylene-monoimide (PMI)/n-Si Schottky barrier diode have been investigated by current–voltage (I–V) and capacitance–voltage (C–V) measurements at room temperature. A good rectifying behavior was seen from the I–V characteristics. The series resistance (Rs) values were determined from I–V and C–V characteristics and were found to be 160 Ω and 53 Ω, respectively. The barrier height (Φb) of Au/PMI/n-Si Schottky diode was found to be 0.694 eV (I–V) and 0.826 eV (C–V). The ideality factor (n) was obtained to be 4.27 from the forward bias I–V characteristics. The energy distribution of interface state density (Nss) of the PMI-based structure was determined, and the energy values of Nss were found in the range from Ec ? 0.508 eV to Ec ? 0.569 eV with the exponential growth from midgap toward the bottom of the conduction band. The values of the Nss without Rs are 2.11 × 1012 eV?1 cm?2 at Ec ? 0.508 eV and 2.00 × 1012 eV?1 cm?2 at Ec ? 0.569 eV. Based on the above results, it is clear that modification of the interfacial potential barrier for metal/n-Si structures has been achieved using a thin interlayer of the perylene-monomide. 相似文献
86.
87.
Unsteady state counter diffusion problem with position dependent diffusion coefficient can be modeled using Fick’s second law. A mathematical model was constructed and solved to quantitatively describe the dynamic behavior of solute diffusion through non-homogeneous materials where diffusion coefficient is a function of position. The eigenfunction expansion approach was utilized to solve the model. The eigenvalues and eigenfunction of the system were obtained using a variational method. It has been shown that position dependency of the material can be neglected if the thickness of the material is relatively small. Mathematical models were solved for different thicknesses and different diffusion coefficient functions. 相似文献
88.
Imran Rizvi Shubhankar Nath Girgis Obaid Mustafa Kemal Ruhi Kaitlin Moore Shazia Bano David Kessel Tayyaba Hasan 《Photochemistry and photobiology》2019,95(1):419-429
A major objective in developing new treatment approaches for lethal tumors is to reduce toxicity to normal tissues while maintaining therapeutic efficacy. Photodynamic therapy (PDT) provides a mechanistically distinct approach to treat tumors without the systemic toxicity of chemotherapy drugs. PDT involves the light‐based activation of a small molecule, a photosensitizer (PS), to generate reactive molecular species (RMS) that are toxic to target tissue. Depending on the PS localization, various cellular and subcellular components can be targeted, causing selective photodamage. It has been shown that targeted lysosomal photodamage followed by, or simultaneous with, mitochondrial photodamage using two different PS results in a considerable enhancement in PDT efficacy. Here, two liposomal formulations of benzoporphyrin derivative (BPD): (1) Visudyne (clinically approved) and (2) an in‐house formulation entrapping a lipid conjugate of BPD are used in combination with direct PS localization to mitochondria, endoplasmic reticulum and lysosomes, enabling simultaneous photodamage to all three organelles using a single wavelength of light. Building on findings by our group, and others, this study demonstrates, for the first time in a 3D model for ovarian cancer, that BPD‐mediated photodestruction of lysosomes and mitochondria/ER significantly enhances PDT efficacy at lower light doses than treatment with either PS formulation alone. 相似文献
89.
Sibel Morkoç Karadeniz Tuba Klnç Burcu Bozkurt rak Tuba Irmak Sakaolu ar rak Mehmet Erturul Ali Ercan Ekinci 《光谱学与光谱分析》2016,36(6):1998-2000
In this Study, Cadmium Oxide (CdO) nanostructures were synthesized by using Chemical Bath Deposition Technique. The synthesized process was carried out at room temperature. The structural and optical properties of nanostructures was characterized by XRD, SEM and UV-Vis techniques. As a result, the CdO nanostructures are oriented along (111) plane of cubic crystal structure. The morphology of CdO nanostructures showed interconnected prism-like and cauliflower-type cluster nanostructure. The UV results of this structures with high absorbtion coefficient are observed to be in accordance with the CdO nanoparticles. 相似文献
90.
I. Mustafaev Y. Tolgonay M. Kemal A. Yamik 《Journal of Radioanalytical and Nuclear Chemistry》1994,188(5):355-365
The regularities of destructive and polycondensation processes in lignites of the Soma coal field, Turkey, were investigated by the methods of EPR, IR spectroscopy, derivatography and chromatography. It was shown that on lignite irradiation by -rays the character of the processes changes, depending on the absorbed dose and temperature. At room temperature and doses up to 200 kGy irradiation leads to the accumulation of radiation defects, which stimulate destructive reactions. At higher doses, due to the recombination of radiation defects, there is radiation lacing of the organic mass of coals. On the conjugate action of heat and irradiation on coals, destrution processes predominate. The mechanism of radiation effect upon coals is explained within the scope of the conception of self-associated multimer structure of coals. 相似文献